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    • 1. 发明授权
    • Polymeric additives to improve print quality and permanence attributes in ink-jet inks
    • 高分子添加剂,以提高喷墨油墨的印刷质量和持久性
    • US07829608B2
    • 2010-11-09
    • US12185055
    • 2008-08-01
    • Joseph W TsangJohn R Moffatt
    • Joseph W TsangJohn R Moffatt
    • C09D11/00
    • B41M5/0017B41J2/2114B41J11/0015B41M7/0018
    • Two-part fixatives are provided in conjunction with overcoating at least one ink-jet ink printed on a print medium and comprise (1) at least one first reactive component comprising a reactive monomer or oligomer, the reactive species selected from the group consisting of iso-cyanates and epoxy-terminated oligomers, optionally in a vehicle, and (2) at least one second component selected from the group consisting of polyols and polyvinyl alcohols, plus one or more base catalysts, optionally in a vehicle. The two components and catalyst(s) are deposited on the print medium on which the ink-jet ink has been printed, and react to form a hydrophobic polymer overcoating the printed ink and having a glass transition temperature within a range of −20° C. to +50° C. and a melting temperature within a range of 30° C. to 100° C.
    • 提供两部分固定剂,其中连续地涂覆印刷在印刷介质上的至少一种喷墨油墨,并且包括(1)至少一种包含反应性单体或低聚物的第一反应性组分,所述反应性物质选自iso - 氰酸酯和环氧封端的低聚物,任选地在载体中,和(2)至少一种选自多元醇和聚乙烯醇的第二组分,以及任选地在载体中的一种或多种碱催化剂。 将两种组分和催化剂沉积在印刷有喷墨油墨的印刷介质上,并反应形成覆盖印刷油墨的疏水性聚合物,玻璃化转变温度在-20℃ 至+ 50℃,熔融温度在30℃至100℃的范围内。
    • 2. 发明授权
    • Polymeric additives to improve print quality and permanence attributes in ink-jet inks
    • 高分子添加剂,以提高喷墨油墨的印刷质量和持久性
    • US07446134B2
    • 2008-11-04
    • US10824687
    • 2004-04-14
    • Joseph W TsangJohn R Moffatt
    • Joseph W TsangJohn R Moffatt
    • C09D11/00
    • B41M5/0017B41J2/2114B41J11/0015B41M7/0018
    • Two-part fixatives are provided in conjunction with overcoating at least one ink-jet ink printed on a print medium and comprise (1) at least one first reactive component comprising a reactive monomer or oligomer, the reactive species selected from the group consisting of iso-cyanates and epoxy-terminated oligomers, optionally in a vehicle, and (2) at least one second component selected from the group consisting of polyols and polyvinyl alcohols, plus one or more base catalysts, optionally in a vehicle. The two components and catalyst(s) are deposited on the print medium on which the ink-jet ink has been printed, and react to form a hydrophobic polymer overcoating the printed ink and having a glass transition temperature within a range of −20° C. to +50° C. and a melting temperature within a range of 30° C. to 100° C.
    • 提供两部分固定剂,其中连续地涂覆印刷在印刷介质上的至少一种喷墨油墨,并且包括(1)至少一种包含反应性单体或低聚物的第一反应性组分,所述反应性物质选自iso - 氰酸酯和环氧封端的低聚物,任选地在载体中,和(2)至少一种选自多元醇和聚乙烯醇的第二组分,以及任选地在载体中的一种或多种碱催化剂。 将两种组分和催化剂沉积在印刷有喷墨油墨的印刷介质上,并反应形成覆盖印刷油墨的疏水性聚合物,玻璃化转变温度在-20℃ 至+ 50℃,熔融温度在30℃至100℃的范围内。
    • 4. 发明申请
    • POLYMERIC ADDITIVES TO IMPROVE PRINT QUALITY AND PERMANENCE ATTRIBUTES IN INK-JET INKS
    • 提高喷墨印刷品质量和耐用性的聚合添加剂
    • US20080293881A1
    • 2008-11-27
    • US12185055
    • 2008-08-01
    • Joseph W. TsangJohn R. Moffatt
    • Joseph W. TsangJohn R. Moffatt
    • C08L75/00
    • B41M5/0017B41J2/2114B41J11/0015B41M7/0018
    • Two-part fixatives are provided in conjunction with overcoating at least one ink-jet ink printed on a print medium and comprise (1) at least one first reactive component comprising a reactive monomer or oligomer, the reactive species selected from the group consisting of iso-cyanates and epoxy-terminated oligomers, optionally in a vehicle, and (2) at least one second component selected from the group consisting of polyols and polyvinyl alcohols, plus one or more base catalysts, optionally in a vehicle. The two components and catalyst(s) are deposited on the print medium on which the ink-jet ink has been printed, and react to form a hydrophobic polymer overcoating the printed ink and having a glass transition temperature within a range of −20° C. to +50° C. and a melting temperature within a range of 30° C. to 100° C.
    • 提供两部分固定剂,其中连续地涂覆印刷在印刷介质上的至少一种喷墨油墨,并且包括(1)至少一种包含反应性单体或低聚物的第一反应性组分,所述反应性物质选自iso - 氰酸酯和环氧封端的低聚物,任选地在载体中,和(2)至少一种选自多元醇和聚乙烯醇的第二组分,以及任选地在载体中的一种或多种碱催化剂。 将两种组分和催化剂沉积在印刷有喷墨油墨的印刷介质上,并反应形成覆盖印刷油墨的疏水性聚合物,玻璃化转变温度在-20℃ 至+ 50℃,熔融温度在30℃至100℃的范围内。
    • 6. 发明授权
    • Ink-jet ink compositions containing reactive macromolecular chromophores for digital and textile printing
    • 含有用于数字和纺织品印刷的反应性大分子发色团的喷墨油墨组合物
    • US06323257B1
    • 2001-11-27
    • US09298626
    • 1999-04-23
    • John R MoffattJoseph W Tsang
    • John R MoffattJoseph W Tsang
    • C09D1102
    • C09B68/24C09B69/10C09D11/32D06P1/38D06P5/30
    • The present invention relates to ink-jet ink compositions that comprise modified pigment particles (macromolecular chromophores) having functional groups covalently attached for water solubility and reactive moieties covalently attached to the pigments. MMC with such reactive moieties attached can either a) react directly with cellulose or other textile material or, b) can participate in polymerization reactions. These reactive moieties may in turn be further derivatized to provide the desirable attribute, such as enhanced smearfastness, enhanced print quality, improved bleed control, and improved resistance to water when applied to the media. Moreover, inks formulated with these reactive MMCs demonstrate viscosity and surface tension characteristics that are useful in ink-jet printing. This includes thermal ink jet, piezoelectric ink jet, and continuous ink jet printing.
    • 本发明涉及喷墨油墨组合物,其包含具有共价连接水溶性官能团的改性颜料颗粒(大分子发色团)和与颜料共价连接的活性部分。 具有这种反应性部分的MMC可以a)直接与纤维素或其它纺织材料反应,或b)可以参与聚合反应。 这些反应性部分又可以进一步衍生化,以提供所需的性质,例如增强的防粘性,增强的印刷质量,改善的渗色控制,以及当施用于培养基时改善的耐水性。 此外,用这些反应性MMC配制的油墨表现出在喷墨印刷中有用的粘度和表面张力特性。 这包括热喷墨,压电喷墨和连续喷墨印刷。
    • 7. 发明授权
    • Black-to-color bleed alleviation using non-specific ionic, pH, and
colloidal effects
    • 使用非特异性离子,pH和胶体效应的黑色到彩色渗色减轻
    • US5853465A
    • 1998-12-29
    • US821952
    • 1997-03-24
    • Joseph W. TsangJohn R. Moffat
    • Joseph W. TsangJohn R. Moffat
    • B41J2/01B41M5/00C09D11/00C09D11/02
    • C09D11/40B41J2/01
    • An ink-jet ink set comprises (a) a microemulsion-based black ink in which the colorant is a water-insoluble black pigment has been chemically modified to impart water solubility by addition of functional groups to form a macromolecular chromophore and (b) at least one non-black (cyan, yellow, or magenta) ink that is a typical aqueous dye-based ink with an agent that increases the ionic strength of the no-black ink and comprises either an inorganic salt or an organic acid; the organic acid is used to adjust the pH of the non-black ink to a value of less than 5. The non-black ink may alternatively comprise a water-insoluble non-black pigment that has also been chemically modified. The macromolecular chromophore-containing ink, or pigment-based ink, of the ink-jet ink set is a microemulsion that contains a substantially water-insoluble organic oil, an organic co-solvent, and water and, optionally, an amphiphile and a high molecular weight colloid. By employing an ink set in which some of the members of the set have a higher ionic strength than the black, microemulsion-based ink, then bleed alleviation can be achieved. When the higher ionic strength ink comes in contact with the lower ionic strength microemulsion ink, the rapid change in ionic strength of the microemulsion causes flocculation of the dissolved modified pigment. The result of the flocculation is that the colorant is precipitated on the print medium. It is no longer capable of diffusion into the other ink, thereby alleviating bleed, nor is it capable of penetration into the medium, thereby resulting in improved color density and edge acuity. The inks described herein also exhibit fast drying times, high waterfastness, and high smearfastness. They also show reduced problems with inter-color bleed and show no halo effect.
    • 一种喷墨墨水组包括(a)其中着色剂是不溶于水的黑色颜料的微乳液型黑色油墨已被化学改性以通过添加官能团形成高分子发色团而赋予水溶性,和(b)在 至少一种非黑色(青色,黄色或品红色)油墨,其是具有增加无黑色油墨的离子强度且包含无机盐或有机酸的试剂的典型的含水染料基油墨; 有机酸用于将非黑色墨水的pH调节至小于5的值。非黑色墨水可以替代地包括也被化学改性的水不溶性非黑色颜料。 喷墨油墨组中含有大分子发色团的油墨或颜料基油墨是含有基本上不溶于水的有机油,有机共溶剂和水以及任选的两亲和高分子的微乳液 分子量胶体。 通过使用其中一些组分的成员具有比黑色基于微乳液的油墨更高的离子强度的油墨组,则可以实现放气缓和。 当较高的离子强度墨水与较低离子强度的微乳液墨接触时,微乳液的离子强度的快速变化引起溶解的改性颜料的絮凝。 絮凝的结果是着色剂在印刷介质上沉淀。 它不再能够扩散到另一个墨水中,从而减轻渗色,也不能渗透到介质中,从而提高颜色密度和边缘的敏锐度。 本文所述的油墨还表现出快速干燥时间,高耐水性和高耐擦性。 他们还显示减少的颜色渗色问题,并且不显示晕圈效应。
    • 8. 发明授权
    • Preparation of microemulsion and micellar color inks from modified
water-soluble color chromaphores for thermal ink-jet printing
    • 用于热喷墨印刷的改性水溶性彩色染料的微乳液和胶束颜料油墨的制备
    • US5749952A
    • 1998-05-12
    • US742097
    • 1996-10-31
    • Joseph W. TsangJohn R. Moffatt
    • Joseph W. TsangJohn R. Moffatt
    • C09D11/00
    • C09D11/30
    • The ink of the invention comprises a vehicle and a colorant, with the vehicle comprising a microemulsion containing at least one substantially water-insoluble organic oil, at least one organic cosolvent, and water and, optionally, at least one amphiphile and at least one high molecular weight colloid. The colorant is a water-insoluble chromaphore that has been chemically modified to be water-soluble by addition of functional groups that impart water solubility. These functional groups are added to the surface of the chromaphore particles, resulting in water-soluble colorant particles. The inks described herein demonstrate high edge acuity, high optical density, fast drying times, reduced bleed, improved halo characteristics, high water fastness, and high smearfastness.
    • 本发明的油墨包括载体和着色剂,其中载体包含含有至少一种基本上不溶于水的有机油,至少一种有机共溶剂和水的微乳液,以及任选地至少一种两亲物和至少一种高分子 分子量胶体。 着色剂是通过添加赋予水溶性的官能团而被化学改性为水溶性的水不溶性发色团。 将这些官能团加入染料颗粒表面,产生水溶性着色剂颗粒。 本文所描述的油墨表现出高边缘光泽度,高光密度,快速干燥时间,减少渗色,改进的光晕特性,高耐水牢度和高耐擦牢性。