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    • 2. 发明授权
    • Production of coated substrates
    • 生产涂层基材
    • US07993707B2
    • 2011-08-09
    • US12092084
    • 2006-08-10
    • Edwin NunHeike BergandtHannelore ArmoneitMarie-Theres WilkesThomas Schrief
    • Edwin NunHeike BergandtHannelore ArmoneitMarie-Theres WilkesThomas Schrief
    • B05D3/02
    • C09D183/06C09D183/04C09D183/08C08L2666/72C08L2666/36C08L2666/34
    • The present invention relates to a process for coating substrates, which comprises the steps: a) provision of a substrate, b) application of a composition to at least one surface of the substrate, the composition comprising a silane of the general formula (Z1)Si(OR3), where Z1 is OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 6 carbon atoms and all radicals R can be identical or different, an inert solvent and an initiator and the inert solvent having a boiling point under the drying conditions of step c) which is in a range from 50° C. above to 50° C. below the drying temperature of step c) and the boiling point of the inert solvent under the drying conditions of step c) being at least 80° C., and c) drying of the composition applied in step b) at a drying temperature of from 100° C. to 250° C., and also to a coated substrate obtainable by means of the abovementioned process.
    • 本发明涉及一种用于涂覆基材的方法,其包括以下步骤:a)提供基材,b)将组合物施用于基材的至少一个表面,所述组合物包含通式(Z1)的硅烷, Si(OR 3),其中Z 1为OR或Gly(Gly = 3-缩水甘油氧基丙基),R为具有1至6个碳原子的烷基,所有基团R可以相同或不同,惰性溶剂和引发剂和惰性 在步骤c)的干燥条件下具有沸点的溶剂在低于步骤c)的干燥温度的50℃以上至50℃的范围内,并且在干燥条件下的惰性溶剂的沸点 步骤c)为至少80℃,和c)在100℃至250℃的干燥温度下干燥步骤b)中所用的组合物,并且还可以通过使用 上述过程。
    • 6. 发明授权
    • Scratch- and abrasion-resistant coatings on polymeric surfaces
    • 聚合物表面上的划痕和耐磨涂层
    • US08940389B2
    • 2015-01-27
    • US12300054
    • 2007-05-09
    • Heike BergandtLiv RandewigMarie-Theres Wilkes
    • Heike BergandtLiv RandewigMarie-Theres Wilkes
    • B32B27/08B05D3/02B05D3/06C09D183/08C09D4/00
    • C09D183/08C09D4/00Y10T428/31507Y10T428/31663C08G77/26
    • The present invention relates to a composition which contains a) at least one reaction product of a1) a silane of the general formula in which Y(1)=3-glycidyloxypropyl-, and R1, R2, R3=like or unlike alkyl groups having 1 to 6 carbon atoms, and a2) a silane of the general formula in which Y(2)=N-2-aminoethyl-3-aminopropyl- or NH2(CH2)2NH(CH2)2NH(CH)3, and R′1, R′2, R′3=like or unlike alkyl groups having 1 to 6 carbon atoms, and b) at least one inorganic filler, and c) a solvent having a boiling point at a temperature ≦85° C., and d) water, and e) a catalyst selected from organic and inorganic acids, to a method of producing a surface coating on a polymeric surface by applying the composition of the invention, and to articles having at least one polymeric surface which have the surface coating of the invention, and to their use.
    • 本发明涉及一种组合物,其含有a)至少一种下列通式的硅烷的反应产物:其中Y(1)= 3-缩水甘油氧基丙基,R1,R2,R3 =相同或不同于具有 1至6个碳原子,和a2)其中Y(2)= N-2-氨基乙基-3-氨基丙基或NH 2(CH 2)2 NH(CH 2)2 NH(CH 3)3和通式 1,R'2,R'3 =类似或不同于具有1至6个碳原子的烷基,以及b)至少一种无机填料,和c)沸点为< nEE; 85℃的溶剂, 和d)水,以及e)选自有机和无机酸的催化剂,通过应用本发明的组合物在聚合物表面上生产表面涂层的方法,以及具有至少一个具有表面的聚合物表面的制品 本发明的涂层及其用途。
    • 7. 发明授权
    • Method for coating substrates
    • 涂布基材的方法
    • US08105656B2
    • 2012-01-31
    • US12092086
    • 2006-10-05
    • Edwin NunHeike BergandtHannelore ArmoneitMarie-Theres WilkesSigrid BankenThomas Schrief
    • Edwin NunHeike BergandtHannelore ArmoneitMarie-Theres WilkesSigrid BankenThomas Schrief
    • B05D3/02
    • D06M11/77B05D7/546C09D183/04C09D183/06D06M11/45D06M11/46D06M11/49D06M11/71D06M11/78D06M11/79D06M11/81D06M11/83D06M13/507D06M13/513Y10T428/31663
    • The present invention relates to a method of coating a substrate, comprising the steps of a) providing a substrate, b) applying a composition to at least one side of the substrate, the composition containing an inorganic compound and the inorganic compound containing at least one metal and/or semimetal selected from the group Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, Tl, Si, Ge, Sn, Zn, Pb, Sb, Bi or a mixture thereof and at least one element selected from the group Te, Se, S, O, Sb, As, P, N, C, Ga or a mixture thereof, c) drying the composition applied in step b), d) applying at least one coating to the at least one side of the substrate to which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, Z1 being R, OR or Gly (Gly is 3-glycidyloxypropyl) and R being an alkyl radical having from 1 to 18 carbon atoms, it being possible for all radicals R to be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or a mixture thereof, a polymer, and an initiator, and e) drying the coating applied in step d), and also to a coated substrate obtainable by the above method.
    • 本发明涉及一种涂覆基材的方法,包括以下步骤:a)提供基材,b)将组合物施用至基材的至少一侧,所述组合物含有无机化合物和含有至少一种 金属和/或半金属选自Sc,Y,Ti,Zr,Nb,V,Cr,Mo,W,Mn,Fe,Co,B,Al,In,Tl,Si,Ge,Sn,Zn,Pb ,Sb,Bi或其混合物和选自Te,Se,S,O,Sb,As,P,N,C,Ga或其混合物中的至少一种元素,c)干燥步骤b ),d)在步骤b)中将至少一个涂层施加到其上施加组合物的基材的至少一侧,所述涂层含有通式(Z1)Si(OR)3的硅烷,Z1为R ,OR或Gly(Gly是3-缩水甘油氧基丙基),R是具有1至18个碳原子的烷基,所有基团R可以相同或不同,选自氧化物的氧化物颗粒 的Ti,Si,Zr,Al,Y,Sn,Zn,Ce或其混合物,聚合物和引发剂,以及e)干燥步骤d)中施加的涂层,以及可以由上述 方法。
    • 8. 发明申请
    • SCRATCH- AND ABRASION-RESISTANT COATINGS ON POLYMERIC SURFACES
    • 聚合物表面的耐刮擦和抗磨损涂层
    • US20090162631A1
    • 2009-06-25
    • US12300054
    • 2007-05-09
    • Heike BergandtLiv RandewigMarie-Theres Wilkes
    • Heike BergandtLiv RandewigMarie-Theres Wilkes
    • B32B27/08B05D3/02B05D3/06
    • C09D183/08C09D4/00Y10T428/31507Y10T428/31663C08G77/26
    • The present invention relates to a composition which contains a) at least one reaction product of a1) a silane of the general formula in which Y(1)=3-glycidyloxypropyl-, and R1, R2, R3=like or unlike alkyl groups having 1 to 6 carbon atoms, and a2) a silane of the general formula in which Y(2)=N-2-aminoethyl-3-aminopropyl- or NH2 (CH2)2NH(CH2)2NH(CH)3, and R′1, R′2, R′3=like or unlike alkyl groups having 1 to 6 carbon atoms, and b) at least one inorganic filler, and c) a solvent having a boiling point at a temperature ≦85° C., and d) water, and e) a catalyst selected from organic and inorganic acids, to a method of producing a surface coating on a polymeric surface by applying the composition of the invention, and to articles having at least one polymeric surface which have the surface coating of the invention, and to their use.
    • 本发明涉及一种组合物,其含有a)至少一种下列通式的硅烷的反应产物:其中Y(1)= 3-缩水甘油氧基丙基,R1,R2,R3 =相同或不同于具有 1至6个碳原子,和a2)其中Y(2)= N-2-氨基乙基-3-氨基丙基或NH 2(CH 2)2 NH(CH 2)2 NH(CH 3)3和通式 1,R'2,R'3 =与具有1至6个碳原子的烷基相似或不同,b)至少一种无机填料,和c)沸点在85℃以下的溶剂, 和d)水,以及e)选自有机和无机酸的催化剂,通过应用本发明的组合物在聚合物表面上生产表面涂层的方法,以及具有至少一个具有表面的聚合物表面的制品 本发明的涂层及其用途。
    • 9. 发明申请
    • Production of Coated Substrates
    • 涂层基材的生产
    • US20080292799A1
    • 2008-11-27
    • US12092084
    • 2006-08-10
    • Edwin NunHeike BergandtHannelore ArmoneitMarie-Theres WilkesThomas Schrief
    • Edwin NunHeike BergandtHannelore ArmoneitMarie-Theres WilkesThomas Schrief
    • B05D3/02
    • C09D183/06C09D183/04C09D183/08C08L2666/72C08L2666/36C08L2666/34
    • The present invention relates to a process for coating substrates, which comprises the steps: a) provision of a substrate, b) application of a composition to at least one surface of the substrate, the composition comprising a silane of the general formula (Z1)Si(OR3), where Z1 is OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 6 carbon atoms and all radicals R can be identical or different, an inert solvent and an initiator and the inert solvent having a boiling point under the drying conditions of step c) which is in a range from 50° C. above to 50° C. below the drying temperature of step c) and the boiling point of the inert solvent under the drying conditions of step c) being at least 80° C., and c) drying of the composition applied in step b) at a drying temperature of from 100° C. to 250° C., and also to a coated substrate obtainable by means of the abovementioned process.
    • 本发明涉及一种用于涂覆基材的方法,其包括以下步骤:a)提供基材,b)将组合物施用于基材的至少一个表面,所述组合物包含通式(Z1)的硅烷, Si(OR 3),其中Z 1为OR或Gly(Gly = 3-缩水甘油氧基丙基),R为具有1至6个碳原子的烷基,所有基团R可以相同或不同,惰性溶剂和引发剂和惰性 在步骤c)的干燥条件下具有沸点的溶剂在低于步骤c)的干燥温度的50℃以上至50℃的范围内,并且在干燥条件下的惰性溶剂的沸点 步骤c)为至少80℃,和c)在100℃至250℃的干燥温度下干燥步骤b)中所用的组合物,并且还可以通过使用 上述过程。
    • 10. 发明申请
    • Method for Coating Substrates
    • 涂层基材的方法
    • US20080280148A1
    • 2008-11-13
    • US12092086
    • 2006-10-05
    • Edwin NunHeike BergandtHannelore ArmoneitMarie-Theres WilkesSigrid BankenThomas Schrief
    • Edwin NunHeike BergandtHannelore ArmoneitMarie-Theres WilkesSigrid BankenThomas Schrief
    • B05D7/00B32B27/14
    • D06M11/77B05D7/546C09D183/04C09D183/06D06M11/45D06M11/46D06M11/49D06M11/71D06M11/78D06M11/79D06M11/81D06M11/83D06M13/507D06M13/513Y10T428/31663
    • The present invention relates to a method of coating a substrate, comprising the steps of a) providing a substrate, b) applying a composition to at least one side of the substrate, the composition containing an inorganic compound and the inorganic compound containing at least one metal and/or semimetal selected from the group Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, TI, Si, Ge, Sn, Zn, Pb, Sb, Bi or a mixture thereof and at least one element selected from the group Te, Se, S, O, Sb, As, P, N, C, Ga or a mixture thereof, c) drying the composition applied in step b), d) applying at least one coating to the at least one side of the substrate to which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, Z1 being R, OR or Gly (Gly is 3-glycidyloxypropyl) and R being an alkyl radical having from 1 to 18 carbon atoms, it being possible for all radicals R to be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or a mixture thereof, a polymer, and an initiator, and e) drying the coating applied in step d), and also to a coated substrate obtainable by the above method.
    • 本发明涉及一种涂覆基材的方法,包括以下步骤:a)提供基材,b)将组合物施用至基材的至少一侧,所述组合物含有无机化合物和含有至少一种 金属和/或半金属选自Sc,Y,Ti,Zr,Nb,V,Cr,Mo,W,Mn,Fe,Co,B,Al,In,TI,Si,Ge,Sn,Zn,Pb ,Sb,Bi或其混合物和选自Te,Se,S,O,Sb,As,P,N,C,Ga或其混合物中的至少一种元素,c)干燥步骤b ),d)在步骤b)中向组合物施加至少一个涂层至所述基材的至少一侧,所述涂层含有通式(Z 1)Si的硅烷 (OR)3,Z 1是R,OR或Gly(Gly是3-缩水甘油氧基丙基),R是具有1至18个碳原子的烷基,它是 所有基团R可能相同或不同,氧化物p 选自Ti,Si,Zr,Al,Y,Sn,Zn,Ce或其混合物的氧化物的物质,聚合物和引发剂,以及e)干燥步骤d)中施加的涂层,以及涂覆 底物可通过上述方法获得。