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    • 5. 发明申请
    • Method for Producing Metal-containing Nanoparticles Enveloped with Polymers and Particles that can be Obtained Therefrom
    • 生产含有聚合物和颗粒的含金属纳米颗粒的方法
    • US20120302703A1
    • 2012-11-29
    • US13147146
    • 2010-02-01
    • Andreas GreinerSeema AgarwalJulia SchmidtStefan Bokern
    • Andreas GreinerSeema AgarwalJulia SchmidtStefan Bokern
    • C08F8/42C08F20/14C08F12/08B82Y99/00
    • C08F6/12A01N55/00B01J13/02B82Y30/00C08K3/08C08K9/08C08K9/10C09D5/14C09D5/24C09D7/62A01N25/26A01N25/34A01N2300/00
    • The present invention provides a method to produce metal-containing nanoparticles enveloped with polymers, as well as particles obtainable therefrom.In the method according to the present invention, at least one anionic polymerizable monomer is polymerized in the presence of an anionic macroinitiator at room temperature. Subsequently, an aliphatic or aromatic sulfide is firstly added, followed by a solution of at least one organosoluble metal salt in an aprotic organic solvent and finally a homogeneous reducing agent. The metal cation is hereby reduced to the metal. Metal-containing nanoparticles are formed which are covalently bonded to the growing anionic polymerizates.The metal salts are preferably salts of silver, copper, gold, tin, lead, chrome or zinc, or mixtures thereof. Anionic polymerizable monomers comprise, by way of example, styrene (St), butadiene, isoprene, ethylene oxide, propylene oxide, caprolactone, lactide, glycolide, acrylates, methacrylates, bisacrylates, cyanoacrylates, amides, siloxanes, vinylpyridines or acrylonitrile.The particles according to the present invention are suitable to be used for the antibacterial finishing of polymers in textiles and materials. Furthermore, they are suitable for the production of inks. If the underlying metals are those metals that show plasmon resonance, the particles are suitable to also be applied in sensors which use the plasmon resonance effect.The metal-containing nanoparticles enveloped with polymers which are accessible using the method according to the present invention do not aggregate or agglomerate, and their physical and chemical properties remain unchanged over a long period of time.
    • 本发明提供一种制备包封有聚合物的含金属纳米颗粒的方法,以及由其获得的颗粒。 在根据本发明的方法中,至少一种阴离子可聚合单体在阴离子大分子引发剂的存在下在室温下聚合。 随后,首先加入脂族或芳族硫化物,然后加入至少一种有机溶剂金属盐在非质子有机溶剂中的溶液,最后加入均匀的还原剂。 因此金属阳离子被还原成金属。 形成含金属的纳米颗粒,其与生长的阴离子聚合物共价键合。 金属盐优选为银,铜,金,锡,铅,铬或锌的盐,或其混合物。 阴离子可聚合单体包括例如苯乙烯(St),丁二烯,异戊二烯,环氧乙烷,环氧丙烷,己内酯,丙交酯,乙交酯,丙烯酸酯,甲基丙烯酸酯,双丙烯酸酯,氰基丙烯酸酯,酰胺,硅氧烷,乙烯基吡啶或丙烯腈。 根据本发明的颗粒适合用于织物和材料中聚合物的抗菌整理。 此外,它们适用于油墨的生产。 如果下面的金属是显示等离子体共振的那些金属,则该颗粒也适用于也使用等离子体共振效应的传感器。 用聚合物包裹的含金属纳米颗粒可以使用根据本发明的方法进行接触,不会聚集或附聚,并且其物理和化学性质在长时间内保持不变。