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1. 发明授权

US08134036B2 Process for liquid phase alkylation 有权
标题翻译：液相烷基化方法
公开(公告)号：US08134036B2
公开(公告)日：2012-03-13
申请号：US12047873
申请日：2008-03-13
申请人： Joseph E. Pelati , James R. Butler , Marcus Ledoux
发明人： Joseph E. Pelati , James R. Butler , Marcus Ledoux
IPC分类号： C07C2/66 , C07C6/12
CPC分类号： C07C2/66 , C07C2523/10 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085 , C07C15/02
摘要： A method for the liquid-phase alkylation of an aromatic substrate is disclosed. A reaction zone has at least one catalyst bed containing a first catalyst modified by the inclusion of a rare earth metal ion.
摘要翻译：公开了一种用于芳族基底的液相烷基化的方法。反应区具有至少一个含有通过包含稀土金属离子而改性的第一催化剂的催化剂床。

2. 发明申请

US20060194992A1 Treatment of alkylation catalyst poisons with dehydrogenation 审中-公开
标题翻译：用脱氢处理烷基化催化剂毒物
公开(公告)号：US20060194992A1
公开(公告)日：2006-08-31
申请号：US11361817
申请日：2006-02-24
申请人： James Butler , Marcus Ledoux , Michael Betbeze
发明人： James Butler , Marcus Ledoux , Michael Betbeze
IPC分类号： C07C2/64
CPC分类号： C07C5/333 , C07C2529/06 , C07C15/46
摘要： Methods and processes for reducing alkylation catalyst poisoning are described herein. Such methods generally include contacting ethylbenzene with a dehydrogenation catalyst to form a dehydrogenation output stream within a dehydrogenation system and passing at least a portion of the dehydrogenation output stream to an alkylation system, wherein the at least a portion of the dehydrogenation output stream contacts an alkylation catalyst. The at least a portion of the dehydrogenation output stream includes a level of impurities resulting from offtest and wherein the level of impurities is sufficiently low to result in essentially no observed effect on the alkylation catalyst life in comparison with an alkylation system feed absent offtest.
摘要翻译：本文描述了用于还原烷基化催化剂中毒的方法和方法。这样的方法通常包括使乙苯与脱氢催化剂接触以在脱氢系统内形成脱氢输出流并将脱氢输出流的至少一部分通入烷基化系统，其中至少部分脱氢输出流接触烷基化催化剂。脱氢输出流的至少一部分包含由最短的杂质产生的杂质水平，并且其中杂质水平足够低以致于与烷基化系统进料相比基本上没有观察到对烷基化催化剂寿命的影响。

3. 发明申请

US20060194991A1 Treatment of alkylation catalyst poisons 审中-公开
标题翻译：烷基化催化剂毒物的处理
公开(公告)号：US20060194991A1
公开(公告)日：2006-08-31
申请号：US11326666
申请日：2006-01-07
申请人： James Butler , Jim Merrill , Marcus Ledoux , Michael Betbeze
发明人： James Butler , Jim Merrill , Marcus Ledoux , Michael Betbeze
IPC分类号： C07C2/00
CPC分类号： C07C2/66 , C07C6/126 , C07C15/073
摘要： Alkylation processes are described herein. The alkylation process generally includes contacting an input stream including benzene with an alkylation catalyst and an alkylating agent to form an alkylation output stream including ethylbenzene. The alkylation process further includes contacting at least a portion of the alkylation output stream with a transalkylation catalyst and a benzene source to form a transalkylation output stream, wherein the benzene source is selected to minimize the amount of alkylation catalyst poisons contacting the alkylation catalyst.
摘要翻译：烷基化方法在本文中描述。烷基化方法通常包括使包含苯的输入流与烷基化催化剂和烷基化剂接触以形成包括乙苯的烷基化输出流。烷基化方法还包括使烷基化输出流的至少一部分与烷基转移催化剂和苯源接触以形成烷基转移输出流，其中选择苯源以使与烷基化催化剂接触的烷基化催化剂毒物的量最小化。

4. 发明授权

US07569738B2 Method and apparatus for addition of aqueous solutions to high temperature processes 失效
标题翻译：用于向高温工艺中加入水溶液的方法和装置
公开(公告)号：US07569738B2
公开(公告)日：2009-08-04
申请号：US12238552
申请日：2008-09-26
申请人： Marcus Ledoux , Jim Butler , Jim Merrill , Clint Persick , Ashley Rabalais
发明人： Marcus Ledoux , Jim Butler , Jim Merrill , Clint Persick , Ashley Rabalais
IPC分类号： C07C5/333
CPC分类号： C07C5/324 , B01J8/02 , B01J8/04 , B01J8/06 , B01J8/18 , B01J19/002 , B01J23/78 , B01J2208/00707 , B01J2219/0004 , C07C5/3335 , C07C2523/04 , C07C2523/745 , Y02P20/52 , C07C15/44 , C07C11/06 , C07C11/167 , C07C15/46
摘要： Methods and systems for extending the life of a dehydrogenation catalyst are described herein. For example, one embodiment includes providing a reaction vessel loaded with a dehydrogenation catalyst with a feedstream via a conduit in operable communication with the reaction vessel. The feedstream may include an alkyl aromatic hydrocarbon and the dehydrogenation catalyst may be adapted to convert the alkyl aromatic hydrocarbon to a vinyl aromatic hydrocarbon. The feedstream may be contacted with an aqueous catalyst life extender, wherein the aqueous catalyst life extender enters the conduit at a linear velocity sufficient to prevent vaporization of the catalyst life extender in the conduit prior to contact with the feedstream.
摘要翻译：本文描述了用于延长脱氢催化剂寿命的方法和系统。例如，一个实施例包括通过与反应容器可操作连通的导管提供装载有脱氢催化剂的反应容器与进料流。进料流可以包括烷基芳族烃，并且脱氢催化剂可以适于将烷基芳族烃转化为乙烯基芳族烃。进料流可以与水性催化剂寿命延长剂接触，其中水性催化剂寿命延长剂以足够的线速度进入导管，以防止在与进料流接触之前导管中催化剂寿命延长剂的蒸发。

5. 发明申请

US20120107199A1 Processes for Reduction of Alkylation Catalyst Deactivation Utilizing Stacked Catalyst Bed 有权
标题翻译：使用堆叠催化剂床减少烷基化催化剂失活的方法
公开(公告)号：US20120107199A1
公开(公告)日：2012-05-03
申请号：US13344390
申请日：2012-01-05
申请人： James Merrill , Marcus Ledoux
发明人： James Merrill , Marcus Ledoux
IPC分类号： B01J8/04
CPC分类号： C07C2/66 , Y02P20/584 , C07C15/02
摘要： Alkylation systems and methods of minimizing alkylation catalyst regeneration are discussed herein. The alkylation systems generally include a preliminary alkylation system adapted to receive an input stream including an alkyl aromatic hydrocarbon and contact the input stream with a first preliminary alkylation catalyst disposed therein to form a first output stream. The first preliminary alkylation catalyst generally includes a Y zeolite. The systems further include a first alkylation system adapted to receive the first output stream and contact the first output stream with a first alkylation catalyst disposed therein and an alkylating agent to form a second output stream.
摘要翻译：本文讨论了使烷基化催化剂再生最小化的烷基化系统和方法。烷基化系统通常包括适于接收包含烷基芳族烃的输入流并将输入流与设置在其中的第一初步烷基化催化剂接触以形成第一输出流的初步烷基化系统。第一初步烷基化催化剂通常包括Y沸石。所述系统还包括适于接收第一输出流并将第一输出流与设置在其中的第一烷基化催化剂接触的第一烷基化系统和烷基化剂以形成第二输出流。

6. 发明申请

US20090149685A1 Treatment of Alkylation Catalyst Poisons with Dehydrogenation 有权
标题翻译：用脱氢处理烷基化催化剂毒物
公开(公告)号：US20090149685A1
公开(公告)日：2009-06-11
申请号：US12327682
申请日：2008-12-03
申请人： James R. Butler , Marcus Ledoux , Michael Betbeze
发明人： James R. Butler , Marcus Ledoux , Michael Betbeze
IPC分类号： C07C2/00
CPC分类号： C07C5/333 , C07C2529/06 , C07C15/46
摘要： Methods and processes for reducing alkylation catalyst poisoning are described herein. Such methods generally include providing a dehydrogenation system including a dehydrogenation reactor and a separation system, wherein the separation system includes a first column and a second column, introducing an alkyl aromatic hydrocarbon into the dehydrogenation reactor, contacting the alkyl aromatic hydrocarbon with a dehydrogenation catalyst disposed within the dehydrogenation reactor to form a dehydrogenation output stream comprising a vinyl aromatic hydrocarbon, passing at least a portion of the dehydrogenation output stream to first column, recovering a first overhead fraction including benzene and a first bottoms fraction from the first column, passing at least a portion of the benzene from the first column to an alkylation system including an alkylation catalyst, passing the first bottoms fraction from the first column to the second column, recovering a second overhead fraction and a second bottoms fraction from the second column, withdrawing offtest from effluent streams selected from the dehydrogenation output stream, the first bottoms fraction, the second bottoms fraction and combinations thereof to form withdrawn offtest and introducing the withdrawn offtest into the separation system downstream from the first column.
摘要翻译：本文描述了用于还原烷基化催化剂中毒的方法和方法。这样的方法通常包括提供包括脱氢反应器和分离系统的脱氢系统，其中分离系统包括第一塔和第二塔，将烷基芳烃引入脱氢反应器中，使烷基芳族烃与脱氢催化剂接触在脱氢反应器内以形成包含乙烯基芳族烃的脱氢输出物流，将至少一部分脱氢输出流送至第一塔，从第一塔回收包括苯和第一塔底馏分的第一塔顶馏分，至少通过从第一塔的一部分苯到包含烷基化催化剂的烷基化体系，将第一塔底馏分从第一塔通到第二塔，从第二塔回收第二塔顶馏分和第二塔底馏分，流出物流选自脱氢输出流，第一塔底馏分，第二塔底馏分及其组合，以形成退出，并将排出的最后馏分引入第一塔下游的分离系统。

7. 发明申请

US20060183953A1 Method and apparatus for addition of aqueous solutions to high temperature processes 审中-公开
公开(公告)号：US20060183953A1
公开(公告)日：2006-08-17
申请号：US11058849
申请日：2005-02-15
申请人： Marcus Ledoux , Jim Butler , Jim Merrill , Clint Persick , Ashley Rabalais
发明人： Marcus Ledoux , Jim Butler , Jim Merrill , Clint Persick , Ashley Rabalais
IPC分类号： C07C2/64 , B01J8/02
CPC分类号： C07C5/324 , B01J8/02 , B01J8/04 , B01J8/06 , B01J8/18 , B01J19/002 , B01J23/78 , B01J2208/00707 , B01J2219/0004 , C07C5/3335 , C07C2523/04 , C07C2523/745 , Y02P20/52 , C07C15/44 , C07C11/06 , C07C11/167 , C07C15/46
摘要： Methods and systems for extending the life of a dehydrogenation catalyst are described herein. For example, one embodiment includes providing a reaction vessel loaded with a dehydrogenation catalyst with a feedstream via a conduit in operable communication with the reaction vessel. The feedstream may include an alkyl aromatic hydrocarbon and the dehydrogenation catalyst may be adapted to convert the alkyl aromatic hydrocarbon to a vinyl aromatic hydrocarbon. The feedstream may be contacted with an aqueous catalyst life extender, wherein the aqueous catalyst life extender enters the conduit at a linear velocity sufficient to prevent vaporization of the catalyst life extender in the conduit prior to contact with the feedstream.

8. 发明授权

US08426662B2 Processes for reduction of alkylation catalyst deactivation utilizing stacked catalyst bed 有权
标题翻译：使用堆叠催化剂床还原烷基化催化剂失活的方法
公开(公告)号：US08426662B2
公开(公告)日：2013-04-23
申请号：US13344390
申请日：2012-01-05
申请人： James T. Merrill , Marcus Ledoux
发明人： James T. Merrill , Marcus Ledoux
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , Y02P20/584 , C07C15/02
摘要： Alkylation systems and methods of minimizing alkylation catalyst regeneration are discussed herein. The alkylation systems generally include a preliminary alkylation system adapted to receive an input stream including an alkyl aromatic hydrocarbon and contact the input stream with a first preliminary alkylation catalyst disposed therein to form a first output stream. The first preliminary alkylation catalyst generally includes a Y zeolite. The systems further include a first alkylation system adapted to receive the first output stream and contact the first output stream with a first alkylation catalyst disposed therein and an alkylating agent to form a second output stream.
摘要翻译：本文讨论了使烷基化催化剂再生最小化的烷基化系统和方法。烷基化系统通常包括适于接收包含烷基芳族烃的输入流并将输入流与设置在其中的第一初步烷基化催化剂接触以形成第一输出流的初步烷基化系统。第一初步烷基化催化剂通常包括Y沸石。所述系统还包括适于接收第一输出流并将第一输出流与设置在其中的第一烷基化催化剂接触的第一烷基化系统和烷基化剂以形成第二输出流。

9. 发明申请

US20110245561A1 Dehydrogenation of Alkyl Aromatics 审中-公开
标题翻译：烷基芳烃脱氢
公开(公告)号：US20110245561A1
公开(公告)日：2011-10-06
申请号：US13158994
申请日：2011-06-13
申请人： James Merrill , Thomas Parenteau , Marcus Ledoux , Mark Gremillion
发明人： James Merrill , Thomas Parenteau , Marcus Ledoux , Mark Gremillion
IPC分类号： C07C5/42
CPC分类号： B01J8/008 , B01J8/0214 , B01J8/0278 , B01J2208/00176 , B01J2208/00371 , B01J2208/00849 , B01J2219/0004 , C07C5/3332 , C07C2523/78 , C07C15/46
摘要： Dehydrogenation of a reactor system of one or more vertically oriented flow reactors equipped with a system for introducing a catalyst extender into the inlet of the reactor. A vertically oriented radial flow reactor comprises inner and outer reactor tubes having perforated wall members extending longitudily of the reactor and defining an annulus containing a dehydrogenation catalyst. A supply line to the reactor is equipped with a rotation vane. An injection nozzle comprising a coaxial flow tube extends into the supply line downstream of the vane. The coaxial flow tube has an interior chamber and an annular chamber surrounding the interior chamber and extending into the supply line along with the interior chamber. The interior chamber is connected to a catalyst extender source and the annular chamber is connected to a source of a carrier gas which is effective to disperse the extender within feedstock flowing into the reactor.
摘要翻译：一个或多个垂直取向的流动反应器的反应器系统的脱氢装备有用于将催化剂增量剂引入反应器入口的系统。垂直取向的径向流动反应器包括内部和外部反应器管，其具有穿过反应器纵向延伸的多孔壁构件并且限定含有脱氢催化剂的环。反应器的供应管路配备有旋转叶片。包括同轴流管的喷嘴延伸到叶片下游的供应管线中。同轴流管具有内部腔室和围绕内部腔室并与内部腔室一起延伸进入供应管线的环形腔室。内部室连接到催化剂延长源，并且环形室连接到载气的源，其有效地将延长剂分散在流入反应器的原料内。

10. 发明申请

US20090234169A1 Process for Liquid Phase Alkylation 有权
标题翻译：液相烷基化方法
公开(公告)号：US20090234169A1
公开(公告)日：2009-09-17
申请号：US12047873
申请日：2008-03-13
申请人： Joseph E. Pelati , James R. Butler , Marcus Ledoux
发明人： Joseph E. Pelati , James R. Butler , Marcus Ledoux
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2523/10 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085 , C07C15/02
摘要： A method for the liquid-phase alkylation of an aromatic substrate is disclosed. A reaction zone has at least one catalyst bed containing a first catalyst modified by the inclusion of a rare earth metal ion.
摘要翻译：公开了一种用于芳族基底的液相烷基化的方法。反应区具有至少一个含有通过包含稀土金属离子而改性的第一催化剂的催化剂床。

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