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1. 发明授权

US5124295A Copper chromite catalyst and process for preparation said catalyst 失效
标题翻译：亚铬酸铜催化剂及其制备方法
公开(公告)号：US5124295A
公开(公告)日：1992-06-23
申请号：US627013
申请日：1990-12-13
申请人： Eugene Nebesh , Donald G. Kelly , Lawrence T. Novak
发明人： Eugene Nebesh , Donald G. Kelly , Lawrence T. Novak
IPC分类号： B01J23/86 , B01J35/10 , B01J37/00 , C07B31/00 , C07B61/00
CPC分类号： B01J37/0009 , B01J23/868 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042
摘要： In one embodiment,the invention relates to a formed copper chromite catalyst prepared from a blend comprising from about 20 to about 80% by weight of copper chromite and from about 20 to about 80% by weight of at least one extrudable inorganic binder material wherein the catalyst has a surface area of from about 20 to about 225 m.sup.2 /g, and the total pore volume of the pores in said catalyst having a diameter of up to about 95,000 .ANG. is between about 0.35 to about 1 cc/g. In another embodiment, the invention relates to a process for preparing the formed copper chromite catalyst of the invention, and the process comprises(A) preparing a blend comprising from about 20 to about 80% by weight of copper chromite, from about 20 to about 80% by weight of at least one extrudable inorganic binder material, from about 1 to about 10% by weight, based on the weight of the binder, of a peptizing agent, and sufficient water to form an extrudable blend;(B) extruding the blend to form an extrudate; and(C) calcining the extrudate.The invention also relates to a process for hydrogenating aldehydes, ketones, carboxylic acids and carboxylic acid esters with catalysts of the type described.
摘要翻译：在一个实施方案中，本发明涉及由共混物制备的形成的亚铬酸铜催化剂，其包含约20至约80重量％的亚铬酸铜和约20至约80重量％的至少一种可挤出无机粘合剂材料，其中催化剂具有约20至约225m 2 / g的表面积，并且所述催化剂中具有高达约95,000安瓿的直径的孔的总孔体积为约0.35至约1cc / g。在另一个实施方案中，本发明涉及一种制备本发明的形成的亚铬酸铜催化剂的方法，该方法包括（A）制备共混物，其包含约20至约80重量％的亚铬酸铜，约20至约 80重量％的至少一种可挤出无机粘合剂材料，约1至约10重量％，基于粘合剂的重量，胶溶剂和足够的水以形成可挤出的共混物; （B）挤出共混物以形成挤出物; 和（C）煅烧挤出物。本发明还涉及用所述类型的催化剂氢化醛，酮，羧酸和羧酸酯的方法。

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