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    • 1. 发明申请
    • ASYMMETRIC AND/OR LOW-SYMMETRIC FLUORINE-CONTAINING PHOSPHATE FOR NON-AQUEOUS ELECTROLYTE SOLUTION
    • 不对称和/或低对称含氟磷酸盐用于非水溶性电解质溶液
    • US20120094190A1
    • 2012-04-19
    • US13380658
    • 2010-07-30
    • Hideyuki MimuraKentaro KonoHisao EguchiKotaro SakodaMasahiro Aoki
    • Hideyuki MimuraKentaro KonoHisao EguchiKotaro SakodaMasahiro Aoki
    • H01M10/056C07F9/141
    • H01M10/0569H01M10/052H01M10/0525H01M10/4235Y02T10/7011
    • As to a fluorine-containing phosphate used to impart flame retardancy to an electrolyte solution for a non-aqueous secondary battery, a fluorine-containing phosphate having high flame retardancy and providing high battery performance such as high-rate charge-discharge characteristics, and a method for manufacturing the same are provided. Also provided are a non-aqueous electrolyte solution and a non-aqueous secondary battery each containing the fluorine-containing phosphate.Further a fluorine-containing phosphate having a high ability to dissolve an electrolyte and capable of providing the composition of a safer electrolyte solution is provided.The fluorine-containing phosphate for a non-aqueous electrolyte solution is represented by the general formula (1) (wherein R represents an alkyl group having 1 to 10 carbon atoms or a fluorine-containing alkyl group having 1 to 10 carbon atoms, A and B are different from each other and each represent a hydrogen atom or a fluorine atom, and n and m each independently represent an integer from 1 to 8) and contains fluorine atoms in a weight ratio of 30% or higher.
    • 对于用于赋予非水二次电池用电解液阻燃性的含氟磷酸盐,具有高阻燃性且具有高电压特性的含氟磷酸盐,例如高倍率充放电特性,以及 提供了制造该方法的方法。 还提供了含有含氟磷酸盐的非水电解液和非水二次电池。 此外,还提供了一种具有高溶解电解质并且能够提供更安全的电解质溶液组成的能力的含氟磷酸盐。 用于非水电解质溶液的含氟磷酸酯由通式(1)表示(其中R表示碳原子数为1〜10的烷基或碳原子数1〜10的含氟烷基,A和 B彼此不同,各自表示氢原子或氟原子,n和m各自独立地表示1〜8的整数),并且含有30重量%以上的氟原子。