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1. 发明授权

US07595362B2 Curable resin composition 有权
标题翻译：可固化树脂组合物
公开(公告)号：US07595362B2
公开(公告)日：2009-09-29
申请号：US10586642
申请日：2005-01-26
申请人： Masanao Kawabe , Hiroyuki Yano , Yasuji Shichijo , Kouhei Tomari , Isamu Akiba
发明人： Masanao Kawabe , Hiroyuki Yano , Yasuji Shichijo , Kouhei Tomari , Isamu Akiba
IPC分类号： C08L71/12 , B32B15/08
CPC分类号： C08L51/003 , B32B15/08 , B32B17/04 , B32B27/18 , B32B27/26 , B32B27/28 , B32B27/285 , B32B27/302 , B32B2307/306 , B32B2307/3065 , B32B2457/08 , C08F257/02 , C08F283/06 , C08F290/06 , C08F290/062 , C08K3/013 , C08K5/0066 , C08K5/14 , C08K5/34924 , C08L53/00 , C08L71/12 , C09D153/00 , H05K1/0353 , H05K3/4626 , Y10T428/12569 , C08L2666/02 , C08L2666/14 , C08L2666/04
摘要： Provided is curable resin composition which gives a cured article excellent in chemical resistance, dielectric properties, low water-absorption, heat resistance, flame retardance, and mechanical properties and which is usable in applications such as dielectric materials, insulating materials, heat-resistant materials, and structural materials. The curable resin composition includes a component (A) which is a polyphenylene ether oligomer having a number-average molecular weight of 700 to 4,000 and having a vinyl group at both end and a component (B) which is a solvent-soluble polyfunctional vinylaromatic copolymer which has structural units derived from monomers including a divinylaromatic compound (a) and an ethylvinylaromatic compound (b) and in which the content of repeating units derived from the divinylaromatic compound (a) is 20 mol % or higher, the ratio of the amount (wt. %) of the component (A) to that (wt. %) of the component (B) being (20 to 98):(2 to 80). The composition can further contain a layered silicate, a halogenated flame retardant, etc.
摘要翻译：本发明提供了耐化学性，介电性，低吸水性，耐热性，阻燃性和机械性能优异的固化物的固化性树脂组合物，其可用于介电材料，绝缘材料，耐热材料，和结构材料。作为固化性树脂组合物，可列举数均分子量为700〜4000的聚苯醚低聚物和两末端具有乙烯基的成分（A）和作为溶剂可溶性多官能乙烯基芳香族共聚物的成分（B）其具有衍生自包括二乙烯基芳族化合物（a）和乙烯基乙烯基芳族化合物（b）的单体的结构单元，并且其中衍生自二乙烯基芳族化合物（a）的重复单元的含量为20摩尔％以上，（A）成分（B）的重量％（重量％）为（20〜98）：（2〜80）。组合物还可以含有层状硅酸盐，卤化阻燃剂等

2. 发明授权

US08163443B2 Photosensitive resin composition for volume phase hologram recording and optical information recording medium using the same 有权
标题翻译：用于体积相位全息记录的光敏树脂组合物和使用其的光学信息记录介质
公开(公告)号：US08163443B2
公开(公告)日：2012-04-24
申请号：US12224598
申请日：2007-03-05
申请人： Kouhei Tomari , Yasuji Shichijo
发明人： Kouhei Tomari , Yasuji Shichijo
IPC分类号： G03H1/02
CPC分类号： G03H1/02 , G03F7/001 , G03F7/033 , G03F7/0388 , G03H2001/0264 , G03H2260/12
摘要： Disclosed is a volume phase hologram recording material characterized by excellent photosensitivity, low cure shrinkage, high transparency, and particularly good storage stability and also disclosed is a recording medium prepared therefrom. Further disclosed is a photosensitive resin composition for volume phase hologram recording that comprises a soluble aromatic copolymer (A), a photoradically polymerizable compound (B) capable of copolymerizing with the soluble aromatic copolymer (A), a photopolymerization initiator (C), and a polymer binder (D). The soluble aromatic copolymer (A) has a structural unit of a divinyl aromatic compound and a structural unit of a monovinyl aromatic compound, comprises 10 to 90 mol % of a structural unit represented by the following formula (a1), has a hydroxyl equivalent of 100 to 30,000 g/equiv, a number average molecular weight (Mn) of 400 to 30,000, and a molecular weight distribution (Mw/Mn) of 10 or less, and accounts for 5 to 60 wt % of the composition.
摘要翻译：公开了一种体积相全息记录材料，其特征在于具有优异的光敏性，低固化收缩率，高透明度和特别好的储存稳定性，并且还公开了由其制备的记录介质。进一步公开了一种用于体积相位全息记录的感光性树脂组合物，其包含可溶性芳香族共聚物（A），能够与可溶性芳香族共聚物（A）共聚的光自由基聚合性化合物（B），光聚合引发剂（C）和聚合物粘合剂（D）。可溶性芳香族共聚物（A）具有二乙烯基芳香族化合物的结构单元和单乙烯基芳香族化合物的结构单元，含有下述通式（a1）所示的结构单元的10〜90摩尔％，羟基当量为 100〜30,000g /当量，数均分子量（Mn）为400〜30,000，分子量分布（Mw / Mn）为10以下，占组合物的5〜60重量％。

3. 发明申请

US20070129502A1 Curable resin composition 有权
标题翻译：可固化树脂组合物
公开(公告)号：US20070129502A1
公开(公告)日：2007-06-07
申请号：US10586642
申请日：2005-01-26
申请人： Masanao Kawabe , Hiroyuki Yano , Yasuji Shichijo , Kouhei Tomari , Isamu Akiba
发明人： Masanao Kawabe , Hiroyuki Yano , Yasuji Shichijo , Kouhei Tomari , Isamu Akiba
IPC分类号： C08L71/12 , C08K3/34
CPC分类号： C08L51/003 , B32B15/08 , B32B17/04 , B32B27/18 , B32B27/26 , B32B27/28 , B32B27/285 , B32B27/302 , B32B2307/306 , B32B2307/3065 , B32B2457/08 , C08F257/02 , C08F283/06 , C08F290/06 , C08F290/062 , C08K3/013 , C08K5/0066 , C08K5/14 , C08K5/34924 , C08L53/00 , C08L71/12 , C09D153/00 , H05K1/0353 , H05K3/4626 , Y10T428/12569 , C08L2666/02 , C08L2666/14 , C08L2666/04
摘要： Provided is curable resin composition which gives a cured article excellent in chemical resistance, dielectric properties, low water-absorption, heat resistance, flame retardance, and mechanical properties and which is usable in applications such as dielectric materials, insulating materials, heat-resistant materials, and structural materials. The curable resin composition includes a component (A) which is a polyphenylene ether oligomer having a number-average molecular weight of 700 to 4,000 and having a vinyl group at both end and a component (B) which is a solvent-soluble polyfunctional vinylaromatic copolymer which has structural units derived from monomers including a divinylaromatic compound (a) and an ethylvinylaromatic compound (b) and in which the content of repeating units derived from the divinylaromatic compound (a) is 20 mol % or higher, the ratio of the amount (wt. %) of the component (A) to that (wt. %) of the component (B) being (20 to 98):(2 to 80). The composition can further contain a layered silicate, a halogenated flame retardant, etc.
摘要翻译：本发明提供了耐化学性，介电性，低吸水性，耐热性，阻燃性和机械性能优异的固化物的固化性树脂组合物，其可用于介电材料，绝缘材料，耐热材料，和结构材料。作为固化性树脂组合物，可列举数均分子量为700〜4000的聚苯醚低聚物和两末端具有乙烯基的成分（A）和作为溶剂可溶性多官能乙烯基芳香族共聚物的成分（B）其具有衍生自包括二乙烯基芳族化合物（a）和乙烯基乙烯基芳族化合物（b）的单体的结构单元，并且其中衍生自二乙烯基芳族化合物（a）的重复单元的含量为20摩尔％以上，（A）成分（B）的重量％（重量％）为（20〜98）：（2〜80）。组合物还可以含有层状硅酸盐，卤化阻燃剂等

4. 发明授权

US08034514B2 Photosensitive resin composition for volume phase hologram recording and optical information recording medium using the same 有权
标题翻译：用于体积相位全息记录的光敏树脂组合物和使用其的光学信息记录介质
公开(公告)号：US08034514B2
公开(公告)日：2011-10-11
申请号：US11885787
申请日：2006-03-01
申请人： Kouhei Tomari , Yasuji Shichijo , Masanao Kawabe
发明人： Kouhei Tomari , Yasuji Shichijo , Masanao Kawabe
IPC分类号： G03H1/02
CPC分类号： G03F7/001 , G03F7/027 , G03F7/033
摘要： The present invention relates to a volume phase hologram recording material excellent in transparency, sensitivity, low curing shrinkage, and transparency, a volume phase hologram recording medium, and a volume phase hologram. A photosensitive resin composition for volume phase hologram recording contains a low-molecular-weight solvent-soluble aromatic copolymer (A) having a structural unit of a divinyl aromatic compound and a structural unit of a monovinyl aromatic compound, a photoradical polymerizable compound (B) which is copolymerizable with the soluble aromatic copolymer (A), and a photopolymerization initiator (C) as essential components. The photosensitive resin composition further contains, one kind or more of a polymer binder (D) and a plasticizer (E), and the soluble aromatic copolymer (A) is incorporated in an amount of 5 to 60% by weight.
摘要翻译：本发明涉及透明度，灵敏度，低固化收缩率和透明度优异，体积相位全息图记录介质和体积相位全息图的体积相位全息图记录材料。用于体积相位全息记录的感光性树脂组合物含有具有二乙烯基芳香族化合物的结构单元和单乙烯基芳香族化合物的结构单元的低分子量溶剂可溶性芳香族共聚物（A），光自由基聚合性化合物（B）其可与可溶性芳族共聚物（A）共聚，光聚合引发剂（C）为必需成分。感光性树脂组合物还含有聚合物粘合剂（D）和增塑剂（E）中的一种以上，可溶性芳香族共聚物（A）的含量为5〜60重量％。

5. 发明申请

US20090130568A1 Photosensitive Resin Composition for Volume Phase Hologram Recording and Optical Information Recording Medium Using the Same 有权
标题翻译：用于体积相位全息记录的光敏树脂组合物和使用其的光学信息记录介质
公开(公告)号：US20090130568A1
公开(公告)日：2009-05-21
申请号：US12224598
申请日：2007-03-05
申请人： Kouhei Tomari , Yasuji Shichijo
发明人： Kouhei Tomari , Yasuji Shichijo
IPC分类号： G03F7/20 , G03F7/004
CPC分类号： G03H1/02 , G03F7/001 , G03F7/033 , G03F7/0388 , G03H2001/0264 , G03H2260/12
摘要： Disclosed is a volume phase hologram recording material characterized by excellent photosensitivity, low cure shrinkage, high transparency, and particularly good storage stability and also disclosed is a recording medium prepared therefrom. Further disclosed is a photosensitive resin composition for volume phase hologram recording that comprises a soluble aromatic copolymer (A), a photoradically polymerizable compound (B) capable of copolymerizing with the soluble aromatic copolymer (A), a photopolymerization initiator (C), and a polymer binder (D). The soluble aromatic copolymer (A) has a structural unit of a divinyl aromatic compound and a structural unit of a monovinyl aromatic compound, comprises 10 to 90 mol % of a structural unit represented by the following formula (a1), has a hydroxyl equivalent of 100 to 30,000 g/equiv, a number average molecular weight (Mn) of 400 to 30,000, and a molecular weight distribution (Mw/Mn) of 10 or less, and accounts for 5 to 60 wt % of the composition.
摘要翻译：公开了一种体积相全息记录材料，其特征在于具有优异的光敏性，低固化收缩率，高透明度和特别好的储存稳定性，并且还公开了由其制备的记录介质。进一步公开了一种用于体积相位全息记录的感光性树脂组合物，其包含可溶性芳香族共聚物（A），能够与可溶性芳香族共聚物（A）共聚的光自由基聚合性化合物（B），光聚合引发剂（C）和聚合物粘合剂（D）。可溶性芳香族共聚物（A）具有二乙烯基芳香族化合物的结构单元和单乙烯基芳香族化合物的结构单元，含有下述通式（a1）所示的结构单元的10〜90摩尔％，羟基当量为 100〜30,000g /当量，数均分子量（Mn）为400〜30,000，分子量分布（Mw / Mn）为10以下，占组合物的5〜60重量％。

6. 发明申请

US20090053615A1 Photosensitive Resin Composition for Volume Phase Hologram Recording and Optical Information Recording Medium Using the Same 有权
标题翻译：用于体积相位全息记录的光敏树脂组合物和使用其的光学信息记录介质
公开(公告)号：US20090053615A1
公开(公告)日：2009-02-26
申请号：US11885787
申请日：2006-03-01
申请人： Kouhei Tomari , Yasuji Shichijo , Masanao Kawabe
发明人： Kouhei Tomari , Yasuji Shichijo , Masanao Kawabe
IPC分类号： G03F7/09 , G03F7/20
CPC分类号： G03F7/001 , G03F7/027 , G03F7/033
摘要： The present invention relates to a volume phase hologram recording material excellent in transparency, sensitivity, low curing shrinkage, and transparency, a volume phase hologram recording medium, and a volume phase hologram. A photosensitive resin composition for volume phase hologram recording contains a low-molecular-weight solvent-soluble aromatic copolymer (A) having a structural unit of a divinyl aromatic compound and a structural unit of a monovinyl aromatic compound, a photoradical polymerizable compound (B) which is copolymerizable with the soluble aromatic copolymer (A), and a photopolymerization initiator (C) as essential components. The photosensitive resin composition further contains, one kind or more of a polymer binder (D) and a plasticizer (E), and the soluble aromatic copolymer (A) is incorporated in an amount of 5 to 60% by weight.
摘要翻译：本发明涉及透明度，灵敏度，低固化收缩率和透明度优异，体积相位全息图记录介质和体积相位全息图的体积相位全息图记录材料。用于体积相位全息记录的感光性树脂组合物含有具有二乙烯基芳香族化合物的结构单元和单乙烯基芳香族化合物的结构单元的低分子量溶剂可溶性芳香族共聚物（A），光自由基聚合性化合物（B）其可与可溶性芳族共聚物（A）共聚，光聚合引发剂（C）为必需成分。感光性树脂组合物还含有聚合物粘合剂（D）和增塑剂（E）中的一种以上，可溶性芳香族共聚物（A）的含量为5〜60重量％。

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