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    • 1. 发明申请
    • ANION EXCHANGE POLYMER ELECTROLYTES
    • 阴离子交换聚合物电解质
    • US20110065018A1
    • 2011-03-17
    • US12878844
    • 2010-09-09
    • Yu Seung KimDae Sik KimKwan-Soo Lee
    • Yu Seung KimDae Sik KimKwan-Soo Lee
    • B01J41/12H01M8/10
    • H01M8/083C08J5/225H01M8/1018
    • Solid anion exchange polymer electrolytes and compositions comprising chemical compounds comprising a polymeric core, a spacer A, and a guanidine base, wherein said chemical compound is uniformly dispersed in a suitable solvent and has the structure: wherein: i) A is a spacer having the structure O, S, SO2, —NH—, —N(CH2)n, wherein n=1-10, —(CH2)n—CH3—, wherein n=1-10, SO2-Ph, CO-Ph, wherein R5, R6, R7 and R8 each are independently —H, —NH2, F, Cl, Br, CN, or a C1-C6 alkyl group, or any combination of thereof; ii) R9, R10, R11, R12, or R13 each independently are —H, —CH3, —NH2, —NO, —CHnCH3 where n=1-6, HC═O—, NH2C═O—, —CHnCOOH where n=1-6, —(CH2)n—C(NH2)—COOH where n=1-6, —CH—(COOH)—CH2—COOH, —CH2—CH(O—CH2CH3)2, —(C═S)—NH2, —(C═NH)—N—(CH2)nCH3, where n=0-6, —NH—(C═S)—SH, —CH2—(C═O)—O—C(CH3)3, —O—(CH2)n—CH—(NH2)—COOH, where n=1-6, —(CH2)n—CH═CH wherein n=1-6, —(CH2)n—CH—CN wherein n=1-6, an aromatic group such as a phenyl, benzyl, phenoxy, methylbenzyl, nitrogen-substituted benzyl or phenyl groups, a halide, or halide-substituted methyl groups; and iii) wherein the composition is suitable for use in a membrane electrode assembly.
    • 固体阴离子交换聚合物电解质和包含化合物的组合物,其包含聚合物芯,间隔物A和胍碱,其中所述化合物均匀分散在合适的溶剂中并具有以下结构:其中:i)A是具有 结构O,S,SO 2,-NH-,-N(CH 2)n,其中n = 1-10, - (CH 2)n -CH 3 - ,其中n = 1-10,SO 2 -P Ph,CO-Ph,其中 R5,R6,R7和R8各自独立地为-H,-NH2,F,Cl,Br,CN或C1-C6烷基,或其任何组合; ii)R9,R10,R11,R12或R13各自独立地为-H,-CH3,-NH2,-NO,-CHnCH3,其中n = 1-6,HC = O - ,NH2C = O - , - CHNCOOH,其中n = 1-6, - (CH 2)n -C(NH 2)-COOH其中n = 1-6,-CH-(COOH)-CH 2 -COOH,-CH 2 -CH(O-CH 2 CH 3)2, - (C = S)-NH 2, - (C = NH)-N-(CH 2)n CH 3,其中n = 0-6,-NH-(C = S)-SH,-CH 2 - (C = O) CH3)3,-O-(CH2)n-CH-(NH2)-COOH,其中n = 1-6, - (CH2)n-CH = CH其中n = 1-6, - (CH2)n-CH -CN,其中n = 1-6,芳基如苯基,苄基,苯氧基,甲基苄基,氮取代的苄基或苯基,卤化物或卤化物取代的甲基; 和iii)其中所述组合物适用于膜电极组件。
    • 5. 发明授权
    • Terphenyl dihalide monomers having sulfonate groups and process for preparing the same
    • 具有磺酸盐基团的二苯甲烷二卤化物单体及其制备方法
    • US07173155B1
    • 2007-02-06
    • US11485855
    • 2006-07-13
    • Jae-Suk LeeSun-Young ChangKwan-Soo LeeMyung-Hwan JeongJung-Eun Yang
    • Jae-Suk LeeSun-Young ChangKwan-Soo LeeMyung-Hwan JeongJung-Eun Yang
    • C07C315/00
    • C07C309/39
    • The present invention relates to a terphenyl dihalide monomer having sulfonate groups and a process for preparing the same. More particularly, the present invention relates to a terphenyl dihalide monomer having sulfonate groups prepared by a process comprising obtaining a terphenyl dihalide derivative by Suzuki cross-coupling of a tetrahalobenzene and phenylboronic acid and introducing sulfonate groups into the phenyl rings at each end of the terphenyl dihalide derivative, the resultant monomer capable of being prepared into a polymer electrolyte having superior ion conductivity through nucleophilic aromatic substitution (SNAr) polymerization due to the presence of two halogen atoms and two conducting sulfonate groups in the monomer molecule, and a process for preparing the same.
    • 本发明涉及具有磺酸盐基团的三联苯二卤化物单体及其制备方法。 更具体地,本发明涉及具有磺酸盐基团的三联苯二卤化物单体,其通过以下方法制备,所述方法包括通过四卤代苯和苯硼酸的Suzuki交叉偶联获得三联苯二卤化物衍生物,并且在三联苯的每个末端将引入磺酸基团引入苯环 二卤化物衍生物,所得单体能够通过亲核芳香取代(S N N Ar)聚合制备成具有优异离子传导性的聚合物电解质,由于两个卤素原子和两个导电磺酸基团的存在, 单体分子及其制备方法。