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1. 发明授权

US08828573B2 Electrode structures for aqueous electrolyte lithium sulfur batteries 有权
标题翻译：电解液锂电池电极结构
公开(公告)号：US08828573B2
公开(公告)日：2014-09-09
申请号：US13440847
申请日：2012-04-05
申请人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz , Lutgard C. De Jonghe , Nikolay Goncharenko , Valentina Loginova
发明人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz , Lutgard C. De Jonghe , Nikolay Goncharenko , Valentina Loginova
IPC分类号： H01M4/38 , H01M4/40 , H01M4/58 , H01M10/36
CPC分类号： H01M4/38 , H01M4/382 , H01M4/405 , H01M4/5815 , H01M10/36 , H01M2200/10 , H01M2200/20 , Y02E60/12 , Y10T29/49108
摘要： Provided are lithium sulfur battery cells that use water as an electrolyte solvent. In various embodiments the water solvent enhances one or more of the following cell attributes: energy density, power density and cycle life. Significant cost reduction can also be realized by using an aqueous electrolyte in combination with a sulfur cathode. For instance, in applications where cost per Watt-Hour (Wh) is paramount, such as grid storage and traction applications, the use of an aqueous electrolyte in combination with inexpensive sulfur as the cathode active material can be a key enabler for the utility and automotive industries, providing a cost effective and compact solution for load leveling, electric vehicles and renewable energy storage.
摘要翻译：提供使用水作为电解质溶剂的锂硫电池。在各种实施方案中，水溶剂增强以下电池属性中的一个或多个：能量密度，功率密度和循环寿命。通过使用与硫阴极组合的水性电解质也可以实现显着的成本降低。例如，在瓦特成本（Wh）至关重要的应用中，例如电网储存和牵引应用，使用含水电解质与廉价硫作为阴极活性材料可以成为实用和关键的关键因素，汽车行业，为负载均衡，电动汽车和可再生能源存储提供了成本效益和紧凑的解决方案。

2. 发明授权

US08658304B2 Catholytes for aqueous lithium/air battery cells 有权
标题翻译：阴极电解液用于锂/空气电池电池
公开(公告)号：US08658304B2
公开(公告)日：2014-02-25
申请号：US13663224
申请日：2012-10-29
申请人： Steven J. Visco , Lutgard C. De Jonghe , Yevgeniy S. Nimon , Alexei Petrov , Kirill Pridatko
发明人： Steven J. Visco , Lutgard C. De Jonghe , Yevgeniy S. Nimon , Alexei Petrov , Kirill Pridatko
IPC分类号： H01M10/12 , H01M6/04 , H01M4/36 , H01M4/48 , H01M2/16 , H01M2/18 , H01M4/13 , H01M4/58 , H01M10/0562 , H01M6/18
CPC分类号： H01M2/1673 , H01M4/382 , H01M6/04 , H01M6/045 , H01M8/08 , H01M12/02 , H01M12/04 , H01M12/06 , Y10T29/49108
摘要： Li/air battery cells are configurable to achieve very high energy density. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. In addition to the aqueous catholyte, components of the cathode compartment include an air cathode (e.g., oxygen electrode) and a variety of other possible elements.
摘要翻译： Li /空气电池单元可配置为实现非常高的能量密度。电池包括在阴极室中的受保护的锂金属或合金阳极和含水阴极电解液。除了水性阴极电解液之外，阴极室的部件还包括空气阴极（例如氧气电极）和各种其它可能的元件。

3. 发明申请

US20130344397A1 SUBSTANTIALLY IMPERVIOUS LITHIUM SUPER ION CONDUCTING MEMBRANES 有权
标题翻译：极大的锂离子超导离子膜
公开(公告)号：US20130344397A1
公开(公告)日：2013-12-26
申请号：US13673789
申请日：2012-11-09
申请人： Steven J. Visco , Lutgard C. De Jonghe , Yevgeniy S. Nimon
发明人： Steven J. Visco , Lutgard C. De Jonghe , Yevgeniy S. Nimon
IPC分类号： H01M10/056 , H01M10/052
CPC分类号： H01M10/056 , H01B1/122 , H01M2/1673 , H01M4/04 , H01M4/0416 , H01M4/08 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/139 , H01M4/242 , H01M4/32 , H01M4/38 , H01M4/383 , H01M4/385 , H01M4/387 , H01M4/62 , H01M4/86 , H01M6/04 , H01M6/16 , H01M6/181 , H01M6/185 , H01M6/188 , H01M6/24 , H01M6/34 , H01M8/08 , H01M10/052 , H01M10/0561 , H01M10/0566 , H01M12/04 , H01M12/06 , H01M12/08 , H01M2004/027 , H01M2300/0005 , H01M2300/0017 , H01M2300/0065 , H01M2300/0068 , H01M2300/0071 , H01M2300/0082 , H01M2300/0085 , H01M2300/0091 , Y02E60/128
摘要： A composite solid electrolyte includes a monolithic solid electrolyte base component that is a continuous matrix of an inorganic active metal ion conductor and a filler component used to eliminate through porosity in the solid electrolyte. In this way a solid electrolyte produced by any process that yields residual through porosity can be modified by the incorporation of a filler to form a substantially impervious composite solid electrolyte and eliminate through porosity in the base component. Methods of making the composites are also disclosed. The composites are generally useful in electrochemical cell structures such as battery cells and in particular protected active metal anodes, particularly lithium anodes, that are protected with a protective membrane architecture incorporating the composite solid electrolyte. The protective architecture prevents the active metal of the anode from deleterious reaction with the environment on the other (cathode) side of the architecture, which may include aqueous, air and organic liquid electrolytes and/or electrochemically active materials.
摘要翻译：复合固体电解质包括作为无机活性金属离子导体的连续基体和用于消除固体电解质中的孔隙率的填充剂组分的整体式固体电解质基底组分。以这种方式，可以通过引入填料以形成基本上不可渗透的复合固体电解质并通过基础组分中的孔隙度来消除通过产生残余孔隙率的任何方法产生的固体电解质。还公开了制备复合材料的方法。复合材料通常可用于电化学电池结构，例如电池单元，特别是保护性活性金属阳极，特别是锂阳极，其被保护膜结构保护，并结合复合固体电解质。保护结构防止阳极的活性金属与结构的另一（阴极）侧的环境有害的反应，其可以包括水性，空气和有机液体电解质和/或电化学活性材料。

4. 发明申请

US20120325678A1 STRUCTURES AND FABRICATION TECHNIQUES FOR SOLID STATE ELECTROCHEMICAL DEVICES 审中-公开
标题翻译：固态电化学装置的结构和制造技术
公开(公告)号：US20120325678A1
公开(公告)日：2012-12-27
申请号：US13599362
申请日：2012-08-30
申请人： Steven J. Visco , Craig P. Jacobson , Lutgard C. De Jonghe
发明人： Steven J. Visco , Craig P. Jacobson , Lutgard C. De Jonghe
IPC分类号： C25B1/02 , C25B9/16
CPC分类号： H01M4/8885 , B01D53/326 , B01D2257/108 , C25B9/00 , H01M4/9025 , H01M4/9033 , H01M4/905 , H01M4/9066 , H01M8/004 , H01M8/1213 , H01M8/1226 , H01M8/1231 , H01M8/1246 , H01M8/1253 , H01M8/126 , H01M8/1266 , H01M8/2425 , H01M8/243 , H01M8/2483 , H01M2008/1293 , H01M2300/0074 , Y02E60/525 , Y02P70/56 , Y10T29/49115
摘要： Porous substrates and associated structures for solid-state electrochemical devices, such as solid-oxide fuel cells (SOFCs), are low-cost, mechanically strong and highly electronically conductive. Some preferred structures have a thin layer of an electrocatalytically active material (e.g., Ni-YSZ) coating a porous high-strength alloy support (e.g., SS-430) to form a porous SOFC fuel electrode. Electrode/electrolyte structures can be formed by co-firing or constrained sintering processes.
摘要翻译：用于固态电化学装置（例如固体氧化物燃料电池（SOFC））的多孔基材和相关结构是低成本，机械强度和高电子导电性的。一些优选的结构具有涂覆多孔高强度合金载体（例如SS-430）的电催化活性材料（例如，Ni-YSZ）的薄层，以形成多孔SOFC燃料电极。电极/电解质结构可以通过共烧或约束烧结工艺形成。

5. 发明授权

US08334075B2 Substantially impervious lithium super ion conducting membranes 有权
标题翻译：基本不渗透的锂超离子导电膜
公开(公告)号：US08334075B2
公开(公告)日：2012-12-18
申请号：US13453964
申请日：2012-04-23
申请人： Steven J. Visco , Lutgard C. De Jonghe , Yevgeniy S. Nimon
发明人： Steven J. Visco , Lutgard C. De Jonghe , Yevgeniy S. Nimon
IPC分类号： H01M4/13
CPC分类号： H01M10/056 , H01B1/122 , H01M2/1673 , H01M4/04 , H01M4/0416 , H01M4/08 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/139 , H01M4/242 , H01M4/32 , H01M4/38 , H01M4/383 , H01M4/385 , H01M4/387 , H01M4/62 , H01M4/86 , H01M6/04 , H01M6/16 , H01M6/181 , H01M6/185 , H01M6/188 , H01M6/24 , H01M6/34 , H01M8/08 , H01M10/052 , H01M10/0561 , H01M10/0566 , H01M12/04 , H01M12/06 , H01M12/08 , H01M2004/027 , H01M2300/0005 , H01M2300/0017 , H01M2300/0065 , H01M2300/0068 , H01M2300/0071 , H01M2300/0082 , H01M2300/0085 , H01M2300/0091 , Y02E60/128
摘要： A composite solid electrolyte includes a monolithic solid electrolyte base component that is a continuous matrix of an inorganic active metal ion conductor and a filler component used to eliminate through porosity in the solid electrolyte. In this way a solid electrolyte produced by any process that yields residual through porosity can be modified by the incorporation of a filler to form a substantially impervious composite solid electrolyte and eliminate through porosity in the base component. Such composites may be made by disclosed techniques. The composites are generally useful in electrochemical cell structures such as battery cells and in particular protected active metal anodes, particularly lithium anodes, that are protected with a protective membrane architecture incorporating the composite solid electrolyte.
摘要翻译：复合固体电解质包括作为无机活性金属离子导体的连续基体和用于消除固体电解质中的孔隙率的填充剂组分的整体式固体电解质基底组分。以这种方式，可以通过引入填料以形成基本上不可渗透的复合固体电解质并通过基础组分中的孔隙度来消除通过产生残余孔隙率的任何方法产生的固体电解质。这样的复合材料可以通过公开的技术制成。复合材料通常可用于电化学电池结构，例如电池单元，特别是保护性活性金属阳极，特别是锂阳极，其被保护膜结构保护，并结合复合固体电解质。

6. 发明申请

US20120094194A1 LITHIUM/SULFUR BATTERY WITH HERMETICALLY SEALED ANODE 有权
标题翻译：锂/硫电池具有密封阳极阳极
公开(公告)号：US20120094194A1
公开(公告)日：2012-04-19
申请号：US13333886
申请日：2011-12-21
申请人： Steven J. Visco , Yevgeniy S. Nimon , Lutgard C. De Jonghe , Bruce D. Katz , Alexei Petrov
发明人： Steven J. Visco , Yevgeniy S. Nimon , Lutgard C. De Jonghe , Bruce D. Katz , Alexei Petrov
IPC分类号： H01M10/0564 , H01M4/13
CPC分类号： H01M4/76 , H01M4/02 , H01M4/13 , H01M4/134 , H01M4/366 , H01M6/34 , H01M10/052 , H01M12/02 , H01M12/06
摘要： Protected anode architectures for active metal anodes have a polymer adhesive seal that provides an hermetic enclosure for the active metal of the protected anode inside an anode compartment. The compartment is substantially impervious to ambient moisture and battery components such as catholyte (electrolyte about the cathode), and prevents volatile components of the protected anode, such as anolyte (electrolyte about the anode), from escaping. The architecture is formed by joining the protected anode to an anode container. The polymer adhesive seals provide an hermetic seal at the joint between a surface of the protected anode and the container.
摘要翻译：用于活性金属阳极的受保护阳极结构具有聚合物粘合剂密封件，其为阳极室内的受保护阳极的活性金属提供密封外壳。隔室基本上不受环境湿度的影响，电池组件如阴极电解液（电解液围绕阴极），并防止受保护阳极的挥发性成分，如阳极电解液（阳极电解液）逸出。该结构通过将受保护的阳极接合到阳极容器而形成。聚合物粘合剂密封件在受保护阳极的表面和容器之间的接合处提供气密密封。

7. 发明授权

US07998626B2 Active metal fuel cells 失效
标题翻译：活性金属燃料电池
公开(公告)号：US07998626B2
公开(公告)日：2011-08-16
申请号：US12831066
申请日：2010-07-06
申请人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz , Lutgard C. De Jonghe
发明人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz , Lutgard C. De Jonghe
IPC分类号： H01M4/02 , H01M12/04 , H01M12/06 , H01M12/08
CPC分类号： H01M12/04 , H01M2/1646 , H01M4/40 , H01M12/08 , H01M16/003 , Y02E60/128 , Y02P90/40
摘要： Active metal fuel cells are provided. An active metal fuel cell has a renewable active metal (e.g., lithium) anode and a cathode structure that includes an electronically conductive component (e.g., a porous metal or alloy), an ionically conductive component (e.g., an electrolyte), and a fluid oxidant (e.g., air, water or a peroxide or other aqueous solution). The pairing of an active metal anode with a cathode oxidant in a fuel cell is enabled by an ionically conductive protective membrane on the surface of the anode facing the cathode.
摘要翻译：提供了活性金属燃料电池。活性金属燃料电池具有可再生活性金属（例如，锂）阳极和包括电子导电组分的阴极结构（例如，多孔金属或合金），离子导电部件（例如，电解质），以及一个流体氧化剂（例如，空气，水或过氧化物或其它水溶液）。用在燃料电池的阴极的氧化剂的活性金属阳极的配对是由面向阴极的阳极的表面上的离子导电保护膜启用。

8. 发明授权

US07901837B2 Structures for dense, crack free thin films 失效
标题翻译：密集，无裂纹薄膜的结构
公开(公告)号：US07901837B2
公开(公告)日：2011-03-08
申请号：US11567056
申请日：2006-12-05
申请人： Craig P. Jacobson , Steven J. Visco , Lutgard C. De Jonghe
发明人： Craig P. Jacobson , Steven J. Visco , Lutgard C. De Jonghe
IPC分类号： H01M8/10
CPC分类号： C04B38/0038 , B01D53/326 , B01D2257/108 , C04B35/016 , C04B2111/00801 , C04B2111/00853 , C25B9/00 , H01M4/9025 , H01M4/9033 , H01M4/9066 , H01M8/1213 , H01M8/1226 , H01M8/1231 , H01M8/124 , H01M8/1246 , H01M8/1253 , H01M8/126 , H01M8/1266 , H01M8/1286 , H01M8/2425 , H01M8/243 , H01M2008/1293 , H01M2300/0074 , Y02E60/525 , Y02P70/56 , C04B38/0054 , C04B38/0074
摘要： The process described herein provides a simple and cost effective method for making crack free, high density thin ceramic film. The steps involve depositing a layer of a ceramic material on a porous or dense substrate. The deposited layer is compacted and then the resultant laminate is sintered to achieve a higher density than would have been possible without the pre-firing compaction step.
摘要翻译：本文所述的方法提供了制造无裂纹的高密度薄陶瓷膜的简单且成本有效的方法。这些步骤包括在多孔或致密基底上沉积陶瓷材料层。沉积层被压实，然后将所得的层压体烧结以实现比没有预烧结压实步骤可能的密度更高的密度。

9. 发明申请

US20100038012A1 JOINED CONCENTRIC TUBES 有权
标题翻译：连接集中管
公开(公告)号：US20100038012A1
公开(公告)日：2010-02-18
申请号：US12304191
申请日：2006-07-28
申请人： Michael C. Tucker , Craig P. Jacobson , Steven J. Visco , Lutgard C. De Jonghe
发明人： Michael C. Tucker , Craig P. Jacobson , Steven J. Visco , Lutgard C. De Jonghe
IPC分类号： B29C65/02 , F16L9/14
CPC分类号： B22F5/106 , B22F7/004 , B22F7/062 , H01M8/004 , H01M8/0252 , H01M8/0297 , H01M8/1213 , H01M8/243 , H01M2008/1293 , Y02P70/56
摘要： Tubular objects having two or more concentric layers that have different properties are joined to one another during their manufacture primarily by compressive and friction forces generated by shrinkage during sintering and possibly mechanical interlocking. It is not necessary for the concentric tubes to display adhesive-, chemical- or sinter-bonding to each other in order to achieve a strong bond. This facilitates joining of dissimilar materials, such as ceramics and metals.
摘要翻译：具有不同性质的具有两个或更多个同心层的管状物体在其制造期间彼此接合，主要是通过在烧结期间收缩和可能的机械互锁而产生的压缩和摩擦力。同心圆管不需要彼此粘合，化学或烧结，以达到很好的粘结。这有助于不同材料如陶瓷和金属的接合。

10. 发明申请

US20080193803A1 Precursor Infiltration and Coating Method 审中-公开
标题翻译：前体渗透和涂层方法
公开(公告)号：US20080193803A1
公开(公告)日：2008-08-14
申请号：US11911959
申请日：2006-04-21
申请人： Tal Z. Sholklapper , Craig P. Jacobson , Steven J. Visco , Lutgard C. De Jonghe
发明人： Tal Z. Sholklapper , Craig P. Jacobson , Steven J. Visco , Lutgard C. De Jonghe
IPC分类号： H01M4/00 , B05D3/02 , B05D5/12 , C25B11/04 , B05D7/22
CPC分类号： H01M4/8621 , H01M4/8652 , H01M4/8885
摘要： A method of forming a composite (e.g., a mixed electrode) by infiltration of a porous structure (e.g., one formed from an ionically conductive material) with a solution of a precursor (e.g., for an electronically conductive material) results in a particulate layer on and within the porous structure with a single infiltration. The method involves forming a solution comprising at least one metal salt and a surfactant; heating the solution to substantially evaporate solvent and form a concentrated salt and surfactant solution; infiltrating the concentrated solution into a porous structure to create a composite; and heating the composite to substantially decompose the salt and surfactant to oxide and/or metal particles. The result is a particulate layer on the pore walls of the porous structure. In some instances the particulate layer is a continuous network. Corresponding devices have improved properties and performance.
摘要翻译：通过用前体（例如，用于电子导电材料）的溶液渗透多孔结构（例如由离子导电材料形成的多孔结构）形成复合材料（例如，混合电极）的方法导致颗粒层在多孔结构内部和内部具有单次渗透。该方法包括形成包含至少一种金属盐和表面活性剂的溶液; 加热溶液以使溶剂基本蒸发并形成浓盐和表面活性剂溶液; 将浓缩溶液渗透到多孔结构中以产生复合材料; 并加热复合物以将盐和表面活性剂基本上分解成氧化物和/或金属颗粒。结果是多孔结构的孔壁上的颗粒层。在某些情况下，颗粒层是连续的网络。对应的设备具有改进的性能和性能。

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