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    • 1. 发明授权
    • Epoxy modified organopolysiloxane resin based compositions useful for protective coatings
    • 用于保护涂层的环氧改性有机聚硅氧烷树脂基组合物
    • US07125609B2
    • 2006-10-24
    • US10513090
    • 2003-04-30
    • Lars Ivar KlaassensJan De JongHenk Van Der Poel
    • Lars Ivar KlaassensJan De JongHenk Van Der Poel
    • B32B9/04
    • C09D183/10C08G59/4085C08G59/504C08G77/14C08G77/16C08G77/18C08G77/42C08G77/70C08K5/17C08L63/00C08L83/04Y10T428/31511Y10T428/31663C08L83/00C08L2666/14
    • The present invention relates to an epoxy modified polysiloxane composition obtainable by combining the following ingredients:—a polysiloxane of formula (1), wherein each R1 is independently selected from hydroxy, alkyl, aryl or alkoxy radicals having up to six carbon atoms, each R2 is independently selected from hydrogen, alkyl or aryl radicals having up to six carbon atoms and, wherein n is selected so that the molecular weight for the polysiloxane is in the range of from about 400 to 10,000; with formula (1)—an epoxy resin having more than one 1,2-epoxy groups per molecule with an epoxy equivalent weight in the range of from 100 to about 5,000; and—an amino hardener component having active hydrogens able to react with epoxy groups in the epoxy resin to form polymers containing hydroxyl groups, which are able to react with the silanol groups of hydrolyzed polysiloxane to form a polymer network, wherein the epoxy chain polymers and polysiloxane polymers polymerize to form a cured epoxy modified polysiloxane polymer composition.
    • 本发明涉及通过组合以下成分获得的环氧改性聚硅氧烷组合物: - 式(1)的聚硅氧烷,其中每个R 1独立地选自羟基,烷基,芳基或烷氧基,其具有 多至六个碳原子,每个R 2独立地选自具有至多6个碳原子的氢,烷基或芳基,并且其中n选择为使得聚硅氧烷的分子量在 约400至10,000; 式(1) - 每分子具有多于一个1,2-环氧基的环氧树脂,其环氧当量为100至约5,000; 和具有能够与环氧树脂中的环氧基反应的活性氢的氨基固化剂组分,以形成能够与水解的聚硅氧烷的硅烷醇基团反应形成聚合物网络的含羟基的聚合物,其中环氧链聚合物和 聚硅氧烷聚合物聚合形成固化的环氧改性聚硅氧烷聚合物组合物。