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    • 1. 发明授权
    • Dental curable composition
    • 牙科固化组合物
    • US08765837B2
    • 2014-07-01
    • US12742524
    • 2008-11-14
    • Kyoichi FujinamiAyumi DodomiKoji MatsushigeKazuhiko Okishio
    • Kyoichi FujinamiAyumi DodomiKoji MatsushigeKazuhiko Okishio
    • A61K31/121C08J3/28
    • A61K6/083A61K6/0073A61K6/0835C08F230/02C08L33/04C08L33/26C08F222/1006
    • [Problems] To provide a chemical polymerization type curable composition which can achieve a very large strength of adhesion even without irradiated with light, and is used in the field of dental therapy.[Means for Solution] A dental curable composition comprising (A) a polymerizable monomer component containing an acidic group-containing polymerizable monomer, (B) water, and (C) a chemical polymerization initiator component comprising a radical-generating species and a reactive species that generates radicals upon reacting with the radical-generating species; wherein, the dental curable composition is stored being divided into a plurality of packages, and is polymerized and cured by mixing together the components contained in the packages; and wherein one package (I) among the packages contains the component (A) and the component (B), and, further, contains polyvalent metal ions in an amount of 0.3 to 10 meq per gram of the polymerizable monomer component (A) contained in the package; and the chemical polymerization initiator (C) is stored being divided into at least two packages so that the radical-generating species and the reactive species do not come in contact with each other.
    • [问题]提供一种化学聚合型固化性组合物,其即使不用光照射即可实现非常大的粘合强度,并且用于牙科治疗领域。 [解决方案]一种牙科用固化性组合物,其包含(A)含有含酸性基团的可聚合单体的可聚合单体组分,(B)水和(C)包含自由基产生物质和反应性物质的化学聚合引发剂组分 与自由基产生物质反应产生自由基; 其中,所述牙科用固化性组合物被分割成多个包装,通过将所述包装物中所含的成分混合在一起聚合固化; 并且其中所述包装中的一个包装(I)包含组分(A)和组分(B),并且还包含每克所述可聚合单体组分(A)含有0.3至10meq的量的多价金属离子 在包装中; 并且化学聚合引发剂(C)被储存为至少两个包装,使得自由基产生物质和反应性物质不彼此接触。
    • 2. 发明授权
    • Dual-cure curable material kit
    • 双固化固化材料套件
    • US08993652B2
    • 2015-03-31
    • US13257855
    • 2009-12-08
    • Kyoichi FujinamiKazuhiko Okishio
    • Kyoichi FujinamiKazuhiko Okishio
    • A61L24/06C08J3/28C08F20/06C08F2/50C08F4/32C08F220/36
    • C08F4/32C08F2/50C08F220/36Y10S522/908
    • A dual-cure curable material kit comprising: (A) a radical-polymerizable monomer component; (B) a photopolymerization initiator component comprising (b1) an α-diketone compound, (b2) an aliphatic tertiary amine compound having a tertiary amino group in which three saturated aliphatic groups are bonded to a nitrogen atom and one of the saturated aliphatic groups has an electron-withdrawing group as a substituent, and (b3) an s-triazine compound having a trihalomethyl group as a substituent, or a diaryliodonium salt compound; and a chemical polymerization initiator component (C) comprising (c1) an organic peroxide, and (c2) an N,N-di(hydroxyalkyl)-p-toluidine compound; which is packed separately at least in two packages so that the component (b2) and the component (b3) of the photopolymerization initiator component (B) are not packed together in a single package and the component (c1) and the component (c2) of the chemical polymerization initiator component (C) are not packed together in a single package.
    • 一种双固化可固化材料试剂盒,其包含:(A)可自由基聚合的单体组分; (B)光聚合引发剂组分,其包含(b1)α-二酮化合物,(b2)具有三个饱和脂族基团与氮原子键合的叔氨基的脂族叔胺化合物和一个饱和脂族基团具有 吸电子基团作为取代基,(b3)具有三卤代甲基作为取代基的s-三嗪化合物或二芳基碘鎓盐化合物; 和(c1)有机过氧化物和(c2)N,N-二(羟烷基) - 对甲苯胺化合物的化学聚合引发剂组分(C) 其至少分成两个包装,使得光聚合引发剂组分(B)的组分(b2)和组分(b3)在单个包装中不被包装在一起,并且组分(c1)和组分(c2) 的化学聚合引发剂组分(C)不被一起包装在单个包装中。
    • 3. 发明申请
    • Dental Curable Composition
    • 牙科固化组合物
    • US20100261144A1
    • 2010-10-14
    • US12742524
    • 2008-11-14
    • Kyoichi FujinamiAyumi DodomiKoji MatsushigeKazuhiko Okishio
    • Kyoichi FujinamiAyumi DodomiKoji MatsushigeKazuhiko Okishio
    • A61C5/00A61C19/02
    • A61K6/083A61K6/0073A61K6/0835C08F230/02C08L33/04C08L33/26C08F222/1006
    • [Problems] To provide a chemical polymerization type curable composition which can achieve a very large strength of adhesion even without irradiated with light, and is used in the field of dental therapy.[Means for Solution] A dental curable composition comprising (A) a polymerizable monomer component containing an acidic group-containing polymerizable monomer, (B) water, and (C) a chemical polymerization initiator component comprising a radical-generating species and a reactive species that generates radicals upon reacting with the radical-generating species; wherein, the dental curable composition is stored being divided into a plurality of packages, and is polymerized and cured by mixing together the components contained in the packages; and wherein one package (I) among the packages contains the component (A) and the component (B), and, further, contains polyvalent metal ions in an amount of 0.3 to 10 meq per gram of the polymerizable monomer component (A) contained in the package; and the chemical polymerization initiator (C) is stored being divided into at least two packages so that the radical-generating species and the reactive species do not come in contact with each other.
    • [问题]提供一种化学聚合型固化性组合物,其即使不用光照射即可实现非常大的粘合强度,并且用于牙科治疗领域。 [解决方案]一种牙科用固化性组合物,其包含(A)含有含酸性基团的可聚合单体的可聚合单体组分,(B)水和(C)包含自由基产生物质和反应性物质的化学聚合引发剂组分 与自由基产生物质反应产生自由基; 其中,所述牙科用固化性组合物被分割成多个包装,通过将所述包装物中所含的成分混合在一起聚合固化; 并且其中所述包装中的一个包装(I)包含组分(A)和组分(B),并且还包含每克所述可聚合单体组分(A)含有0.3至10meq的量的多价金属离子 在包装中; 并且化学聚合引发剂(C)被储存为至少两个包装,使得自由基产生物质和反应性物质不彼此接触。
    • 4. 发明申请
    • DUAL-CURE CURABLE MATERIAL KIT
    • 双重固化材料套件
    • US20120059079A1
    • 2012-03-08
    • US13257855
    • 2009-12-08
    • Kyoichi FujinamiKazuhiko Okishio
    • Kyoichi FujinamiKazuhiko Okishio
    • A61K6/083
    • C08F4/32C08F2/50C08F220/36Y10S522/908
    • A dual-cure curable material kit comprising: (A) a radical-polymerizable monomer component; (B) a photopolymerization initiator component comprising (b1) an α-diketone compound, (b2) an aliphatic tertiary amine compound having a tertiary amino group in which three saturated aliphatic groups are bonded to a nitrogen atom and one of the saturated aliphatic groups has an electron-withdrawing group as a substituent, and (b3) an s-triazine compound having a trihalomethyl group as a substituent, or a diaryliodonium salt compound; and a chemical polymerization initiator component (C) comprising (c1) an organic peroxide, and (c2) an N,N-di(hydroxyalkyl)-p-toluidine compound; which is packed separately at least in two packages so that the component (b2) and the component (b3) of the photopolymerization initiator component (B) are not packed together in a single package and the component (c1) and the component (c2) of the chemical polymerization initiator component (C) are not packed together in a single package.
    • 一种双固化可固化材料试剂盒,其包含:(A)可自由基聚合的单体组分; (B)光聚合引发剂组分,其包含(b1)α-二酮化合物,(b2)具有三个饱和脂族基团与氮原子键合的叔氨基的脂族叔胺化合物和一个饱和脂族基团具有 吸电子基团作为取代基,(b3)具有三卤代甲基作为取代基的s-三嗪化合物或二芳基碘鎓盐化合物; 和(c1)有机过氧化物和(c2)N,N-二(羟烷基) - 对甲苯胺化合物的化学聚合引发剂组分(C) 其至少分成两个包装,使得光聚合引发剂组分(B)的组分(b2)和组分(b3)在单个包装中不被包装在一起,并且组分(c1)和组分(c2) 的化学聚合引发剂组分(C)不被一起包装在单个包装中。