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    • 2. 发明授权
    • Plastic molding composition
    • 塑料成型组合物
    • US4244860A
    • 1981-01-13
    • US51422
    • 1979-06-25
    • Werner KuhnelKarl-Gunter ScharfPaul SpielauRichard Weiss
    • Werner KuhnelKarl-Gunter ScharfPaul SpielauRichard Weiss
    • C08K5/00C08K5/54C08K5/5425C08L1/00C08L27/00C08L27/06C08K9/06
    • C08K5/54
    • A process for preventing separation of fillers and other dispersed additives from thermoplastic molding compositions during extrusion, calendering or like processing, along metallic contact surfaces of a processing unit, involves admixing a silane additive to a portion of a thermoplastic molding composition containing a thermoplastic molding resin and at least one filler or other dispersed additive that tends to separate out from the molding composition during the processing, processing the portion of thermoplastic molding composition in a processing unit, measuring the electrical energy applied to the processing unit during processing per kilogram of molding composition per unit time, determining if the electrical energy applied has been increased by the addition of the silane additive as compared to the electrical energy required per kilogram of molding composition per unit time for processing another portion of the thermoplastic molding composition free of the silane additive and thereafter adding an effective amount of the silane additive determined to be capable of increasing the applied electrical energy required to process the molding composition by at least 20% with the thermoplastic molding composition and processing the resulting thermoplastic molding composition in the processing unit. Among the silane additives disclosed as being suitable for this process are .beta.-chloroethyl triethoxysilane and vinyl trialkoxysilanes containing alkoxy groups having from 1 to 6 carbon atoms.
    • 沿着加工单元的金属接触表面,在挤出,压延或类似加工期间,防止填料和其它分散添加剂从热塑性模塑组合物中分离的方法包括将硅烷添加剂与包含热塑性模塑树脂的热塑性模塑组合物的一部分混合 以及至少一种填料或其它分散的添加剂,其倾向于在加工期间与成型组合物分离出来,在处理单元中处理热塑性模塑组合物的该部分,测量在每千克模塑组合物的加工期间施加到处理单元的电能 每单位时间,通过添加硅烷添加剂而增加的电能与每单位时间每千克成型组合物所需的电能相比是否增加,用于处理不含硅烷添加剂的热塑性模塑组合物的另一部分,以及 th 之后加入有效量的硅烷添加剂被确定为能够使用热塑性模塑组合物将加工模塑组合物所需的施加的电能增加至少20%,并将所得到的热塑性模塑组合物加工到处理单元中。 在适用于该方法的硅烷添加剂中,含有具有1至6个碳原子的烷氧基的β-氯乙基三乙氧基硅烷和乙烯基三烷氧基硅烷。