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1. 发明授权

US08602222B2 Composite semipermeable membranes, methods for production thereof and uses thereof 失效
标题翻译：复合半透膜，其制造方法及其用途
公开(公告)号：US08602222B2
公开(公告)日：2013-12-10
申请号：US12085676
申请日：2006-12-13
申请人： Koji Nakatsuji , Hiroki Tomioka
发明人： Koji Nakatsuji , Hiroki Tomioka
IPC分类号： B01D71/56 , B01D71/68
CPC分类号： B01D71/56 , B01D61/025 , B01D69/12 , B01D69/125 , C02F1/441 , C02F2103/08 , Y02A20/131
摘要： There is provided a composite semipermeable membrane that shows a high salt removal ratio and high performance in rejecting boron that is not dissociated in the neutral region. The composite semipermeable membrane is produced by a process that includes forming a separating functional polyamide layer on a porous substrate film, while using an organic solvent solution containing a specific cyclic aliphatic compound or a specific aromatic compound such that a polyamide molecule that forms the separating functional polyamide layer has a partial structure composed of “a cyclic aliphatic group or an aromatic group having at least two specific substituents, at least one of which contains a heteroatom bond and a carbonyl group at the β or γ position”.
摘要翻译：提供了一种复合半透膜，其显示出高的除盐率和在中性区域中不分离的硼的排除高性能。复合半透膜通过包括在多孔基材膜上形成分离功能性聚酰胺层，同时使用含有特定环状脂肪族化合物或特定芳香族化合物的有机溶剂溶液使得形成分离功能性的聚酰胺分子聚酰胺层具有由“环状脂族基团或具有至少两个特定取代基的芳香族基团”组成的部分结构，其中至少一个在β或γ位置含有杂原子键和羰基。

2. 发明申请

US20130032530A1 COMPOSITE SEMIPERMEABLE MEMBRANE 有权
标题翻译：复合可切片膜
公开(公告)号：US20130032530A1
公开(公告)日：2013-02-07
申请号：US13579138
申请日：2011-03-28
申请人： Hiroki Minehara , Koji Nakatsuji
发明人： Hiroki Minehara , Koji Nakatsuji
IPC分类号： B01D71/70 , B01D71/68
CPC分类号： B01D71/70 , B01D65/022 , B01D67/0006 , B01D67/0027 , B01D69/12 , B01D71/78 , B01D71/82 , B01D2321/16 , B01D2321/343 , B01D2325/14 , C08G77/26 , C08L83/08 , Y02A20/131
摘要： Disclosed is a composite semipermeable membrane, which comprises a separation functional layer on a microporous support, and in which the separation functional layer is made of a condensation product of a polymer that has acidic groups and a trialkoxysilane groups having an imidazolium structure in side chains. The composite semipermeable membrane has excellent selective separation performance for divalent ions over monovalent ions, while exhibiting excellent long-term durability. Also disclosed is a method for producing the composite semipermeable membrane. The composite semipermeable membrane is suitable for uses in various water treatment fields such as the desalination of seawater and the production of drinking water. In addition, the composite semipermeable membrane does not deteriorate as much as conventional composite semipermeable membrane even in cases where the membrane is sterilized by having chlorine-containing raw water permeate therethrough continuously or intermittently.
摘要翻译：公开了一种复合半透膜，其包含在微孔载体上的分离功能层，其中分离功能层由具有酸性基团的聚合物和侧链上具有咪唑结构的三烷氧基硅烷基团的缩合产物制成。复合半透膜相对于一价离子具有优异的二价离子选择性分离性能，同时具有优异的长期耐久性。还公开了一种复合半透膜的制造方法。复合半透膜适用于各种水处理领域，如海水淡化和饮用水生产。此外，即使在通过使含有含氯原水的渗透通过其连续地或间歇地进行灭菌的情况下，复合半透膜也不会劣化常规的复合半透膜。

3. 发明申请

US20080000843A1 Composite Semipermeable Membrane, Production Process Thereof, and Element, Fluid Separation Equipment and Treatment Method for Boron-Containing Water Using the Same 有权
标题翻译：复合半透膜，其生产工艺及其元素，流体分离设备及含硼水处理方法
公开(公告)号：US20080000843A1
公开(公告)日：2008-01-03
申请号：US11666752
申请日：2005-11-04
申请人： Takao Sasaki , Hiroki Tomioka , Koji Nakatsuji
发明人： Takao Sasaki , Hiroki Tomioka , Koji Nakatsuji
IPC分类号： B01D71/56 , B01D65/10 , B01D67/00 , C02F1/44 , B01D69/02 , B01D69/12
CPC分类号： B01D67/0088 , B01D65/10 , B01D67/0093 , B01D69/02 , B01D69/122 , B01D69/125 , B01D71/56 , B01D2323/30 , C02F1/441 , C02F2103/08 , Y02A20/131
摘要： A composite semipermeable membrane, which comprises a separating functional layer comprising a reactant of polyfunctional amine with polyfunctional acid halide, wherein a water-soluble organic material is in contact with the separating functional layer, and the separating functional layer has a boron removal ratio of 95% or more, when seawater at 25° C. having a pH of 6.5, a boron concentration of 5 ppm and a TDS concentration of 3.5% by weight is permeated under an operation pressure of 5.5 MPa.
摘要翻译：一种复合半透膜，其包含分离功能层，其包含多官能胺与多官能酰卤的反应物，其中水溶性有机材料与分离功能层接触，分离功能层的脱硼率为95 ％以上，当pH为6.5，硼浓度为5ppm，TDS浓度为3.5重量％的25℃的海水在5.5MPa的操作压力下渗透。

4. 发明授权

US07184733B2 High frequency receiving device, integrated circuit used for the same, and TV receiver using them 失效
标题翻译：高频接收设备，集成电路用于同一电视接收机，电视接收机使用它们
公开(公告)号：US07184733B2
公开(公告)日：2007-02-27
申请号：US10874810
申请日：2004-06-24
申请人： Sanae Asayama , Koji Nakatsuji , Atsuhito Terao , Yoshihide Tabata , Hideji Takami , Masanori Suzuki , Hirochika Kashima
发明人： Sanae Asayama , Koji Nakatsuji , Atsuhito Terao , Yoshihide Tabata , Hideji Takami , Masanori Suzuki , Hirochika Kashima
IPC分类号： H04B1/06
CPC分类号： H03J5/244 , H03J3/28 , H03J2200/36
摘要： An oscillation frequency changing means is inserted between a tuner and an oscillator of local oscillator (56) of a high frequency receiving device, and the oscillation frequency changing means, in each frequency band received, changes the oscillation frequency characteristic of local oscillator (56) in relation to the tuning voltage supplied from PLL circuit (78), and operates in accordance with the frequency characteristic of tuning filter (52, 54, 62, 64) to obtain an oscillation signal varied just by a predetermined frequency, thereby making it possible to receive broadband channels of continuous VHF broadcast band and UHF broadcast band.
摘要翻译：在调谐器和高频接收装置的本地振荡器（56）的振荡器之间插入振荡频率改变装置，并且在接收到的每个频带中的振荡频率改变装置改变本地振荡器（56）的振荡频率特性，关于从PLL电路（78）提供的调谐电压，并根据调谐滤波器（52,54,62,64）的频率特性进行操作，以获得刚好按预定频率变化的振荡信号，从而使其成为可能接收连续VHF广播频段和UHF广播频段的宽带频道。

5. 发明申请

US20050032492A1 High frequency receiving device, integrated circuit used for same, and TV receiver using them 失效
标题翻译：高频接收装置，与其相同的集成电路，以及使用它们的电视接收机
公开(公告)号：US20050032492A1
公开(公告)日：2005-02-10
申请号：US10874810
申请日：2004-06-24
申请人： Sanae Asayama , Koji Nakatsuji , Atsuhito Terao , Yoshihide Tabata , Hideji Takami , Masanori Suzuki , Hirochika Kashima
发明人： Sanae Asayama , Koji Nakatsuji , Atsuhito Terao , Yoshihide Tabata , Hideji Takami , Masanori Suzuki , Hirochika Kashima
IPC分类号： H03J3/20 , H03J3/28 , H03J5/00 , H03J5/24 , H04B1/06 , H04B1/16 , H04B1/18 , H04B1/40 , H04B7/00 , H04N5/44
CPC分类号： H03J5/244 , H03J3/28 , H03J2200/36
摘要： An oscillation frequency changing means is inserted between a tuner and an oscillator of local oscillator (56) of a high frequency receiving device, and the oscillation frequency changing means, in each frequency band received, changes the oscillation frequency characteristic of local oscillator (56) in relation to the tuning voltage supplied from PLL circuit (78), and operates in accordance with the frequency characteristic of tuning filter (52, 54, 62, 64) to obtain an oscillation signal varied just by a predetermined frequency, thereby making it possible to receive broadband channels of continuous VHF broadcast band and UHF broadcast band.
摘要翻译：在调谐器和高频接收装置的本地振荡器（56）的振荡器之间插入振荡频率改变装置，并且在接收到的每个频带中的振荡频率改变装置改变本地振荡器（56）的振荡频率特性，关于从PLL电路（78）提供的调谐电压，并根据调谐滤波器（52,54,62,64）的频率特性进行操作，以获得刚好按预定频率变化的振荡信号，从而使其成为可能接收连续VHF广播频段和UHF广播频段的宽带频道。

6. 发明申请

US20130256215A1 COMPOSITE SEMIPERMEABLE MEMBRANE 审中-公开
标题翻译：复合可切片膜
公开(公告)号：US20130256215A1
公开(公告)日：2013-10-03
申请号：US13988772
申请日：2011-12-22
申请人： Koji Nakatsuji , Masahiro Kimura , Takao Sasaki , Kiyohiko Takaya , Harutoki Shimura
发明人： Koji Nakatsuji , Masahiro Kimura , Takao Sasaki , Kiyohiko Takaya , Harutoki Shimura
IPC分类号： B01D71/64
CPC分类号： B01D71/56 , B01D67/0006 , B01D67/0081 , B01D67/0093 , B01D69/02 , B01D69/10 , B01D69/125 , B01D71/40 , B01D71/64 , B01D2252/2053 , B01D2323/08 , B01D2323/30 , B01D2323/36 , B01D2325/22
摘要： Provided is a composite semipermeable membrane, comprising: a microporous support membrane which comprises a substrate and a porous support, and a polyamide separation functional layer formed on the microporous support membrane, wherein the polyamide has an irreversible heat absorption, which is measured using temperature modulated DSC, of 275 J/g or more at a temperature in the range of −20 to 150° C. in the first heating process.Provided is a high-performance composite semipermeable membrane having high chemical durability, high water permeation and high rejection.
摘要翻译：本发明提供一种复合半透膜，包括：微孔支撑膜，其包含基材和多孔载体，以及形成在微孔支撑膜上的聚酰胺分离功能层，其中所述聚酰胺具有不可逆的吸热性，其使用温度调制 DSC为275J / g以上，在第一加热工序中，在-20〜150℃的温度范围内。提供具有高化学耐久性，高透水性和高排斥性的高性能复合半透膜。

7. 发明申请

US20120024778A1 COMPOSITE SEMIPERMEABLE MEMBRANE AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：复合可切割膜及其制造方法
公开(公告)号：US20120024778A1
公开(公告)日：2012-02-02
申请号：US13258356
申请日：2010-03-18
申请人： Hiroki Minehara , Koji Nakatsuji
发明人： Hiroki Minehara , Koji Nakatsuji
IPC分类号： B01D71/82 , B05D3/06 , B01D67/00 , B05D3/02 , B01D69/12 , B01D71/70
CPC分类号： B01D69/12 , B01D67/0006 , B01D67/0088 , B01D71/70 , B01D2323/02 , B01D2323/34 , B01D2323/345 , B01D2323/40 , C02F1/441 , C02F2103/08 , C08F212/14 , C08G77/26 , C09D183/08 , Y02A20/131
摘要： Disclosed herein are a composite semipermerable membrane and a method for producing the same. The composite semipermeable membrane comprises a microporous support membrane and a separation functional layer provided on the microporous support membrane, wherein the separation functional layer contains a condensation product produced by condensation of at least one selected from the group consisting of ions of trialkoxysilanes each having an imidazolium group and a conjugated base of a polymer having at least one acidic group. The composite semipermeable membrane achieves excellent selective separation of divalent ions over monovalent ions, and is suitable for use in various water treatment fields such as seawater desalination and drinking water production.
摘要翻译：本文公开了一种复合半渗透膜及其制造方法。复合半透膜包括微孔支撑膜和设置在微孔支撑膜上的分离功能层，其中分离功能层含有通过缩合产生的缩合产物，所述缩合产物是选自三烷氧基硅烷的离子中的至少一种，其各自具有咪唑鎓基团和具有至少一个酸性基团的聚合物的共轭碱。复合半透膜实现了二价离子优于一价离子的优异选择性分离，适用于各种水处理领域，如海水淡化和饮用水生产。

8. 发明申请

US20050079839A1 Radio-frequency receiver and integrated circuit for use in receiver 失效
标题翻译：射频接收机和用于接收机的集成电路
公开(公告)号：US20050079839A1
公开(公告)日：2005-04-14
申请号：US10962850
申请日：2004-10-12
申请人： Sanae Asayama , Koji Nakatsuji , Masanori Suzuki , Atsuhito Terao
发明人： Sanae Asayama , Koji Nakatsuji , Masanori Suzuki , Atsuhito Terao
IPC分类号： H03B27/00 , H03D7/16 , H03D7/18 , H03J3/08 , H03J5/24 , H04B1/26 , H04B1/28 , H04B1/40 , H04N5/44 , H04N5/46 , H04B1/18 , H04B1/10 , H04M1/00
CPC分类号： H04B1/406 , H03J3/08 , H03J5/244 , H04B1/28
摘要： A radio-frequency (RF) receiver includes an input terminal for receiving RF signals in a first frequency band and a second frequency band lower than the first frequency band, a first tuned filter allowing a signal of a passing frequency in the RF signal in the first frequency band to pass through the filter, a local oscillator, a frequency divider for frequency-dividing a signal output from the local oscillator, a first mixer operable to convert the signal output from the first tuned filter into a signal of an intermediate frequency, a second tuned filter allowing a signal of a passing frequency of the RF signal in the second frequency band to pass through the filter, a second mixer operable to convert the signal output from the second tuned filter into a signal of the intermediate frequency, and a phase-locked-loop (PLL) circuit operable to control an oscillation frequency of the local oscillator and the passing frequencies of the first tuned filter and the second tuned filter.
摘要翻译：射频（RF）接收机包括用于接收第一频带中的RF信号的输入端和低于第一频带的第二频带的第一调谐滤波器，其允许RF信号中的通过频率的信号第一频带通过滤波器，本地振荡器，用于对从本地振荡器输出的信号进行分频的分频器，可操作以将从第一调谐滤波器输出的信号转换为中频信号的第一混频器，允许第二频带中的RF信号的通过频率的信号通过滤波器的第二调谐滤波器，可操作以将从第二调谐滤波器输出的信号转换成中频信号的第二混频器，以及锁相环（PLL）电路，其可操作以控制本地振荡器的振荡频率和第一调谐滤波器和第二调谐滤波器的通过频率。

9. 发明授权

US08672143B2 Composite semipermeable membrane 有权
标题翻译：复合半透膜
公开(公告)号：US08672143B2
公开(公告)日：2014-03-18
申请号：US13579138
申请日：2011-03-28
申请人： Hiroki Minehara , Koji Nakatsuji
发明人： Hiroki Minehara , Koji Nakatsuji
IPC分类号： B01D71/06 , B01D39/00 , B01D39/14 , B01D29/46 , B01D67/00 , B05D5/00 , B01D71/70
CPC分类号： B01D71/70 , B01D65/022 , B01D67/0006 , B01D67/0027 , B01D69/12 , B01D71/78 , B01D71/82 , B01D2321/16 , B01D2321/343 , B01D2325/14 , C08G77/26 , C08L83/08 , Y02A20/131
摘要： Disclosed is a composite semipermeable membrane, which comprises a separation functional layer on a microporous support, and in which the separation functional layer is made of a condensation product of a polymer that has acidic groups and a trialkoxysilane groups having an imidazolium structure in side chains. The composite semipermeable membrane has excellent selective separation performance for divalent ions over monovalent ions, while exhibiting excellent long-term durability. Also disclosed is a method for producing the composite semipermeable membrane. The composite semipermeable membrane is suitable for uses in various water treatment fields such as the desalination of seawater and the production of drinking water. In addition, the composite semipermeable membrane does not deteriorate as much as conventional composite semipermeable membrane even in cases where the membrane is sterilized by having chlorine-containing raw water permeate therethrough continuously or intermittently.
摘要翻译：公开了一种复合半透膜，其包含在微孔载体上的分离功能层，其中分离功能层由具有酸性基团的聚合物和侧链上具有咪唑结构的三烷氧基硅烷基团的缩合产物制成。复合半透膜相对于一价离子具有优异的二价离子选择性分离性能，同时具有优异的长期耐久性。还公开了一种复合半透膜的制造方法。复合半透膜适用于各种水处理领域，如海水淡化和饮用水生产。此外，即使在通过使含有含氯原水的渗透通过其连续地或间歇地进行灭菌的情况下，复合半透膜也不会劣化常规的复合半透膜。

10. 发明申请

US20130313186A1 COMPOSITE SEMIPERMEABLE MEMBRANE AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：复合可切割膜及其制造方法
公开(公告)号：US20130313186A1
公开(公告)日：2013-11-28
申请号：US13882910
申请日：2011-12-05
申请人： Hiroki Minehara , Koji Nakatsuji , Hiroki Tomioka
发明人： Hiroki Minehara , Koji Nakatsuji , Hiroki Tomioka
IPC分类号： B01D71/70
CPC分类号： B01D71/70 , B01D67/0006 , B01D69/02 , B01D69/12 , B01D69/125 , B01D71/26 , B01D2323/345 , B01D2323/40 , B01D2325/14 , B01D2325/24
摘要： Provided is a composite semipermeable membrane comprising a microporous support membrane and a separation functional layer formed thereon, wherein the separation functional layer is formed from Compound (A) in which a reactive group(s) having an ethylenically unsaturated group and a hydrolyzable group(s) are bonded directly to a silicon atom, Compound (B) having an ethylenically unsaturated group, the Compound (B) being different from said Compound (A), and Compound (C) having an ethylenically unsaturated group, the Compound (C) being different from said Compound (A) and (B), by condensation of hydrolyzable groups that the Compound (A) has and polymerization of ethylenically unsaturated groups that the Compound (A), the Compound (B), and the Compound (C) have, and the Compound (A), the Compound (B), and the Compound (C) satisfy the relationship of the following equation (I): |QA−QC|+|QB−QC|=|QA−QB| (I) (QX represents an Alfrey-Price Q value of Compound X).A composite semipermeable membrane having excellent chemical resistivity to chemicals represented by chlorine, separation performance, and water permeability can be provided.
摘要翻译：本发明提供一种复合半透膜，其包含微孔载体膜和形成在其上的分离功能层，其中分离功能层由化合物（A）形成，其中具有烯属不饱和基团的反应性基团和可水解基团）直接键合到硅原子上，具有烯键式不饱和基团的化合物（B），化合物（B）与所述化合物（A）不同，和具有烯键式不饱和基团的化合物（C），化合物（C）与所述化合物（A）和（B）不同，通过化合物（A）与化合物（A），化合物（B）和化合物（C）具有的烯属不饱和基团的聚合反应的可水解基团的缩合化合物（A），化合物（B）和化合物（C）满足下式（I）的关系：| QA-QC | + | QB-QC | = | QA-QB |（I ）（QX表示化合物X的Alfrey-Price Q值）。可以提供对由氯表示的化学物质具有优异的化学电阻率的复合半透膜，分离性能和透水性。

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