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1. 发明授权

US4927452A 1-carbonyl-2-pyrazoline derivatives having herbicidal activity 失效
标题翻译：具有除草活性的1-羰基-2-吡唑啉衍生物
公开(公告)号：US4927452A
公开(公告)日：1990-05-22
申请号：US277529
申请日：1988-11-28
申请人： Kobus Wellinga , Jacobus H. H. Eussen
发明人： Kobus Wellinga , Jacobus H. H. Eussen
IPC分类号： A01N47/38 , A01P13/00 , C07C33/02 , C07C33/025 , C07D231/06 , C07D231/18 , C07D231/56 , C07D405/04 , C07D409/12
CPC分类号： A01N47/38 , C07C33/02 , C07C33/025 , C07D231/06 , C07D231/18 , C07D231/56 , C07D405/04 , C07D409/12
摘要： The invention relates to a herbicidally active compound of the general ##STR1## wherein R.sub.1, R.sub.2 R.sub.3 and R.sub.4 are equal or different and represent hydrogen atoms, alkyl groups having 1-6 carbon atoms, cycloalkyl groups having 3-6 carbon atoms or alkoxycarbonyl groups having 2-5 carbon atoms;R.sub.5 is a hydrogen atom, an alkyl group or haloalkyl group having 1-8 carbon atoms, a substituted or non-substituted phenyl group, a substituted or non-substituted heterocyclic group, or an alkenyl, alkynyl or alkoxycarbonyl group having 2-5 carbon atoms;and wherein two of the groups R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 together may form a straight or branched alkylene group having 3-5 carbon atoms;Ar is a phenyl group, a phenyl (C.sub.1 -C.sub.4)alkyl group or a heteroaryl group;R.sub.6 is a hydrogen atom or substitutent to Ar, which substituent, in case Ar is a phenyl or phenylalkyl group, is attached to the phenyl group in the ortho position with respect to the sulphonyl or sulphonylalkyl group, and which substituent is selected from the following atoms and groups: a halogen atom; a nitro group; an alkoxycarbonyl group that has 2-8 carbon atoms and is unsubstituted or substituted with one or more hydroxy or C.sub.1 -C.sub.4 alkoxy groups; and an alkyl, hydroxyalkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulphonyl and haloalkylsulphonyl group having 1-6 carbon atoms; andR.sub.7 represent a hydrogen atom or one or two halogen atoms or C.sub.1 -C.sub.4 alkyl groups.
摘要翻译：本发明涉及通用化合物（I）的除草活性化合物，其中R1，R2 + L，R3和R4相同或不同，代表氢原子，具有1-6个碳原子的烷基，具有3- 6个碳原子或具有2-5个碳原子的烷氧基羰基; R5为氢原子，具有1-8个碳原子的烷基或卤代烷基，取代或未取代的苯基，取代或未取代的杂环基或具有2-5个碳原子的烯基，炔基或烷氧基羰基原子并且其中基团R1，R2，R3，R4和R5中的两个可以一起形成具有3-5个碳原子的直链或支链亚烷基; Ar是苯基，苯基（C 1 -C 4）烷基或杂芳基; R6为氢原子或与Ar取代，在Ar为苯基或苯基烷基的情况下，该取代基与相对于磺酰基或磺酰基烷基的邻位苯基相连，该取代基选自下列原子和基团：卤素原子; 硝基; 具有2-8个碳原子且未被取代或被一个或多个羟基或C 1 -C 4烷氧基取代的烷氧基羰基; 和具有1-6个碳原子的烷基，羟基烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基磺酰基和卤代烷基磺酰基; 并且R 7表示氢原子或一个或两个卤素原子或C 1 -C 4烷基。

2. 发明授权

US4920135A Insecticidal ureas and thioureas 失效
标题翻译：杀虫脲和硫脲
公开(公告)号：US4920135A
公开(公告)日：1990-04-24
申请号：US306928
申请日：1989-02-07
申请人： Kobus Wellinga , Rudolf Wulder
发明人： Kobus Wellinga , Rudolf Wulder
IPC分类号： A01N43/50 , A01N43/54 , A01N43/88 , A01N47/34 , A01P7/02 , C07C67/00 , C07C275/54 , C07C301/00 , C07C303/40 , C07C311/39 , C07C313/00 , C07C315/04 , C07C317/42 , C07C319/20 , C07C323/44 , C07C325/00 , C07C327/50 , C07C335/26 , C07D213/75 , C07D233/66 , C07D233/72 , C07D273/04 , C07D317/66 , H01L27/00
CPC分类号： C07D233/66 , A01N43/50 , A01N43/54 , A01N43/88 , A01N47/34 , C07C275/54 , C07D233/72 , C07D273/04 , H01L27/00 , Y10S516/01
摘要： Certain organic compounds derived from urea or thiourea having insecticidal activity and methods of their preparation are disclosed. The compounds according to the invention have been found to interfere with the mechanism of metamorphoses which occurs in insects. Hence, the substances according to the invention are specifically active against insects. Owing to this specificity and because of the absence of phytotoxicity effects, the compounds of this invention are of prime importance.

3. 发明授权

US4854961A Substituted 2-phenylimino-oxazolidine compounds having herbicidal activity 失效
标题翻译：具有除草活性的取代的2-苯基亚氨基 - 恶唑烷化合物
公开(公告)号：US4854961A
公开(公告)日：1989-08-08
申请号：US114863
申请日：1987-10-30
申请人： Kobus Wellinga , Jacobus H. H. Eussen
发明人： Kobus Wellinga , Jacobus H. H. Eussen
IPC分类号： A01N43/76 , A01P13/00 , C07D263/48
CPC分类号： C07D263/48 , A01N43/76
摘要： The invention relates to a herbicidally and/or algicidally active compound of the general formula ##STR1## wherein R.sub.1 is a substituted or non-substituted alkyl group having 1-6 carbon atoms, or an alkenyl or alkynyl group having 2-6 carbon atoms;R.sub.2 is a halogen atom; a nitro group; a cyano group; a substituted or non-substituted benzyl, phenyl, phenoxy, phenylthio, phenylsulphinyl, phenylsulphonyl or phenylsulphonyloxy group; or a halogenated or non-halogenated alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl or alkylsulphonyloxy group having 1-4 carbon atoms;R.sub.3 is a hydrogen atom, a halogen atom, or an alkyl group having 1-4 carbon atoms; andX is O or S;or a salt of this compound with an organic or inorganic acid.

4. 发明授权

US4166124A Insecticidal 2,6-dihalobenzoyl urea derivatives 失效
标题翻译：杀虫剂2,6-二羟基苯甲酸尿衍生物
公开(公告)号：US4166124A
公开(公告)日：1979-08-28
申请号：US717633
申请日：1976-08-25
申请人： Kobus Wellinga , Rudolf Mulder
发明人： Kobus Wellinga , Rudolf Mulder
IPC分类号： C07C275/54 , A01N9/22
CPC分类号： C07C275/54
摘要： New 2,6-dihalobenzoyl urea derivatives and their use as insecticides.

5. 发明授权

US3991073A Pyrazoline compounds having insecticidal activity 失效
标题翻译：吡唑啉化合物具有杀虫活性
公开(公告)号：US3991073A
公开(公告)日：1976-11-09
申请号：US547991
申请日：1975-02-07
申请人： Rudolf Mulder , Kobus Wellinga
发明人： Rudolf Mulder , Kobus Wellinga
IPC分类号： A01N47/38 , C07D231/12 , C07D231/04
CPC分类号： C07D231/12 , A01N47/38
摘要： It has been found that novel pyrazoline compounds have a strong and specific biocidal activity against arthropods and especially insects. In addition to their more direct biocidal activity the novel compounds influence the pattern of motion of arthropods, which results in uncoordinated movements. A highly active substance is, for example, 1-(4-chlorophenylcarbamoyl)-3-(4-chlorophenyl)-5-(4-isopropoxyphenyl)-.DELTA..sup.2 -pyrazoline. After the substances have been worked up into preparations they can be used for controlling arthropods and especially insects which are pests in agriculture and horticulture and in industrial products.
摘要翻译：已经发现，新颖的吡唑啉化合物对节肢动物特别是昆虫具有很强的和特异性的杀生物活性。除了它们更直接的杀生物活性之外，新型化合物还影响节肢动物的运动模式，这导致不协调的运动。高活性物质是例如1-（4-氯苯基氨基甲酰基）-3-（4-氯苯基）-5-（4-异丙氧基苯基） - DELTA 2-吡唑啉。物质被加工成制剂后，可用于控制节肢动物，特别是农业，园艺和工业产品中的害虫。

6. 发明授权

US3989842A Certain substituted benzoyl urea insecticides 失效
标题翻译：某些取代的苯甲酰脲类杀虫剂
公开(公告)号：US3989842A
公开(公告)日：1976-11-02
申请号：US522058
申请日：1974-11-08
申请人： Kobus Wellinga , Rudolf Mulder
发明人： Kobus Wellinga , Rudolf Mulder
IPC分类号： C07C275/54 , A01N9/20
CPC分类号： C07C275/54
摘要： Organic compounds derived from urea or thiourea are used as active ingredients in insecticidal compositions.
摘要翻译：使用衍生自脲或硫脲的有机化合物作为杀虫组合物中的活性成分。

7. 发明授权

US4010271A Novel pyrazoline compounds having insecticidal activity 失效
标题翻译：具有杀虫活性的新型吡咯烷酮化合物
公开(公告)号：US4010271A
公开(公告)日：1977-03-01
申请号：US582308
申请日：1975-05-30
申请人： Rudolf Mulder , Kobus Wellinga
发明人： Rudolf Mulder , Kobus Wellinga
IPC分类号： A01N47/38 , C07D231/12 , A01N9/22
CPC分类号： C07D231/12 , A01N47/38
摘要： It has been found that novel pyrazoline compounds have a strong and specific biocidal activity against arthropods and especially insects. In addition to their more direct biocidal activity the novel compounds influence the pattern of motion of arthropods, which results in uncoordinated movements. A highly active substance is, for example, 1-(4-chlorophenylcarbamoyl)-3-(4-chlorophenyl)-5-(4-isopropoxyphenyl)-.DELTA..sup.2 -pyrazoline. After the substances have been worked up into preparations they can be used for controlling arthropods and especially insects which are pests in agriculture and horticulture and in industrial products.

8. 发明授权

US3933908A Substituted benzoyl ureas 失效
标题翻译：取代苯甲酰脲
公开(公告)号：US3933908A
公开(公告)日：1976-01-20
申请号：US354393
申请日：1973-04-25
申请人： Kobus Wellinga , Rudolf Mulder
发明人： Kobus Wellinga , Rudolf Mulder
IPC分类号： C07C275/54 , C07C127/22
CPC分类号： C07C275/54
摘要： New organic compounds derived from urea or thiourea, insecticidal preparations on the basis of the new substances and methods of producing the substances.
摘要翻译：来自脲或硫脲的新型有机化合物，以新物质为基础的杀虫剂及其制备方法。

9. 发明授权

US5342958A Organic compounds derived from urea or thiourea 失效
标题翻译：衍生自脲或硫脲的有机化合物
公开(公告)号：US5342958A
公开(公告)日：1994-08-30
申请号：US104645
申请日：1993-08-11
申请人： Kobus Wellinga , Rudolf Mulder
发明人： Kobus Wellinga , Rudolf Mulder
IPC分类号： A01N43/50 , A01N43/54 , A01N43/88 , A01N47/34 , C07C275/54 , C07D233/66 , C07D233/72 , C07D273/04 , H01L27/00 , C07D233/96
CPC分类号： A01N43/50 , A01N43/54 , A01N43/88 , A01N47/34 , C07C275/54 , C07D233/66 , C07D233/72 , C07D273/04 , H01L27/00
摘要： Compounds of the formula ##STR1## wherein A is a hydrogen atoms, a halogen atom, a methyl group, or a methoxy group;B is a hydrogen atom, a halogen atom, a methyl group, or a methoxy group, with the proviso that A and B ar not both a hydrogen atom;X and Y each are an oxygen atom or a sulfur atom;R is a hydrogen atom, an alkyl group, a hydroxy group, an alkoxy group, an alkoxymethyl group, an acyl group, or an alkoxycarbonyl group;R.sub.1 is a hydrogen atom, an alkyl group, a halogen substituted alkyl group, an alkoxy substituted alkyl group, an alkylthio substituted alkyl group, a cyano substituted alkyl group, a 1-cycloalkenyl group, a benzyl group, a halogen substituted benzyl group, a hydroxy group, an alkoxy group, an acyl group, an alkoxycarbonyl group, an alkoxythiocarbonyl group, an alkylsulfonyl group, or a phenylsulfonyl group, while furthermore R and R.sub.1 together with the group ##STR2## indicated in the above formula may form a ring system; and R.sub.2 is a substituted or non-substituted phenyl group or a pyridyl group that may be substituted with halogen, with nitro, with cyano, or with halogenated alkyl. The compounds have strong insecticidal activity against a wide variety of insects and function according to a unique mechanism. Specifically, the compounds are active against insects in the larval stage and are absorbed by the larva via its stomach to interfere with the mechanism of metamorphoses that occurs in insects.
摘要翻译：其中A为氢原子，卤原子，甲基或甲氧基的式IMA化合物; B是氢原子，卤素原子，甲基或甲氧基，条件是A和B不都是氢原子; X和Y各自为氧原子或硫原子; R是氢原子，烷基，羟基，烷氧基，烷氧基甲基，酰基或烷氧基羰基; R1是氢原子，烷基，卤素取代的烷基，烷氧基取代的烷基，烷硫基取代的烷基，氰基取代的烷基，1-环烯基，苄基，卤素取代的苄基，羟基，烷氧基，酰基，烷氧基羰基，烷氧基硫代羰基，烷基磺酰基或苯基磺酰基，此外，R和R 1与上式中所示的基团可以形成环系统; 并且R 2是可以被卤素，硝基，氰基或卤代烷基取代的取代或未取代的苯基或吡啶基。该化合物对各种昆虫具有很强的杀虫活性，并且具有独特的作用机制。具体来说，这些化合物对幼虫期的昆虫是有效的，并且被幼虫通过其胃吸收，以干扰昆虫中发生的变态机制。

10. 发明授权

US4833151A Insecticidal Ureas and thioureas 失效
标题翻译：杀虫脲和硫脲
公开(公告)号：US4833151A
公开(公告)日：1989-05-23
申请号：US867695
申请日：1986-05-28
申请人： Kobus Wellinga , Rudolf Mulder
发明人： Kobus Wellinga , Rudolf Mulder
IPC分类号： A01N43/50 , A01N43/54 , A01N43/88 , A01N47/34 , A01P7/02 , C07C67/00 , C07C275/54 , C07C301/00 , C07C303/40 , C07C311/39 , C07C313/00 , C07C315/04 , C07C317/42 , C07C319/20 , C07C323/44 , C07C325/00 , C07C327/50 , C07C335/26 , C07D213/75 , C07D233/66 , C07D233/72 , C07D273/04 , C07D317/66 , H01L27/00
CPC分类号： C07D233/66 , A01N43/50 , A01N43/54 , A01N43/88 , A01N47/34 , C07C275/54 , C07D233/72 , C07D273/04 , H01L27/00 , Y10S516/01
摘要： Certain organic compounds derived from urea or thio-urea having insectical activity and methods of their preparation are disclosed. The compounds according to the invention have been found to interfere with the mechanism of metamorphoses which occurs in insects. Hence, the substances according to the invention are specifically active against insects. Owing to this specificity and because of the absence of phytotoxicity effects, the compounds of this invention are of prime importance.
摘要翻译：公开了一些衍生自具有昆虫活性的尿素或硫脲的某些有机化合物及其制备方法。已经发现根据本发明的化合物干扰在昆虫中发生的变态机制。因此，根据本发明的物质对昆虫具有特异性的活性。由于这种特异性，并且由于没有植物毒性作用，本发明的化合物是至关重要的。

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