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    • 2. 发明申请
    • COMPLEX COMPOUNDS HAVING A LIGAND CONTAINING AN N DONOR AND A P DONOR AND THE USE THEREOF IN THE OPTO-ELECTRONIC FIELD
    • 具有包含N和DONOR的配体的复合化合物及其在光电场中的用途
    • US20140213806A1
    • 2014-07-31
    • US14234781
    • 2012-07-19
    • Lars WesemannFritz-Robert KüchleHermann August MayerSophie WernitzHartmut YersinMarkus Leitl
    • Lars WesemannFritz-Robert KüchleHermann August MayerSophie WernitzHartmut YersinMarkus Leitl
    • H01L51/00
    • H01L51/009C07F1/08C09K11/06C09K2211/1096H01L51/0004H01L51/0091H01L51/5012H05B33/14Y02E10/549
    • The invention describes electronic devices comprising a metal complex compound having at least one ligand contain-ing an N donor and a P donor having the formula (I), in which the carbons C1 and C2 are part of an aromatic or non-aromatic ring system F1, P and N are phosphorus and nitrogen, where the nitrogen is in sp2-hybridised form, the radicals R3 and R4 are, indepen-dently of one another, hydrogen or an alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, cyclo-alkynyl, alkylcycloalkyl, heteroalkyl, heterocycloalkyl, heteroalkylcycloalkyl, aryl, hetero-aryl, aralkyl or heteroaralkyl radical having up to 40 C atoms, and R1 and R2 are, independently of one another, an atom or radical from the group comprising hydrogen, halogen, R, RO—, RS—, RCO—, RCOO—, RNH—, R2N—, RCONR— and —Si(R)X(OR)3-X, where R=an alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, cycloalkynyl, alkylcycloalkyl, heteroalkyl, hetero-cycloalkyl, hetero-alkyl-cycloalkyl, aryl, heteroaryl, aralkyl or heteroaralkyl radical having up to 40 C atoms and X=1, 2 or 3. The invention furthermore describes a process for the production of an electronic device of this type and processes for the generation of light or blue emission using a metal complex compound of this type.
    • 本发明描述了包含具有至少一个含有N供体的配位体和具有式(I)的P给体的金属络合物的电子器件,其中碳C1和C2是芳族或非芳族环系的一部分 F1,P和N是磷和氮,其中氮是sp2杂交形式,基团R3和R4彼此独立地是氢或烷基,环烷基,烯基,环烯基,炔基,环炔基 具有至多40个C原子的烷基环烷基,杂烷基,杂环烷基,杂烷基环烷基,芳基,杂芳基,芳烷基或杂芳烷基,R 1和R 2彼此独立地为包含氢,卤素,R ,RO-,RS-,RCO-,RCOO-,RNH-,R2N-,RCONR-和-Si(R)X(OR)3-X,其中R =烷基,环烷基,烯基,环烯基,炔基, 烷基环烷基,杂烷基,杂环烷基,杂 - 烷基 - 环烷基,芳基,杂芳基,芳烷基或它 具有至多40个C原子且X = 1,2或3的三芳基烷基。本发明还描述了一种用于生产这种类型的电子器件的方法,并且使用这种金属络合物来产生光或蓝色发射的方法 类型。
    • 7. 发明授权
    • Complex compounds having a ligand containing an N donor and a P donor and the use thereof in the opto-electronic field
    • 具有含有N供体和P供体的配体的复合化合物及其在光电场中的用途
    • US09082990B2
    • 2015-07-14
    • US14234781
    • 2012-07-19
    • Lars WesemannFritz-Robert KuechleHermann August MayerSophie WernitzHartmut YersinMarkus Leitl
    • Lars WesemannFritz-Robert KuechleHermann August MayerSophie WernitzHartmut YersinMarkus Leitl
    • H01L51/00C09K11/06H05B33/14C07F1/08H01L51/50
    • H01L51/009C07F1/08C09K11/06C09K2211/1096H01L51/0004H01L51/0091H01L51/5012H05B33/14Y02E10/549
    • The invention describes electronic devices comprising a metal complex compound having at least one ligand containing an N donor and a P donor having the formula (I), in which the carbons C1 and C2 are part of an aromatic or non-aromatic ring system F1, P and N are phosphorus and nitrogen, where the nitrogen is in sp2-hybridized form, the radicals R3 and R4 are, independently of one another, hydrogen or an alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, cycloalkynyl, alkylcycloalkyl, heteroalkyl, heterocycloalkyl, heteroalkylcycloalkyl, aryl, heteroaryl, aralkyl or heteroaralkyl radical having up to 40 C atoms, and R1 and R2 are, independently of one another, an atom or radical from the group comprising hydrogen, halogen, R, RO—, RS—, RCO—, RCOO—, RNH—, R2N—, RCONR— and —Si(R)X(OR)3-X, where R=an alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, cycloalkynyl, alkylcycloalkyl, heteroalkyl, heterocycloalkyl, heteroalkylcycloalkyl, aryl, heteroaryl, aralkyl or heteroaralkyl radical having up to 40 C atoms and X=1, 2 or 3. The invention furthermore describes a process for the production of an electronic device of this type and processes for the generation of light or blue emission using a metal complex compound of this type.
    • 本发明描述了包含具有至少一个含有N供体的配位体和具有式(I)的P给体的金属络合物的电子器件,其中碳C1和C2是芳族或非芳族环系F1的一部分, P和N是磷和氮,其中氮是sp2杂交形式,基团R 3和R 4彼此独立地是氢或烷基,环烷基,烯基,环烯基,炔基,环炔基,烷基环烷基,杂烷基,杂环烷基 具有至多40个C原子的杂烷基环烷基,芳基,杂芳基,芳烷基或杂芳烷基,R 1和R 2彼此独立地为包含氢,卤素,R,RO-,RS-,RCO - ,RCOO-,RNH-,R2N-,RCONR-和-Si(R)X(OR)3-X,其中R =烷基,环烷基,烯基,环烯基,炔基,环炔基,烷基环烷基,杂烷基,杂环烷基,杂烷基环烷基 ,芳基,杂芳基,芳烷基或杂亚烷基 具有至多40个C原子且X = 1,2或3的烷基。本发明还描述了一种用于生产这种类型的电子器件的方法,并且使用这种金属络合物来产生光或蓝色发射的方法 类型。