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    • 1. 发明申请
    • POLYMERISABLE NAPHTHOPYRANE DERIVATIVES AND POLYMER MATERIALS OBTAINED FROM THESE DERIVATIVES
    • 可聚合的萘二甲酰衍生物和从这些衍生物获得的聚合物材料
    • US20100317805A1
    • 2010-12-16
    • US12868500
    • 2010-08-25
    • Sébastien GIBANELJean-Luc POZZOAnne PAGNOUXMarc DOLATKHANI
    • Sébastien GIBANELJean-Luc POZZOAnne PAGNOUXMarc DOLATKHANI
    • C08F34/02C08F265/04C07D311/78
    • C09K9/02C07D311/92C09K2211/1088C09K2211/145
    • The invention relates to novel compounds of formula (I): in which R1, R2 and R3, identical or different, independently represent: hydrogen a halogen a C1 to C15 hydroxy or hydroxyalkyl group a C1 to C15 linear or branched alkyl group a, b and c independently lying between 0 and 5. R4 is linked to the naphthalene unit at position 1, 2 or 3 via a —CH2—O— bond and represents: either a divalent group which is (co)polymerisable with a monomer; in which case d lies between 1 and 3 or a monovalent group which is (co)polymerisable with a monomer; in which case d is equal to 2 or 3 and R5 is linked to the naphthalene unit at position 1, 2 or 3 and represents: hydrogen, a halogen, a C1 to C15 hydroxyalkyl group, a C1 to C15 linear or branched alkyl group, and e is an integer lying between 0 and 2 and such that d+e=3. It also relates to the method for synthesising these compounds and to their use for the manufacture of photochromic or photosensitive polymers.
    • 本发明涉及新的式(I)化合物:其中R 1,R 2和R 3相同或不同,独立地表示:氢,卤素,C 1至C 15羟基或羟烷基,C 1至C 15直链或支链烷基a,b 并且c独立地位于0和5之间.R4通过-CH 2 -O-键与位置1,2或3处的萘单元连接并且表示:与单体可共聚合的二价基团; 在这种情况下d位于1和3之间,或与单体可共聚合的一价基团; 在这种情况下,d等于2或3,R 5在1,2或3位与萘单元连接,代表氢,卤素,C1至C15羟基烷基,C1至C15直链或支链烷基, e是0和2之间的整数,d + e = 3。 它还涉及合成这些化合物的方法及其在制备光致变色或光敏聚合物中的用途。