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1. 发明授权

US06353001B1 2-nitromethylidene/2-cyanimino/2-nitro-imino-pyrrolidines and piperidines, intermediates, and their use as pesticides 失效
标题翻译： 2-硝基亚甲基/ 2-氰基亚氨基/ 2-硝基 - 亚氨基 - 吡咯烷酮和哌啶，中间体及其作为农药的用途
公开(公告)号：US06353001B1
公开(公告)日：2002-03-05
申请号：US09501464
申请日：2000-02-09
申请人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
发明人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
IPC分类号： A61K3144
CPC分类号： C07D401/06 , A01N43/40 , A01N47/38 , A01N51/00 , C07D417/06
摘要： Compounds of formula: wherein A is an unsubstituted or substituted aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical wherein a ring nitrogen atom may have been replaced by a group R1 is hydrogen or C1-C3alkyl; R2 is hydrogen or C1-C3alkyl; R3 is hydrogen, an unsubstituted or substituted C1-C6alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl group, or C(═O)—R5, R5 is C1-C4alkyl, C1-C4alkoxy, an unsubstituted or substituted phenyl, phenoxy or benzyloxy group, or N(R6)2, each R6, independently of the other, is hydrogen, C1-C4alkyl or unsubstituted or substituted phenyl, X is CH—NO2, N—CN or N—NO2 and n is from 1 to 3, in free form or in salt form, and, where appropriate, tautomers of those compounds and the salts thereof, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：下式的化合物：其中A是未取代或取代的芳环或非芳族单环或双环杂环基，其中环氮原子可以被基团R 1取代为氢或C 1 -C 3烷基; R 2是氢或C 1 -C 3烷基; R 3是氢，未取代或取代的C1-C6烷基，C3-C6环烷基，C2-C6链烯基或C2-C6炔基，或C（= O）-R5，R5是C1-C4烷基，C1-C4烷氧基，未取代或取代的苯基，苯氧基或苄基氧基或N（R6）2，各自独立地为氢，C1-C4烷基或未取代或取代的苯基，X为CH-NO2，N-CN或N-NO2，n为1至3，游离形式或盐形式，并且在适当时，这些化合物及其盐的互变异构体可用作农业化学活性成分，并且可以以本身已知的方式制备。

2. 发明授权

US06664248B2 2-nitromethylidene/2-cyanimino/2-nitro-imino-pyrrolidines and piperidines, intermediates, and their use as pesticides 失效
标题翻译： 2-硝基亚甲基/ 2-氰基亚氨基/ 2-硝基 - 亚氨基 - 吡咯烷酮和哌啶，中间体及其作为农药的用途
公开(公告)号：US06664248B2
公开(公告)日：2003-12-16
申请号：US10341555
申请日：2003-01-13
申请人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
发明人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
IPC分类号： A61K3133
CPC分类号： C07D401/06 , A01N43/40 , A01N47/38 , A01N51/00 , C07D417/06
摘要： Compounds of formula wherein A is an unsubstituted or substituted aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical wherein a ring nitrogen atom may have been replaced by a group R1 is hydrogen or C1-C3alkyl; R2 is hydrogen or C1-C3alkyl; R3 is hydrogen an unsubstituted or substituted C1-C6alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl group, or C(═O)—R5, R5 is C1-C4alkyl, C1-C4alkoxy, an unsubstituted or substituted phenyl, phenoxy or benzyloxy group, or N(R6)2, each R6, independently of the other, is hydrogen, C1-C4alkyl or unsubstituted or substituted phenyl, X is CH—NO2, N—CN or N—NO2 and n is from 1 to 3, in free form or in salt form, and, where appropriate, tautomers of those compounds and the salts thereof, can be used as agrochemical active ingredients and can be prepared in a manner known per se
摘要翻译：马来酰亚胺A的化合物是未取代或取代的芳族或非芳族单环或双环杂环基，其中环氮原子可以被基团R 1取代为氢或C 1 -C 3烷基; R 2是氢或C 1 -C 3烷基; R 3是氢未取代或取代的C 1 -C 6烷基，C 3 -C 6环烷基，C 2 -C 6烯基或C 2 -C 6炔基，或C（= O）-R 5，R 5是C 1 -C 4烷基，C 1 -C 4烷氧基，未取代或取代的苯基，苯氧基或苄氧基，或N（R 6）2，每个R 6彼此独立地为氢，C 1 -C 4烷基或未取代或取代的苯基，X为CH-NO 2，N-CN或N-NO 2，n为1至3，为游离形式或盐形式，并且在适当的情况下，这些化合物及其盐的互变异构体可用作农业化学活性成分，并且可以以本身已知的方式制备

3. 发明授权

US06506743B2 2-nitromethylidene/2-cyanimino/2-nitro-imino-pyrrolidines and piperidines, intermediates, and their use as pesticides 失效
标题翻译： 2-硝基亚甲基/ 2-氰基亚氨基/ 2-硝基 - 亚氨基 - 吡咯烷酮和哌啶，中间体及其作为农药的用途
公开(公告)号：US06506743B2
公开(公告)日：2003-01-14
申请号：US10013778
申请日：2001-12-11
申请人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
发明人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
IPC分类号： C07D4006
CPC分类号： C07D401/06 , A01N43/40 , A01N47/38 , A01N51/00 , C07D417/06
摘要： Compounds of formula wherein A is an unsubstituted or substituted aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical wherein a ring nitrogen atom may have been replaced by a group R1 is hydrogen or C1-C3alkyl; R2 is hydrogen or C1-C3alkyl; R3 is hydrogen, an unsubstituted or substituted C1-C3-C6alkyl, C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl group, or C(═O)—R5, R5 is C1-C4alkyl, C1-C4alkoxy, an unsubstituted or substituted phenyl, phenoxy or benzyloxy group, or N(R6)2, each R6, independently of the other, is hydrogen, C1-C4alkyl or unsubstituted or substituted phenyl, X is CH—NO2, N—CN or N—NO2 and n is from 1 to 3, in free form or in salt form, and, where appropriate, tautomers of those compounds and the salts thereof, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：马来酰亚胺碱A的化合物是未取代或取代的芳族或非芳族单环或双环杂环基，其中环氮原子可以被基团R 1取代为氢或C 1 -C 3烷基; R 2是氢或C 1 -C 3烷基; R 3是氢，未取代或取代的C1-C3-C6烷基，C6环烷基，C2-C6链烯基或C2-C6炔基，或C（= O）-R5，R5是C1-C4烷基，C1-C4烷氧基，未取代或取代的苯基，苯氧基或苄氧基，或N（R 6）2，每个R 6彼此独立地是氢，C 1 -C 4烷基或未取代或取代的苯基，X是CH-NO 2，N-CN或N-NO 2，并且n为1至3，形式或盐形式，并且在适当的情况下，这些化合物及其盐的互变异构体可以用作农业化学活性成分，并且可以以本身已知的方式制备。

4. 发明授权

US6048824A 2-nitromethylidene/2-cyanimino/2-nitro-imino-pyrrolidines and piperidines, intermediates, and their use as pesticides 失效
标题翻译： 2-硝基亚甲基/ 2-氰基亚氨基/ 2-硝基 - 亚氨基 - 吡咯烷酮和哌啶，中间体及其作为农药的用途
公开(公告)号：US6048824A
公开(公告)日：2000-04-11
申请号：US532553
申请日：1995-11-22
申请人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
发明人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
IPC分类号： A01N43/36 , A01N43/40 , A01N43/54 , A01N43/58 , A01N43/84 , A01N43/86 , A01N43/88 , A01N47/38 , A01N51/00 , C07D401/06 , C07D417/06
CPC分类号： C07D401/06 , A01N43/40 , A01N47/38 , A01N51/00 , C07D417/06
摘要： Compounds of formula (I), wherein A is an unsubstituted or substituted aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical wherein a ring nitrogen atom may have been replaced by a group ##STR2## R.sub.1 is hydrogen or C.sub.1 -C.sub.3 alkyl; R.sub.2 is hydrogen or C.sub.1 -C.sub.3 alkyl; R.sub.3 is hydrogen, an unsubstituted or substituted C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl C.sub.2 -C.sub.6 alkenyl or C.sub.2 -C.sub.6 alkynyl group, or C(.dbd.O)--R.sub.5, R.sub.5 is C.sub.1 -C.sub.4 alkyl C.sub.1 -C.sub.4 alkoxy, an unsubstituted or substituted phenyl, phenoxy or benzyloxy group, or N(R.sub.6).sub.2, each R.sub.6, independently of the other, is hydrogen, C.sub.1 -C.sub.4 alkyl or unsubstituted or substituted phenyl, X is CH--NO.sub.2, N--CN or N--NO.sub.2 and n is from 1 to 3, in free form or in salt form, and, where appropriate, tautomers of those compounds and the salts thereof, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译： PCT No.PCT / EP94 / 00963 Sec。 371日期：1995年11月22日 102（e）日期1995年11月22日PCT 1994年3月26日PCT公布。出版物WO94 / 24124 日期：1994年10月27日，式（I）化合物其中A是未取代或取代的芳环或非芳香单环或双环杂环基，其中环氮原子可以被基团R 1取代为氢或C 1 -C 3烷基; R2是氢或C1-C3烷基; R3是氢，未取代或取代的C1-C6烷基，C3-C6环烷基C2-C6链烯基或C2-C6炔基，或C（= O）-R5，R5是C1-C4烷基C1-C4烷氧基，未取代或取代的苯基，苯氧基或苄基氧基或N（R6）2，每个R6独立地为氢，C1-C4烷基或未取代或取代的苯基，X为CH-NO2，N-CN或N-NO2，n为1至3 ，以游离形式或盐形式，并且在适当时，这些化合物及其盐的互变异构体可以用作农业化学活性成分，并且可以以本身已知的方式制备。

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