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1. 发明授权

US09241482B2 Self-decontaminating surface coatings and articles prepared therefrom 有权
标题翻译：自净化表面涂层及其制备的物品
公开(公告)号：US09241482B2
公开(公告)日：2016-01-26
申请号：US11548406
申请日：2006-10-11
申请人： Martin E. Rogers , Janice P. Phillips , Bryan Koene , Marc S. Hirsch , James H. Wynne
发明人： Martin E. Rogers , Janice P. Phillips , Bryan Koene , Marc S. Hirsch , James H. Wynne
IPC分类号： A01N25/34 , A01N33/12 , A01P1/00 , A01N25/10 , C09D5/14
CPC分类号： A01N25/34 , A01N25/10 , A01N33/12 , C09D5/14 , A01N25/00 , A01N25/08 , A01N37/44 , A01N63/00 , A01N2300/00 , A01N25/04
摘要： The present invention is directed toward a self-decontaminating surface coating, which when cured has a partially hydrophobic surface. The coating comprises a polymeric coating resin which, when cured, is hydrophilic. The coating also comprises a biocide, a germinating agent, and a hydrophobic micro/nano particulate material. The coating is suitable for application to ceramics, metals, and polymer substrates. Articles coated with the coating of the present invention are resistant to spores.
摘要翻译：本发明涉及一种自净化表面涂层，其在固化时具有部分疏水性表面。涂层包括聚合物涂层树脂，其在固化时是亲水的。涂层还包括杀生物剂，发芽剂和疏水微/纳米颗粒材料。该涂层适用于陶瓷，金属和聚合物基材。用本发明的涂层涂覆的制品对孢子具有抗性。

2. 发明授权

US08202614B2 Additive particles having superhydrophobic characteristics and coatings and methods of making and using the same 失效
标题翻译：具有超疏水特性和涂层的添加剂颗粒及其制备和使用方法
公开(公告)号：US08202614B2
公开(公告)日：2012-06-19
申请号：US12420618
申请日：2009-04-08
申请人： Bryan E. Koene , Martin E. Rogers , Jonas C. Gunter
发明人： Bryan E. Koene , Martin E. Rogers , Jonas C. Gunter
IPC分类号： B32B5/16 , C04B14/00 , C04B14/04 , C04B38/00
CPC分类号： B05D5/08 , B05D2601/20 , C03C17/007 , C03C2217/46 , C03C2217/76 , C08K3/22 , C08K3/36 , C08K9/06 , C08K9/12 , C09D7/62 , C09D7/68 , C09D7/69 , D06M11/45 , D06M11/46 , D06M11/79 , D06M11/83 , D06M15/263 , D06M15/564 , D06M15/643 , D06M23/08 , D06M2200/12 , Y10T428/25 , Y10T428/259 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T442/2164
摘要： Additive particles may be employed in sufficient amounts to impart superhydrophobicity to a coating system in which the additive particles are incorporated. The additive particles include carrier microparticles and a dense plurality of nanoparticles adhered to the surfaces of the carrier microparticles (e.g., preferably by electrostatic deposition or covalent bonding). The additive particles are advantageously incorporated into a coating material (e.g., a polymeric material) in amounts sufficient to render a substrate surface superhydrophobic when coated with the coating material. The substrate may be rigid (e.g., glass, ceramic or metal) or flexible (e.g., a polymeric film or sheet or a fabric). In some preferred embodiments, both the microparticle and nanoparticles are formed of silica and are surface treated with a hydrophobic treatment so as to impart superhydrophobic properties thereto. Especially preferred are particles treated with silicone fluid comprised of a polysiloxane and/or a perfluoro silane having between 1 and 40 carbon atoms.
摘要翻译：可以以足够的量使用添加剂颗粒以赋予其中掺入添加剂颗粒的涂料体系超疏水性。添加剂颗粒包括载体微粒和粘附到载体微粒表面的致密多个纳米颗粒（例如优选通过静电沉积或共价键合）。添加剂颗粒有利地以足以在涂覆涂料时使基材表面超疏水的量掺入涂料（例如聚合物材料）中。基底可以是刚性的（例如，玻璃，陶瓷或金属）或柔性的（例如，聚合物膜或片或织物）。在一些优选的实施方案中，微粒和纳米颗粒均由二氧化硅形成，并用疏水处理进行表面处理，以赋予其超疏水性。特别优选的是用聚硅氧烷和/或具有1至40个碳原子的全氟硅烷组成的硅氧烷流体处理的颗粒。

3. 发明授权

US07060636B2 Tunable dielectric device and process relating thereto 失效
标题翻译：可调电介质器件及其相关工艺
公开(公告)号：US07060636B2
公开(公告)日：2006-06-13
申请号：US10960341
申请日：2004-10-07
申请人： Janice P. Phillips , Bryan E. Koene , Steven A. Stevenson , Daniela M. Topasna , Martin E. Rogers
发明人： Janice P. Phillips , Bryan E. Koene , Steven A. Stevenson , Daniela M. Topasna , Martin E. Rogers
IPC分类号： H01L21/31
CPC分类号： B82Y30/00 , H01G7/06 , H01P1/181 , H01P1/203
摘要： The present invention is directed toward a tunable dielectric device comprising: a substrate and an endohedral fullerene encapsulating trimetallic nitride template compound disposed on the substrate. The endohedral fullerene encapsulating trimetallic nitride template compound has a dipole moment that is oriented when a voltage of less than about 5 volts is applied thereto causing a change in the orientation of the dipole moment of the compound. The physical dimension of the compound is essentially unchanged.
摘要翻译：本发明涉及一种可调电介质器件，其包括：衬底和封装镶嵌在衬底上的三金属氮化物模板化合物的内嵌富勒烯。封装三叠系金属氮化物模板化合物的内嵌富勒烯具有当施加小于约5伏的电压时定向的偶极矩，引起化合物的偶极矩的取向的变化。化合物的物理尺寸基本上没有变化。

4. 发明授权

US06254950B1 Polyester phenylenedi (oxyacetic acid) copolyester blends having improved gas barrier properties 失效
标题翻译：具有改进的气体阻隔性能的聚酯亚苯基二（氧乙酸）共聚酯共混物
公开(公告)号：US06254950B1
公开(公告)日：2001-07-03
申请号：US09332829
申请日：1999-06-14
申请人： Martin E. Rogers , Robert B. Barbee , David R. Fagerburg , Timothy E. Long
发明人： Martin E. Rogers , Robert B. Barbee , David R. Fagerburg , Timothy E. Long
IPC分类号： C08L6702
CPC分类号： C08J5/18 , C08J2367/02 , C08L67/02 , C08L67/025 , Y10T428/1352 , Y10T428/1397
摘要： This invention relates to polyester compositions that possess improved gas barrier properties. The novel copolyester blends comprise repeat units of phenylenedi(oxyacetic acid). Such copolyesters with improved gas barrier properties are useful in packaging applications where low gas permeability are required for protection or preservation of the contents.
摘要翻译：本发明涉及具有改善的阻气性的聚酯组合物。新型共聚酯共混物包含亚苯基二（重氮乙酸）的重复单元。具有改善的气体阻隔性能的这种共聚酯可用于需要低气体渗透性以保护或保存内容物的包装应用中。

5. 发明授权

US07001942B2 Flame retardant thermoset resins and methods of making the same 失效
标题翻译：阻燃热固树脂及其制造方法
公开(公告)号：US07001942B2
公开(公告)日：2006-02-21
申请号：US10829443
申请日：2004-04-22
申请人： Martin E. Rogers , Pascal Deschatelets , Janice P. Phillips
发明人： Martin E. Rogers , Pascal Deschatelets , Janice P. Phillips
IPC分类号： C08K3/32 , C08K3/38 , C08K3/28
CPC分类号： C08J3/203 , C08K3/016 , C08K3/32 , Y10T428/31504
摘要： Articles and processes are provided whereby flame-retardant SAP particles are incorporated into synthetic resins, especially curable thermosettable resins. The SAP particles are most preferably hydrated with an aqueous flame-retardant solution. In this regard, the flame-retardant solution may consist essentially of water alone or a water solution containing one or more water soluble inorganic flame retardants. When SAP particles are hydrated with an aqueous inorganic flame retardant solution, the SAP particles may thereafter be dried to remove substantially the water component. In such a manner, the inorganic flame retardant will remain as a dried residue physically entrained within the SAP particles. As such, the SAP particles serve as a physical matrix in which the inorganic flame retardant is homogenously dispersed. The SAP particles may then be blended with a synthetic resin as is or alternatively may be ground into more finely divided particles which contain the dried residue of the aqueous inorganic flame retardant solution and then blended with a suitable synthetic resin.
摘要翻译：提供了制品和方法，其中阻燃SAP颗粒被并入合成树脂，特别是可固化的可热固树脂中。 SAP颗粒最优选用含水阻燃溶液水合。在这方面，阻燃溶液可以基本上由单独的水或含有一种或多种水溶性无机阻燃剂的水溶液组成。当SAP颗粒与含水无机阻燃剂溶液水合时，此后可将SAP颗粒干燥以除去基本上水分。以这种方式，无机阻燃剂将保留为物理夹带在SAP颗粒内的干燥残余物。因此，SAP颗粒用作其中无机阻燃剂均匀分散的物理基体。然后可以将SAP颗粒与合成树脂共混，或者可以研磨成更细的颗粒，其含有无机阻燃剂水溶液的干燥残余物，然后与合适的合成树脂混合。

6. 发明授权

US07018709B2 Contamination-resistant coated substrates 失效
标题翻译：耐污染涂层基材
公开(公告)号：US07018709B2
公开(公告)日：2006-03-28
申请号：US10690070
申请日：2003-10-21
申请人： Janice P. Stevenson , Martin E. Rogers , Daniela M. Topasna
发明人： Janice P. Stevenson , Martin E. Rogers , Daniela M. Topasna
IPC分类号： B32B1/00
CPC分类号： G02B1/18 , B05D1/185 , B05D7/52 , B05D7/56 , B82Y30/00 , B82Y40/00 , C03C17/3405 , C08F8/24 , C08F8/44 , C08J7/04 , C08J2367/02 , G02B1/10 , G02B27/0006 , Y10T428/26 , Y10T428/265 , Y10T428/31507 , Y10T428/3154
摘要： A coated substrate is claimed. The coating, disposed on the substrate, comprises a self-assembled film having at least one bilayer. Each bilayer comprises a polyanion electrolyte layer and a polycation electrolyte layer. The uppermost layer or exposed layer of the coating comprises a fluoroalkyl group. Each bilayer thickness ranges from about 0.1 nanometers to about 20 nanometers. The resulting coated substrate has a low surface energy and is hydrophobic and/or oleophobic.
摘要翻译：要求涂覆的基材。设置在基板上的涂层包括具有至少一个双层的自组装膜。每个双层包含聚阴离子电解质层和聚阳离子电解质层。涂层的最上层或暴露层包含氟代烷基。每个双层厚度范围为约0.1纳米至约20纳米。所得到的涂覆的基材具有低的表面能并且是疏水的和/或疏油的。

7. 发明申请

US20090298369A1 ADDITIVE PARTICLES HAVING SUPERHYDROPHOBIC CHARACTERISTICS AND COATINGS AND METHODS OF MAKING AND USING THE SAME 失效
标题翻译：具有超级特性和涂层的添加剂颗粒及其制备和使用方法
公开(公告)号：US20090298369A1
公开(公告)日：2009-12-03
申请号：US12420618
申请日：2009-04-08
申请人： Bryan E. KOENE , Martin E. ROGERS , Jonas C. GUNTER
发明人： Bryan E. KOENE , Martin E. ROGERS , Jonas C. GUNTER
IPC分类号： B32B5/30 , B32B1/00 , C08K9/10 , C08K9/06 , B32B5/16 , B05D1/00 , B05D1/06
CPC分类号： B05D5/08 , B05D2601/20 , C03C17/007 , C03C2217/46 , C03C2217/76 , C08K3/22 , C08K3/36 , C08K9/06 , C08K9/12 , C09D7/62 , C09D7/68 , C09D7/69 , D06M11/45 , D06M11/46 , D06M11/79 , D06M11/83 , D06M15/263 , D06M15/564 , D06M15/643 , D06M23/08 , D06M2200/12 , Y10T428/25 , Y10T428/259 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T442/2164
摘要： Additive particles may be employed in sufficient amounts to impart superhydrophobicity to a coating system in which the additive particles are incorporated. The additive particles include carrier microparticles and a dense plurality of nanoparticles adhered to the surfaces of the carrier microparticles (e.g., preferably by electrostatic deposition or covalent bonding). The additive particles are advantageously incorporated into a coating material (e.g., a polymeric material) in amounts sufficient to render a substrate surface superhydrophobic when coated with the coating material. The substrate may be rigid (e.g., glass, ceramic or metal) or flexible (e.g., a polymeric film or sheet or a fabric). In some preferred embodiments, both the microparticle and nanoparticles are formed of silica and are surface treated with a hydrophobic treatment so as to impart superhydrophobic properties thereto. Especially preferred are particles treated with silicone fluid comprised of a polysiloxane and/or a perfluoro silane having between 1 and 40 carbon atoms.
摘要翻译：可以以足够的量使用添加剂颗粒以赋予其中掺入添加剂颗粒的涂料体系超疏水性。添加剂颗粒包括载体微粒和粘附到载体微粒表面的致密多个纳米颗粒（例如优选通过静电沉积或共价键合）。添加剂颗粒有利地以足以在涂覆涂料时使基材表面超疏水的量掺入涂料（例如聚合物材料）中。基底可以是刚性的（例如，玻璃，陶瓷或金属）或柔性的（例如，聚合物膜或片或织物）。在一些优选的实施方案中，微粒和纳米颗粒均由二氧化硅形成，并用疏水处理进行表面处理，以赋予其超疏水性。特别优选的是用聚硅氧烷和/或具有1至40个碳原子的全氟硅烷组成的硅氧烷流体处理的颗粒。

8. 发明授权

US07423079B2 Flame-retardant synthetic textile articles and methods of making the same 有权
标题翻译：阻燃合成纤维制品及其制造方法
公开(公告)号：US07423079B2
公开(公告)日：2008-09-09
申请号：US11130409
申请日：2005-05-17
申请人： Martin E. Rogers , Janice Paige Phillips , Bryan Koene
发明人： Martin E. Rogers , Janice Paige Phillips , Bryan Koene
IPC分类号： C08K5/49
CPC分类号： C08K3/32 , C08K3/016
摘要： Synthetic textile articles (e.g., filaments, fibers, yarns, fabrics and the like) and processes of making the same are provided which include flame-retardant SAP particles. The SAP particles are most preferably hydrated with an aqueous flame-retardant solution. In this regard, the flame-retardant solution may consist essentially of water alone or a water solution containing one or more water soluble inorganic flame retardants. When SAP particles are hydrated with an aqueous inorganic flame retardant solution, the SAP particles may thereafter be dried to remove substantially the water component. In such a manner, the inorganic flame retardant will remain as a dried residue physically entrained within the SAP particles. As such, the SAP particles serve as a physical matrix in which the inorganic flame retardant is homogenously dispersed. The SAP particles may then be chemically or physically affixed to the textile article in an amount sufficient to render the article flame-retardant.
摘要翻译：提供了合成织物制品（例如长丝，纤维，纱线，织物等）及其制备方法，其包括阻燃SAP颗粒。 SAP颗粒最优选用含水阻燃溶液水合。在这方面，阻燃溶液可以基本上由单独的水或含有一种或多种水溶性无机阻燃剂的水溶液组成。当SAP颗粒与含水无机阻燃剂溶液水合时，此后可将SAP颗粒干燥以除去基本上水分。以这种方式，无机阻燃剂将保留为物理夹带在SAP颗粒内的干燥残余物。因此，SAP颗粒用作其中无机阻燃剂均匀分散的物理基体。 SAP颗粒然后可以化学或物理地固定到织物制品上，其量足以使制品阻燃。

9. 发明授权

US07329461B2 Flame-retardant synthetic resin articles containing flame-retardant superabsorbent polymer (SAP) particles 失效
标题翻译：含有阻燃超吸收聚合物（SAP）颗粒的阻燃合成树脂制品
公开(公告)号：US07329461B2
公开(公告)日：2008-02-12
申请号：US11121942
申请日：2005-05-05
申请人： Martin E. Rogers , Pascal Deschatelets , Janice P. Phillips
发明人： Martin E. Rogers , Pascal Deschatelets , Janice P. Phillips
IPC分类号： C08K5/49
CPC分类号： C08J3/203 , C08K3/016 , C08K3/32 , Y10T428/31504
摘要： Flame-retardant synthetic resin articles and methods of making the same are provided whereby flame-retardant SAP particles are incorporated into synthetic resins, especially curable thermosettable resins. The SAP particles are most preferably hydrated with an aqueous flame-retardant solution. In this regard, the flame-retardant solution may consist essentially of water alone or a water solution containing one or more water soluble inorganic flame retardants. When SAP particles are hydrated with an aqueous inorganic flame retardant solution, the SAP particles may thereafter be dried to remove substantially the water component. In such a manner, the inorganic flame retardant will remain as a dried residue physically entrained within the SAP particles. As such, the SAP particles serve as a physical matrix in which the inorganic flame retardant is homogenously dispersed. The SAP particles may then be blended with a synthetic resin as is or alternatively may be ground into more finely divided particles which contain the dried residue of the aqueous inorganic flame retardant solution and then blended with a suitable synthetic resin.
摘要翻译：提供阻燃合成树脂制品及其制备方法，其中阻燃SAP颗粒被引入合成树脂，特别是可固化的可热固树脂中。 SAP颗粒最优选用含水阻燃溶液水合。在这方面，阻燃溶液可以基本上由单独的水或含有一种或多种水溶性无机阻燃剂的水溶液组成。当SAP颗粒与含水无机阻燃剂溶液水合时，此后可将SAP颗粒干燥以除去基本上水分。以这种方式，无机阻燃剂将保留为物理夹带在SAP颗粒内的干燥残余物。因此，SAP颗粒用作其中无机阻燃剂均匀分散的物理基体。然后可以将SAP颗粒与合成树脂共混，或者可以研磨成更细的颗粒，其含有无机阻燃剂水溶液的干燥残余物，然后与合适的合成树脂混合。

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