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1. 发明授权

US08927683B2 Polymerization fluid, method for producing the polymerization fluid, transparent film and transparent electrode made from the polymerization fluid 有权
标题翻译：聚合流体，聚合流体的制造方法，由聚合流体制成的透明膜和透明电极
公开(公告)号：US08927683B2
公开(公告)日：2015-01-06
申请号：US13582282
申请日：2011-03-01
申请人： Mahito Atobe , Koji Nakabayashi , Kenji Machida , Sekihiro Takeda
发明人： Mahito Atobe , Koji Nakabayashi , Kenji Machida , Sekihiro Takeda
IPC分类号： C08G75/00 , H01G9/028 , C08G61/12 , H01B1/12 , H05B33/28 , H01G11/56
CPC分类号： H01G9/028 , C08G61/126 , C08G2261/1424 , C08G2261/3223 , C08G2261/44 , H01B1/127 , H01G11/56 , H05B33/28 , Y02E60/13
摘要： Disclosed is a polymerization fluid for electropolymerization which exhibits a reduced environmental burden and excellent economic efficiency and which can yield a conductive polymer film that has high conductivity and that is dense and highly transparent. The polymerization fluid includes at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes which is dispersed as oil drops in surfactant-free water, and the polymerization fluid is transparent. The polymerization fluid can be produced by a method which includes: an addition step of adding the monomer to surfactant-free water to prepare a phase separation fluid where water and the monomer are phase-separated; a first dispersion step of irradiating the phase separation fluid with ultrasonic waves to make the monomer dispersed in the form of oil drops and thus prepare an opaque dispersion, and a second dispersion step of irradiating the opaque dispersion with ultrasonic waves having a frequency higher than that of the ultrasonic waves used in the first dispersion step to reduce the mean size of the oil drops of the monomer and thus prepare a transparent dispersion.
摘要翻译：公开了用于电聚合的聚合流体，其具有降低的环境负担和优异的经济效率，并且可以产生具有高导电性并且致密和高度透明的导电聚合物膜。聚合流体包括至少一种选自3,4-二取代噻吩的单体，其以油滴分散在不含表面活性剂的水中，聚合流体是透明的。聚合流体可以通过以下方法制备：将单体添加到无表面活性剂的水中以制备其中水和单体相分离的相分离流体的添加步骤; 第一分散步骤，用超声波照射相分离液，使单体以油滴的形式分散，从而制备不透明的分散体;第二分散步骤，用频率高于其的频率的超声波照射不透明分散体。的第一分散步骤中使用的超声波，以减少单体的油滴的平均尺寸，从而制备透明分散体。

2. 发明授权

US09184401B2 Electrode body for solar cell, method for producing the electrode body, and solar cell provided with the electrode body 有权
标题翻译：太阳能电池用电极体，电极体的制造方法以及设置有电极体的太阳能电池
公开(公告)号：US09184401B2
公开(公告)日：2015-11-10
申请号：US14008137
申请日：2012-03-31
申请人： Mahito Atobe , Koji Nakabayashi , Kenji Machida , Sekihiro Takeda
发明人： Mahito Atobe , Koji Nakabayashi , Kenji Machida , Sekihiro Takeda
IPC分类号： H01L51/44 , H01B1/12 , H01B1/20 , H01G9/20 , H01L51/00 , H01L51/42 , H01M14/00
CPC分类号： H01L51/442 , C08G2261/1424 , C08G2261/3223 , C08G2261/792 , C08G2261/91 , H01B1/127 , H01B1/20 , H01G9/20 , H01G9/2004 , H01G9/2022 , H01G9/2031 , H01G9/2059 , H01L51/0006 , H01L51/0021 , H01L51/0037 , H01L51/0086 , H01L51/4226 , H01L51/441 , H01L2251/306 , H01L2251/308 , H01M14/005 , Y02E10/542 , Y02E10/549 , Y02P70/521
摘要： Disclosed is an electrode body for a solar cell, which is capable of being used as a component of both an organic thin-film solar cell and a dye-sensitized solar cell, and has excellent heat resistance. This electrode body for a solar cell is provided with a substrate with a conductive part at least on the surface and a conductive polymer layer located on the conductive part of the substrate, in which the conductive polymer layer includes: a polymer which is obtained by polymerizing a monomer selected from the group consisting of 3,4-disubstituted thiophenes; and an anion as a dopant to the polymer generated from at least one organic non-sulfonate compound having an anion with the molecular weight of 200 or more. Since the anion of the organic non-sulfonate compound is included as a dopant in the conductive polymer layer, the heat resistance of the conductive polymer layer is improved.
摘要翻译：公开了一种用于太阳能电池的电极体，其能够用作有机薄膜太阳能电池和染料敏化太阳能电池的组分，并且具有优异的耐热性。该太阳能电池用电极体具有至少在表面具有导电部的基板和位于基板的导电部的导电性聚合物层，导电性聚合物层中，导电性聚合物层包含：通过聚合而得到的聚合物选自3,4-二取代噻吩的单体; 以及由具有分子量为200以上的阴离子的至少一种有机非磺酸盐化合物生成的聚合物作为聚合物的阴离子。由于在导电聚合物层中包含有机非磺酸盐化合物的阴离子作为掺杂剂，所以导电聚合物层的耐热性得到改善。

3. 发明申请

US20130037411A1 POLYMERIZATION FLUID, METHOD FOR PRODUCING THE POLYMERIZATION FLUID, TRANSPARENT FILM AND TRANSPARENT ELECTRODE MADE FROM THE POLYMERIZATION FLUID 有权
标题翻译：聚合流体，聚合流体生产方法，透明膜和透明电极从聚合流体
公开(公告)号：US20130037411A1
公开(公告)日：2013-02-14
申请号：US13582282
申请日：2011-03-01
申请人： Mahito Atobe , Koji Nakabayashi , Kenji Machida , Sekihiro Takeda
发明人： Mahito Atobe , Koji Nakabayashi , Kenji Machida , Sekihiro Takeda
IPC分类号： C25D9/02 , B32B27/00 , C25D7/00
CPC分类号： H01G9/028 , C08G61/126 , C08G2261/1424 , C08G2261/3223 , C08G2261/44 , H01B1/127 , H01G11/56 , H05B33/28 , Y02E60/13
摘要： Disclosed is a polymerization fluid for electropolymerization which exhibits a reduced environmental burden and excellent economic efficiency and which can yield a conductive polymer film that has high conductivity and that is dense and highly transparent. The polymerization fluid includes at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes which is dispersed as oil drops in surfactant-free water, and the polymerization fluid is transparent. The polymerization fluid can be produced by a method which includes: an addition step of adding the monomer to surfactant-free water to prepare a phase separation fluid where water and the monomer are phase-separated; a first dispersion step of irradiating the phase separation fluid with ultrasonic waves to make the monomer dispersed in the form of oil drops and thus prepare an opaque dispersion, and a second dispersion step of irradiating the opaque dispersion with ultrasonic waves having a frequency higher than that of the ultrasonic waves used in the first dispersion step to reduce the mean size of the oil drops of the monomer and thus prepare a transparent dispersion.
摘要翻译：公开了用于电聚合的聚合流体，其具有降低的环境负担和优异的经济效率，并且可以产生具有高导电性并且致密和高度透明的导电聚合物膜。聚合流体包括至少一种选自3,4-二取代噻吩的单体，其以油滴分散在不含表面活性剂的水中，聚合流体是透明的。聚合流体可以通过以下方法制备：将单体添加到无表面活性剂的水中以制备其中水和单体相分离的相分离流体的添加步骤; 第一分散步骤，用超声波照射相分离液，使单体以油滴的形式分散，从而制备不透明的分散体;第二分散步骤，用频率高于其的频率的超声波照射不透明分散体。的第一分散步骤中使用的超声波，以减少单体的油滴的平均尺寸，从而制备透明分散体。

4. 发明申请

US20140014168A1 ELECTRODE BODY FOR SOLAR CELL, METHOD FOR PRODUCING THE ELECTRODE BODY, AND SOLAR CELL PROVIDED WITH THE ELECTRODE BODY 有权
标题翻译：用于太阳能电池的电极体，用于制造电极体的方法和用电极体提供的太阳能电池
公开(公告)号：US20140014168A1
公开(公告)日：2014-01-16
申请号：US14008137
申请日：2012-03-31
申请人： Mahito Atobe , Koji Nakabayashi , Kenji Machida , Sekihiro Takeda
发明人： Mahito Atobe , Koji Nakabayashi , Kenji Machida , Sekihiro Takeda
IPC分类号： H01L51/44 , H01G9/20 , H01L51/00
CPC分类号： H01L51/442 , C08G2261/1424 , C08G2261/3223 , C08G2261/792 , C08G2261/91 , H01B1/127 , H01B1/20 , H01G9/20 , H01G9/2004 , H01G9/2022 , H01G9/2031 , H01G9/2059 , H01L51/0006 , H01L51/0021 , H01L51/0037 , H01L51/0086 , H01L51/4226 , H01L51/441 , H01L2251/306 , H01L2251/308 , H01M14/005 , Y02E10/542 , Y02E10/549 , Y02P70/521
摘要： Disclosed is an electrode body for a solar cell, which is capable of being used as a component of both an organic thin-film solar cell and a dye-sensitized solar cell, and has excellent heat resistance. This electrode body for a solar cell is provided with a substrate with a conductive part at least on the surface and a conductive polymer layer located on the conductive part of the substrate, in which the conductive polymer layer includes: a polymer which is obtained by polymerizing a monomer selected from the group consisting of 3,4-disubstituted thiophenes; and an anion as a dopant to the polymer generated from at least one organic non-sulfonate compound having an anion with the molecular weight of 200 or more. Since the anion of the organic non-sulfonate compound is included as a dopant in the conductive polymer layer, the heat resistance of the conductive polymer layer is improved.
摘要翻译：公开了一种用于太阳能电池的电极体，其能够用作有机薄膜太阳能电池和染料敏化太阳能电池的组分，并且具有优异的耐热性。该太阳能电池用电极体具有至少在表面具有导电部的基板和位于基板的导电部的导电性聚合物层，导电性聚合物层中，导电性聚合物层包含：通过聚合而得到的聚合物选自3,4-二取代噻吩的单体; 以及由具有分子量为200以上的阴离子的至少一种有机非磺酸盐化合物生成的聚合物作为聚合物的阴离子。由于在导电聚合物层中包含有机非磺酸盐化合物的阴离子作为掺杂剂，所以导电聚合物层的耐热性得到改善。

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