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    • 2. 发明授权
    • Process for producing dysprosium-iron alloy and
neodymium-dysprosium-iron alloy
    • 生产镝铁合金和钕镝铁合金的方法
    • US4737248A
    • 1988-04-12
    • US941040
    • 1986-12-12
    • Eiji NakamuraKatsuhisa ItohMasahiro NishioMikio Sakakibara
    • Eiji NakamuraKatsuhisa ItohMasahiro NishioMikio Sakakibara
    • C22B59/00C25C3/34C25C7/00C25C3/36
    • C25C3/34C22B59/00C25C7/005
    • A process and an apparatus for producing a dysprosium-iron alloy or a neodymium-dysprosium-iron alloy by electrolytic reduction of dysprosium fluoride or neodymium fluoride and dysprosium fluoride in a bath of molten electrolyte, consisting essentially of 20-95% by weight of dysprosium fluoride or a mixture of neodymium fluoride and dysprosium fluoride, 5-80% by weight of lithium fluoride, up to 40% by weight or barium fluoride and up to 20% by weight of calcium fluoride, conducted between one or more iron cathode and one or more carbon anode. The apparatus comprises an electrowinning cell of refractory materials coated inside with a lining resistive to the bath, the carbon anode of constant transverse cross-sectional shape over its length, immersed in the electrolyte bath at its free end, the iron cathode of constant transverse cross-sectional shape over its length, immersed in the electrolyte bath at its free end, a receiver placed on the bottom of the cell for collecting the produced dysprosium-iron alloy or neodymium-dysposium-iron alloy in a liquid state on the tip of the iron cathode, siphoning means for withdrawing the molten alloy pooled in the receiver out of the cell, and feeding means for feeding the iron cathode into the electrolyte bath so as to apply the direct current to the iron cathode with a predetermined current density.
    • 一种生产镝铁合金或钕 - 镝 - 铁合金的方法和装置,其通过在熔融电解液浴中电解还原氟化镝或氟化钕和氟化镝,基本上由20-95%重量的镝 氟化物或氟化钕和氟化镝的混合物,5-80重量%的氟化锂,至多40重量%或氟化钡和至多20重量%的氟化钙,在一个或多个铁阴极和一个 或更多的碳阳极。 该装置包括涂覆在其内部的耐熔材料的电解沉积池,其具有抵抗浴的衬里,其长度上具有恒定横截面形状的碳阳极,浸入其自由端的电解液浴池中,恒定横向交叉的铁阴极 在其长度上的截面形状,浸入其自由端的电解质浴中,放置在电池底部的接收器,用于收集在液体状态下产生的镝铁合金或钕 - 铁基 - 铁合金 铁阴极,用于将收集在接收器中的熔融合金排出电池的虹吸装置,以及用于将铁阴极供入电解质浴中以将电流以预定电流密度施加到铁阴极的馈送装置。
    • 7. 发明授权
    • Process of producing neodymium-iron alloy
    • 生产钕铁合金的工艺
    • US4684448A
    • 1987-08-04
    • US776800
    • 1985-09-17
    • Katsuhisa ItohYoshiaki WatanabeEiji NakamuraMasayasu Toyoshima
    • Katsuhisa ItohYoshiaki WatanabeEiji NakamuraMasayasu Toyoshima
    • C25C3/34C25C7/00C25C3/36
    • C25C7/005C25C3/34
    • A process and an apparatus for producing a neodymium-iron alloy by electrolysis reduction of neodymium fluoride in a bath of molten electrolyte, consisting essentially of 35-76% by weight of neodymium fluoride, 20-60% by weight of lithium fluoride, up to 40% by weight of barium fluoride and up to 20% by weight of calcium fluoride, conducted between one or more iron cathode and one or more carbon anode. The apparatus comprises an electrowinning cell of refractory materials coated inside with a lining resistive to the bath, the carbon anode of constant transverse cross-sectional shape over its length, immersed into the electrolyte bath at its free and, the iron cathode of constant transverse cross-sectional shape over its length, immersed into the electrolytic bath at its free end, a receiver placed on the bottom of the cell for collecting the produced neodymium-iron alloy in a liquid state on the tip of the iron cathode, siphoning means for withdrawing the molten alloy pooled in the receiver out of the cell, and feeding means for feeding the ever wearing iron cathode into the electrolyte bath so as to apply the direct current to the iron cathode with a predetermined current density.
    • 一种用于通过在熔融电解质浴中电解还原氟化钕来生产钕 - 铁合金的方法和装置,其基本上由35-76重量%的氟化钕,20-60重量%的氟化锂组成,直至 在一个或多个铁阴极和一个或多个碳阳极之间进行40重量%的氟化钡和至多20重量%的氟化钙。 该装置包括涂覆在其内部的耐熔材料的电解沉积池,其具有耐熔池的衬里,其长度上具有恒定横截面形状的碳阳极,浸入其游离的电解质浴池中,并且恒定横向交叉的铁阴极 在其长度上的截面形状,浸入其自由端的电解浴中,放置在电池底部的接收器,用于在铁阴极的尖端上收集液态的所生产的钕 - 铁合金,用于抽出的虹吸装置 将熔融合金收集在电池内的接收器中,以及馈送装置,用于将经过磨损的铁阴极供入电解槽中,以便以预定电流密度将直流施加到铁阴极。
    • 8. 发明授权
    • Method for manufacturing glass preform and glass fiber
    • 制造玻璃预制件和玻璃纤维的方法
    • US06053012A
    • 2000-04-25
    • US9873
    • 1998-01-21
    • Katsuhisa Itoh
    • Katsuhisa Itoh
    • G02B6/00C03B37/012C03B37/014C03B37/027C03C13/04C03C15/00C03C3/32C03B37/075C03C13/00
    • C03B37/027C03B37/012C03B37/01211C03B37/01274C03C13/043C03C15/00C03B2201/86Y10S65/15
    • A method for manufacturing a glass preform from a metal sulfide chalcogenide glass to which a large amount of light emitting substances can be added includes steps of etching a surface made of the chalcogenide glass or oxychalcogenide glass of disc shape core and clad forming glass starting materials by an etchant including an acid and a compound reacting with a hydrogen chalcogenide, and forming the core forming glass starting material and the clad forming glass starting material into a united body serving as a glass preform. In a method for manufacturing a single-mode glass fiber using a preform method by drawing the glass preform whose outer round surface is made of a chalcogenide glass or oxychalcogenide glass, the outer round surface of the glass preform is etched using an etchant including an acid and a compound reacting with a hydrogen chalcogenide and then drawn into the glass fiber. In another method for manufacturing a glass fiber by drawing a rod-in-tube in which an outer round surface of the rod and inner and outer round surfaces of the tube are made of a chalcogenide glass or oxychalcogenide glass, the round surfaces made of the chalcogenide glass or oxychalcogenide glass are etched by the etchant including an acid and a compound reacting with a hydrogen chalcogenide and then drawn into the glass fiber.
    • 从可以添加大量发光物质的金属硫化物硫族化物玻璃制造玻璃预制体的方法包括以下步骤:通过以下步骤:蚀刻由盘状芯的硫族化物玻璃或氧化硫化物玻璃制成的表面,以及包覆成形玻璃原料,由 包括酸和与氢硫族化合物反应的化合物的蚀刻剂,以及将形成芯的玻璃起始材料和包层成形玻璃起始材料形成为用作玻璃预制件的联合体。 在使用预成型法制造单模玻璃纤维的方法中,通过拉制其外圆表面由硫族化物玻璃或氧化硫化物玻璃制成的玻璃预制件,使用包括酸的蚀刻剂来蚀刻玻璃预制件的外圆面 和与氢硫族化合物反应然后吸入玻璃纤维的化合物。 在另一种制造玻璃纤维的方法中,通过拉伸杆的外圆表面和管的内外圆表面由硫族化物玻璃或氧化硫化物玻璃制成的管内管,由 硫属化物玻璃或氧化硫化物玻璃被蚀刻剂蚀刻,包括酸和与氢硫族化合物反应的化合物,然后被吸入玻璃纤维中。
    • 10. 发明授权
    • Electrolytic method of producing a high purity aluminum-lithium mother
alloy
    • 生产高纯度铝锂母合金的电解方法
    • US4521284A
    • 1985-06-04
    • US661554
    • 1984-10-17
    • Zenichi TanabeKatsuhisa ItohYoshiaki Watanabe
    • Zenichi TanabeKatsuhisa ItohYoshiaki Watanabe
    • C25C3/02C25C3/00C25C3/36
    • C25C3/00
    • A method of producing high purity aluminum-lithium mother alloys essentially free from other alkali metals than lithium, which comprises electrolyzing a mixed molten salts consisting of 34 to 64 wt. % of lithium chloride and 66 to 36 wt. % of potassium chloride, and, optionally, 1 to 20 wt. % of sodium chloride based on a combined weight of the aforesaid two components, using solid aluminum as cathodes, and an .alpha.+.beta. phase aluminum lithium alloy electrode or the alloy coated electrode as a reference electrode, under a current density in the range of 0.005 to 1 A/cm.sup.2, whereby producing aluminum-lithium alloys on the cathode. During electrolyzing, the potential difference between the cathode and the reference electrode is continuously measured and differentiated with respect to time and at the point of a sudden change in the differentiated value, electrolyzing is stopped.
    • 一种生产基本上不含锂的其它碱金属的高纯度铝 - 锂母体合金的方法,包括电解由34-64重量% 氯化锂和66〜36重量% 的氯化钾,和任选的1至20wt。 基于上述两种组分的组合重量,使用固体铝作为阴极,和α+β相铝锂合金电极或合金涂覆电极作为参比电极,在电流密度为0.005 至1A / cm 2,由此在阴极上制造铝 - 锂合金。 在电解过程中,阴极和参考电极之间的电位差在时间上和分辨值突然变化的时刻连续测量和区分,电解停止。