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    • 2. 发明授权
    • Photographic elements for silver salt diffusion transfer process
containing mercapto imidazole stabilizers
    • US4520096A
    • 1985-05-28
    • US620204
    • 1984-06-13
    • Katsusuke EndoYoshio Inagaki
    • Katsusuke EndoYoshio Inagaki
    • G03C8/06G03C7/00G03C8/24G03C5/54G03C1/35
    • G03C8/243G03C7/00Y10S430/166
    • A photographic element for a silver salt diffusion transfer process is described, comprising a silver halide light-sensitive element, an image receiving element and a processing element, the improvement wherein said photographic element contains a compound represented by formula (I) or (II) ##STR1## wherein the R.sub.O s, which may be identical or different from one another each represents hydrogen, a halogen atom, an alkyl group, a substituted alkyl group, a substituted or unsubstituted cycloalkyl group, an alkoxy group, a substituted alkoxy group, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, a sulfamoyl group, an alkyl or arylsulfonamido group, a carbamoyl group, a carbonamido group, a heterocyclic group, a substituted or unsubstituted aryl group, an acyl group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted acyloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a primary amino group or a salt thereof, a secondary or tertiary amino group substituted by alkyl groups or aryl groups or the salt thereof, a nitro group, a hydroxyl group, a carboxyl group, a sulfonic acid group or a cyano group; R.sub.1 and R.sub.2 each represents hydrogen, an alkyl group, a substituted alkyl group or an aryl group; R.sub.3 and R.sub.4 each represents hydrogen, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or a heterocyclic group; R.sub.3 and R.sub.4 may form a 5- or 6-membered ring together with the nitrogen atom, wherein the ring may further contain hetero atoms; R.sub.5 and R.sub.6 each represents hydrogen, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or a heterocyclic group; A.sub.1 represents a divalent group; m represents an integer of 1 to 4; and n represents 1 or 2.
    • 3. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4493888A
    • 1985-01-15
    • US514216
    • 1983-07-15
    • Katsusuke EndoEiichi KatoNobutaka OhkiTakatoshi Ishikawa
    • Katsusuke EndoEiichi KatoNobutaka OhkiTakatoshi Ishikawa
    • G03C7/26C09B55/00G03C1/42G03C7/392G03C7/413G03C5/24G03C1/02
    • G03C7/4136G03C7/39284Y10S430/16
    • A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one organic metal complex represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## wherein M represents a divalent metal atom; R.sup.1 and R.sup.2, which may be the same or different, each represents an alkyl group having from 1 to 5 carbon atoms, a hydroxyalkyl group having from 1 to 5 carbon atoms, an alkoxyalkyl group having from 2 to 10 carbon atoms or an alkylsulfonamidoalkyl group having from 2 to 10 carbon atoms, or R.sup.1 and R.sup.2 may be bonded each other to form a heterocyclic ring together with the nitrogen atom; R.sup.3, represents a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms or an alkoxy group having from 1 to 5 carbon atoms; and R.sup.4 and R.sup.5, which may be the same or different, each represents a hydrogen atom, a halogen atom, a hydroxy group, an amino group, a carboxylic acid group, a sulfonic acid group, an alkoxycarbonyl group, an alkyl group or an alkoxy, or R.sup.4 and R.sup.5 may be bonded to each other to form a 5-membered or 6-membered ring.The compound represented by the general formula (I) is a precursor of a color developing agent which provides a sufficiently high color density on development and causes less desensitization and little fog or stain formation during storage of the photographic light-sensitive material containing thereof. A method of forming a color photographic image using the silver halide photographic light-sensitive material is also disclosed.
    • 一种含有扩散阻抗成色剂,感光卤化银和由以下通式(I)表示的至少一种有机金属络合物的卤化银照相感光材料,在支持体上相同层或不同层。 其中M表示二价金属原子; 可以相同或不同的R 1和R 2各自表示具有1至5个碳原子的烷基,具有1至5个碳原子的羟烷基,具有2至10个碳原子的烷氧基烷基或烷基磺酰胺基烷基 具有2至10个碳原子,或者R 1和R 2可以彼此键合以与氮原子一起形成杂环; R3表示氢原子,具有1至5个碳原子的烷基或具有1至5个碳原子的烷氧基; R 4和R 5可以相同或不同,分别表示氢原子,卤素原子,羟基,氨基,羧酸基,磺酸基,烷氧基羰基,烷基或 烷氧基或R 4和R 5可以彼此键合以形成5元或6元环。 由通式(I)表示的化合物是彩色显影剂的前体,其在显影时提供足够高的色密度,并且在含有它们的照相感光材料的储存期间引起较少的脱敏和很少的灰雾或污迹形成。 还公开了使用卤化银照相感光材料形成彩色照相图像的方法。
    • 4. 发明授权
    • Photographic light-sensitive sheet for the color diffusion transfer
process
    • 用于彩色扩散转印过程的照相感光片
    • US4245028A
    • 1981-01-13
    • US013998
    • 1979-02-21
    • Shinsaku FujitaTooru HaradaKatsusuke Endo
    • Shinsaku FujitaTooru HaradaKatsusuke Endo
    • G03C8/10G03C1/40G03C1/10
    • G03C8/10
    • A photographic light-sensitive sheet for the color diffusion transfer process which comprises a support having thereon at least one light-sensitive silver halide emulsion layer with at least one of said silver halide emulsion layers having associated therewith a compound represented by the following general formula (I): ##STR1## wherein Q represents a cyano group, a trifluoromethyl group or a carbamoyl group represented by the formula --CONR.sup.3 R.sup.4 wherein R.sup.3 represents a hydrogen atom or an alkyl group; R.sup.4 represents a hydrogen atom, an alkyl group, an aralkyl group or an aryl group; and R.sup.3 and R.sup.4 may combine directly or through an oxygen atom to form a ring; M represents a hydrogen atom, an alkyl group, an alkoxy group, a sulfamoyl group represented by the formula --SO.sub.2 NR.sup.3 R.sup.4, wherein R.sup.3 and R.sup.4 are as defined above, a group represented by the formula --COOR.sup.5 wherein R.sup.5 represents an alkyl group, a phenyl group or a substituted phenyl group; or a halogen atom; R.sup.1a and R.sup.1b, which may be the same or different, each represents an alkylene group having 2 or more carbon atoms; R.sup.2a and R.sup.2b, which may be the same or different each represents an alkyl group, Y represents a moiety which releases or provides, as a result of development processing under alkaline conditions, an azo dye having a different diffusibility from that of said dye image-providing material and m represents 0 or 1.The compound is a dye image providing material which provides a yellow dye image having excellent properties.
    • 一种用于颜色扩散转移方法的照相感光片,其包括其上具有至少一个感光卤化银乳剂层的支撑体,其中至少一个所述卤化银乳剂层具有与下列通式( I):其中Q表示氰基,三氟甲基或由式-CONR 3 R 4表示的氨基甲酰基,其中R 3表示氢原子或烷基; R4表示氢原子,烷基,芳烷基或芳基; 并且R 3和R 4可以直接或通过氧原子结合形成环; M表示氢原子,烷基,烷氧基,由式-SO2NR3R4表示的氨磺酰基,其中R3和R4如上定义,由式-COOR5表示的基团,其中R5表示烷基,苯基 基团或取代的苯基; 或卤素原子; 可以相同或不同的R 1a和R 1b各自表示具有2个或更多个碳原子的亚烷基; 可以相同或不同的R 2a和R 2b各自表示烷基,Y表示作为在碱性条件下显影处理的结果,释放或提供与所述染料影像相比具有不同扩散性的偶氮染料的部分, 提供材料,m表示0或1.化合物是提供具有优异性质的黄色染料图像的染料图像提供材料。
    • 6. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4473635A
    • 1984-09-25
    • US495873
    • 1983-05-18
    • Takatoshi IshikawaKatsusuke EndoSigeru KuwazimaEiichi KatoNobutaka Ohki
    • Takatoshi IshikawaKatsusuke EndoSigeru KuwazimaEiichi KatoNobutaka Ohki
    • G03C1/42G03C1/43G03C7/26G03C7/30G03C5/24G03C1/02
    • G03C1/43Y10S430/16
    • A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one compound represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## Wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom or an alkyl group having from 1 to 10 carbon atoms, or R.sub.1 and R.sub.2 may be bonded to each other to form a heterocyclic ring together with the nitrogen atom; R.sub.3, R.sub.4, R.sub.5 and R.sub.6, which may be the same or different, each represents a hydrogen atom, a halogen atom, a hydroxy group, an amino group, an alkoxy group, an acylamido group, a sulfonamido group, an alkylsulfonamido group or an alkyl group, or R.sub.1 and R.sub.6 or R.sub.2 and R.sub.3 may be bonded to each other to form a 5-membered or 6-membered ring; X represents HPF.sub.6 or HBF.sub.4 ; and n represents an integer from 1 to 3.The compound represented by the general formula (I) is a precursor of a color developing agent which provides a sufficiently high color density on development and causes less desensitization and little formation of fogs or stains during storage of the photographic light-sensitive material containing thereof. A method of forming a color photographic image using the silver halide photographic light-sensitive material is also disclosed.
    • 一种含有扩散阻抗成色剂,感光卤化银和至少一种由下述通式(I)表示的化合物的卤化银照相感光材料,在载体上的相同层或不同层中。 (I)其中R1和R2可以相同或不同,各自表示氢原子或具有1-10个碳原子的烷基,或者R1和R2可以彼此键合形成杂环基 与氮原子一起环; 可以相同或不同的R 3,R 4,R 5和R 6各自表示氢原子,卤素原子,羟基,氨基,烷氧基,酰基酰氨基,亚磺酰氨基,烷基磺酰氨基或 烷基或R 1和R 6或R 2和R 3可以彼此键合形成5元或6元环; X代表HPF6或HBF4; 并且n表示1至3的整数。由通式(I)表示的化合物是彩色显影剂的前体,其在显影时提供足够高的色密度,并且在储存期间引起较少的脱敏和很少的雾或污渍形成 的摄影感光材料。 还公开了使用卤化银照相感光材料形成彩色照相图像的方法。