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1. 发明授权

US12071507B2 Method and composition for improving adhesion of metathesis compositions to substrates 有权
公开(公告)号：US12071507B2
公开(公告)日：2024-08-27
申请号：US15955876
申请日：2018-04-18
申请人： MATERIA, INC.
发明人： Anthony R. Stephen , Christopher J. Cruce , Mark S. Trimmer , Michael A. Giardello
IPC分类号： C08G61/02 , B29B15/12 , C03C17/32 , C03C25/30 , C08G61/08 , C08J5/04 , C08K3/36 , C08K3/40 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08K7/14 , C08K7/28 , C08L65/00 , C09D165/00 , B29K309/08
CPC分类号： C08G61/02 , B29B15/122 , C03C17/328 , C03C25/30 , C08G61/08 , C08J5/043 , C08K3/36 , C08K3/40 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08K7/14 , C08K7/28 , C08L65/00 , C09D165/00 , B29K2309/08 , C08G2261/3325 , C08G2261/964 , C08J2323/20 , C08L65/00 , C08K5/5419 , C08K5/14 , C08L65/00 , C08K5/5425 , C08K5/14 , C08L65/00 , C08K5/5425 , C08K5/14 , C08K3/36 , C08K3/40 , C08L65/00 , C08K5/5425 , C08K5/14 , C08K3/40 , C08L65/00 , C08K5/5425 , C08K5/14 , C08K7/14 , C08L65/00 , C08K5/5425 , C08K5/14 , C08K3/36 , C08K7/28
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

2. 发明申请

US20210347935A1 POLYMERS FOR SPECIALTY APPLICATIONS 有权
公开(公告)号：US20210347935A1
公开(公告)日：2021-11-11
申请号：US17280991
申请日：2019-10-03
申请人： MATERIA, INC.
发明人： Jennifer A. BEERMAN , Alexandria K. DUNCAN , Brian D. EDGECOMBE , Kristina GOULINIAN , Jessica R. HERRON , John H. PHILLIPS
IPC分类号： C08G61/08 , B01J31/22
摘要： The invention relates to ring-opening metathesis polymerization (ROMP) reactions of making polymers suitable for the electronic industry. Particularly, the invention relates to novel polymers with low dielectric constant (Dk) and low dielectric loss (Df) suited for smaller, lighter, higher speeds and higher frequency transmission electronic products. Such polymers can be used in a variety of materials and composites of the printed circuit board (PCB) industry.

3. 发明申请

US20170166714A1 ADHESION PROMOTER COMPOSITIONS FOR CYCLIC OLEFIN RESIN COMPOSITIONS 审中-公开
公开(公告)号：US20170166714A1
公开(公告)日：2017-06-15
申请号：US15120554
申请日：2015-02-25
申请人： MATERIA, INC.
发明人： Christopher J. CRUCE , Brian EDGECOMBE , Paul W. BOOTHE , Michael A. GIARDELLO
IPC分类号： C08J5/10 , C08K5/29 , C08K5/101 , C08G61/08
CPC分类号： C08J5/10 , C08G18/6715 , C08G18/672 , C08G61/08 , C08G2261/3324 , C08G2261/3325 , C08G2261/418 , C08J5/24 , C08J2345/00 , C08K5/101 , C08K5/29 , C08L65/00
摘要： This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the adhesion of ROMP compositions to substrate materials using an adhesion promoter composition, where the adhesion promoter composition comprises a pre-reacted mixture comprising at least one compound containing at least two isocyanate groups and at least one compound comprising a heteroatom-containing functional group and a metathesis active olefin, where the adhesion promoter composition is storage stable and/or possesses in-resin storage stability when added to a resin composition, particularly a cyclic olefin resin composition, such as a ROMP composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

4. 发明申请

US20170130089A1 METHOD AND COMPOSITION FOR IMPROVING ADHESION OF METATHESIS COMPOSITIONS TO SUBSTRATES 审中-公开
公开(公告)号：US20170130089A1
公开(公告)日：2017-05-11
申请号：US15413703
申请日：2017-01-24
申请人： MATERIA, INC.
发明人： Anthony R. STEPHEN , Christopher J. CRUCE , Mark S. TRIMMER , Michael A. GIARDELLO
IPC分类号： C09D143/00
CPC分类号： C09D143/00 , C09D143/04
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

5. 发明申请

US20170066869A1 THERMAL INSULATION 审中-公开
标题翻译：热绝缘
公开(公告)号：US20170066869A1
公开(公告)日：2017-03-09
申请号：US15122860
申请日：2014-12-23
申请人： MATERIA, INC.
发明人： Christopher J. CRUCE , Michael A. GIARDELLO , Brian L. CONLEY , Anthony R. STEPHEN
IPC分类号： C08G61/02 , F16L59/02 , F16L59/20 , C09D165/00
摘要： The present invention is directed to addressing one or more of the aforementioned concerns and relates to thermal insulation materials and thermal insulation material compositions and methods for thermally insulating pipelines and associated equipment, structures, and objects used in offshore drilling. The present invention is directed to articles of manufacture comprising the thermal insulation materials and/or thermal insulation material compositions of the invention. More particularly the present invention relates to the use of ring opening metathesis polymerization polymers (ROMP polymers) and/or ROMP polymer composites for thermally insulating pipelines and associated equipment, structures, and objects used in offshore oil drilling.
摘要翻译：本发明涉及解决上述问题中的一个或多个，并且涉及隔热材料和绝热材料组合物和用于隔热管道及相关设备，结构和用于海上钻井中的物体的方法。本发明涉及包含本发明的隔热材料和/或绝热材料组合物的制品。更具体地说，本发明涉及开环易位聚合聚合物（ROMP聚合物）和/或ROMP聚合物复合材料用于隔热管道和相关设备，结构和用于海上石油钻井中的物体的用途。

6. 发明授权

US09339805B2 Catalyst complex with carbene ligand 有权
公开(公告)号：US09339805B2
公开(公告)日：2016-05-17
申请号：US14481401
申请日：2014-09-09
申请人： MATERIA, INC.
发明人： Steven P. Nolan , Jinkun Huang
IPC分类号： C07F15/00 , B01J31/16 , B01J31/24 , B01J31/22 , C07C6/04 , C07C67/30 , C07D207/46 , C07D223/04 , C07D225/02 , C07D313/00 , C07D498/04
CPC分类号： B01J31/2278 , B01J31/2265 , B01J31/2273 , B01J31/2295 , B01J31/2404 , B01J2231/10 , B01J2231/4205 , B01J2231/54 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/04 , C07C67/30 , C07C2531/22 , C07D207/46 , C07D223/04 , C07D225/02 , C07D313/00 , C07D498/04 , C07F15/00 , C07F15/002 , C07F15/0046
摘要： Catalytic complexes including a metal atom having anionic ligands, at least one nucleophilic carbene ligand, and an alkylidene, vinylidene, or allenylidene ligand. The complexes are highly stable to air, moisture and thermal degradation. The complexes are designed to efficiently carry out a variety of olefin metathesis reactions.

7. 发明授权

US09238709B2 Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand 有权
标题翻译：含有N-杂环卡宾配体的潜在的高活性烯烃复分解催化剂
公开(公告)号：US09238709B2
公开(公告)日：2016-01-19
申请号：US14497387
申请日：2014-09-26
申请人： MATERIA, INC. , CALIFORNIA INSTITUTE OF TECHNOLOGY
发明人： Thay Ung , Yann Schrodi , Mark S. Trimmer , Andrew Hejl , Daniel Sanders , Robert H. Grubbs
IPC分类号： C08F132/08 , C07C67/333 , B01J31/22 , C08G61/02 , C07F15/00 , C08G61/06 , C07D493/10
CPC分类号： C08G61/02 , C07C67/333 , C07D493/10 , C07F15/0046 , C08F132/08 , C08G61/06 , C08G2261/11 , C08G2261/3325 , C08G2261/418
摘要： The invention provides novel organometallic complexes useful as olefin metathesis catalysts. The complexes have an N-heterocyclic carbene ligand and a chelating carbene ligand associated with a Group 8 transition metal center. The molecular structure of the complexes can be altered so as to provide a substantial latency period. The complexes are particularly useful in catalyzing ring closing metathesis of acyclic olefins and ring opening metathesis polymerization of cyclic olefins.
摘要翻译：本发明提供了用作烯烃复分解催化剂的新型有机金属络合物。络合物具有与8族过渡金属中心相关的N-杂环卡宾配体和螯合卡宾配体。可以改变配合物的分子结构，以便提供大量潜伏期。该络合物特别可用于催化环烯烃的闭环复分解和环烯烃的开环易位聚合。

8. 发明公开

US20240018298A1 OLEFINIC COMPOSITIONS COMPRISING HYDROCARBON RESINS 审中-公开
公开(公告)号：US20240018298A1
公开(公告)日：2024-01-18
申请号：US18041484
申请日：2021-08-12
申请人： MATERIA, INC.
发明人： Brian EDGECOMBE , Ashley ZUZEK
IPC分类号： C08G61/08 , C09D165/00 , C09J165/00 , C08L65/00
CPC分类号： C08G61/08 , C09D165/00 , C09J165/00 , C08L65/00 , C08G2261/124 , C08G2261/1424 , C08G2261/1426 , C08G2261/1432 , C08G2261/144 , C08G2261/3324 , C08G2261/418 , C08G2261/45
摘要： The invention relates to compositions comprising at least one cyclic olefin monomer, optionally at least one linear olefin monomer, at least one thermoplastic hydrocarbon resin, and at least one olefin metathesis catalyst. The invention also relates to articles of manufacture made from the compositions of the invention, and methods of making the articles. The invention also relates to coating compositions comprising the compositions of the invention, and to objects or substrates coated with the coating compositions of the invention, which may then be cured. The invention also relates to methods of coating the objects or substrates with the coating compositions of the invention. The invention further relates to the use of the compositions of the invention as adhesives.

9. 发明申请

US20210403654A1 ADHESION PROMOTER COMPOSITIONS FOR CYCLIC OLEFIN RESIN COMPOSITIONS 有权
公开(公告)号：US20210403654A1
公开(公告)日：2021-12-30
申请号：US17164095
申请日：2021-02-01
申请人： MATERIA, INC.
发明人： Christopher J. CRUCE , Brian EDGECOMBE , Paul W. BOOTHE , Michael A. GIARDELLO
IPC分类号： C08J5/10 , C08L65/00 , C08G18/67 , C08J5/24 , C08G61/08 , C08K5/101 , C08K5/29
摘要： This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the adhesion of ROMP compositions to substrate materials using an adhesion promoter composition, where the adhesion promoter composition comprises a pre-reacted mixture comprising at least one compound containing at least two isocyanate groups and at least one compound comprising a heteroatom-containing functional group and a metathesis active olefin, where the adhesion promoter composition is storage stable and/or possesses in-resin storage stability when added to a resin composition, particularly a cyclic olefin resin composition, such as a ROMP composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

10. 发明授权

US10344118B2 Romp polymers having improved resistance to hydrocarbon fluids 有权
公开(公告)号：US10344118B2
公开(公告)日：2019-07-09
申请号：US15547930
申请日：2016-02-11
申请人： MATERIA, INC.
发明人： Daryl P. Allen , Christopher J. Cruce , James J. Danford
IPC分类号： C08G61/02 , C08G61/08 , C08K5/13 , C08K5/14
摘要： The present invention relates to compositions comprising at least one cyclic olefin, at least one metal carbene olefin metathesis catalyst, and dicumyl peroxide. The present invention relates to a method of making ROMP polymers and articles of manufacture with improved resistance to hydrocarbon fluids. Particularly the invention relates to ROMP polymer compositions with improved resistance to hydrocarbon fluids. Such ROMP polymers and ROMP polymer compositions can be used in a variety of materials and composite applications.

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