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    • 2. 发明授权
    • Coated films and coating compositions comprising biopolymer nanoparticles
    • 包覆生物聚合物纳米粒子的涂膜和涂料组合物
    • US07452592B2
    • 2008-11-18
    • US10416274
    • 2001-11-12
    • Lucy Cowton
    • Lucy Cowton
    • B32B5/16
    • C08J7/047C08J2403/00Y10T428/25Y10T428/253Y10T428/254
    • There is described a substantially planar self-supporting sheet (preferably an thermoplastic film e.g. formed from a polyolefin such as BOPP) comprising on at least one side thereof a substantially continuous adherent coating, thereon to create a barrier to oxygen, the coating comprising nano-particles, the sheet characterized in that: (a) the nano-particles form a substantially continuous phase on the sheet; and/or (b) the nano-particles are present in an amount of at least about 20% by dry weight of the coating; and/or (c) the coating is substantially free of polymeric binder, synthetic hydrophilic resin and/or a resin with a hydrophilic/hydrophobic character. The coated sheets have a high oxygen barrier, with preferred OTR values (at 23° C. and 0% RH)
    • 描述了一种基本上平面的自支撑片材(优选例如由诸如BOPP的聚烯烃形成的热塑性膜),其至少在其一侧上包含基本上连续的粘附涂层,以形成对氧的屏障, 颗粒,其特征在于:(a)纳米颗粒在片材上形成基本上连续的相; 和/或(b)纳米颗粒以涂层的干重至少约20%的量存在; 和/或(c)涂层基本上不含聚合物粘合剂,合成亲水树脂和/或具有亲水/疏水特性的树脂。 涂覆的片材具有高的阻氧性,优选的OTR值(在23℃和0%RH)<10cm 3 / m 2 /天。 优选的纳米颗粒是诸如淀粉的生物聚合物,并且涂层优选基本上不含已经发现降低氧阻隔效能的蜡。 也已经发现小分子或低聚物如生物共聚物(例如蔗糖)的组分的涂层增强颗粒涂层的氧阻隔性能,无论颗粒是微米还是纳米尺寸。 还描述了涂料组合物,涂膜,涂布方法和包装制品。