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1. 发明授权

US4269629A Stabilized cellulose ester compositions 失效
标题翻译：稳定的纤维素酯组合物
公开(公告)号：US4269629A
公开(公告)日：1981-05-26
申请号：US77875
申请日：1979-09-21
申请人： Joseph S. Zannucci
发明人： Joseph S. Zannucci
IPC分类号： C08K5/105 , C08K5/3475 , C08L1/10
CPC分类号： C08K5/105 , C08K5/10 , C08K5/13 , C08K5/3475
摘要： This invention is directed to a three component stabilizer system for cellulose esters. These commercially useful stabilized cellulose ester compositions can be molded, shaped and otherwise processed in a thermoplastic condition at elevated temperatures to provide products having improved ultraviolet light stability or weatherability.
摘要翻译：本发明涉及用于纤维素酯的三组分稳定剂体系。这些商业上有用的稳定的纤维素酯组合物可以在高温下在热塑性条件下模制，成型和以其它方式加工，以提供具有改善的紫外光稳定性或耐气候性的产品。

2. 发明授权

US4256626A Multichromophoric ultraviolet stabilizers and their use in organic compositions 失效
标题翻译：多色性紫外线稳定剂及其在有机组合物中的应用
公开(公告)号：US4256626A
公开(公告)日：1981-03-17
申请号：US924021
申请日：1978-07-12
申请人： Richard H. S. Wang , Joseph S. Zannucci
发明人： Richard H. S. Wang , Joseph S. Zannucci
IPC分类号： C08K5/3447 , C08K5/47 , C08K5/34
CPC分类号： C08K5/47 , C08K5/3447
摘要： The invention relates to multichromophoric compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the multichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stablizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
摘要翻译：本发明涉及已被发现是有效的紫外线稳定剂的多色素化合物。本发明还涉及含有稳定量的多色母体组合物以防止这种降解的紫外可降解有机组合物。这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中，涂覆在模制品，膜或挤出纤维的外部。

3. 发明授权

US4525504A Stabilized polyester compositions suitable for outdoor applications 失效
标题翻译：稳定的聚酯组合物适用于户外应用
公开(公告)号：US4525504A
公开(公告)日：1985-06-25
申请号：US544034
申请日：1983-10-24
申请人： John C. Morris , Joseph S. Zannucci
发明人： John C. Morris , Joseph S. Zannucci
IPC分类号： C08G63/199 , C08K5/00 , C08K5/3435 , C08K5/3462 , C08L33/20 , C08K5/34 , C08K5/07 , C08K5/10
CPC分类号： C08K5/3435 , C08G63/199 , C08K5/005 , C08K5/3462 , C08L33/20
摘要： Disclosed are stabilized polyester compositions having significantly improved weatherability, said polyesters consisting of homopolyesters derived from a dicarboxylic acid component wherein at least a major portion of which is 1,4-cyclohexanedicarboxylic acid (or ester) having a trans isomer content of at least 65% and a glycol component wherein at least a major portion of which is 2,2,4,4-tetramethyl-1,3-cyclobutanediol and copolyesters thereof with modifying aliphatic glycols and/or aliphatic dicarboxylic acids, said polyesters being stabilized with the combination of at least one ultraviolet light stabilizing compound compatible with said polyester and at least one hindered amine light stabilizer having the formulae ##STR1## the groups shown as R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from various substituents.
摘要翻译：公开了具有显着改善的耐候性的稳定的聚酯组合物，所述聚酯由衍生自二羧酸组分的均聚酯组成，其中至少大部分是具有至少65％的反式异构体含量的1,4-环己烷二羧酸（或酯）和二醇组分，其中至少大部分为2,2,4,4-四甲基-1,3-环丁二醇及其与改性脂族二醇和/或脂族二羧酸的共聚酯，所述聚酯通过与所述聚酯相容的至少一种紫外线稳定化合物和具有式I或II的至少一种受阻胺光稳定剂，所示的R1，R2，R3和R4所示的基团各自独立地选自各种取代基。

4. 发明授权

US4115348A Multichromophoric ultraviolet stabilizers and their use in organic compositions 失效
标题翻译：多色性紫外线稳定剂及其在有机组合物中的应用
公开(公告)号：US4115348A
公开(公告)日：1978-09-19
申请号：US711045
申请日：1976-08-02
申请人： Richard H. S. Wang , Joseph S. Zannucci
发明人： Richard H. S. Wang , Joseph S. Zannucci
IPC分类号： C08K5/35 , C08K5/15
CPC分类号： C08K5/35
摘要： The invention relates to multichromophoric compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the multichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
摘要翻译：本发明涉及已被发现是有效的紫外线稳定剂的多色素化合物。本发明还涉及含有稳定量的多色母体组合物以防止这种降解的紫外可降解有机组合物。这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中，涂覆在模塑制品，薄膜或挤出纤维的外部上。

5. 发明授权

US4524165A Stabilized copolyesterether compositions suitable for outdoor applications 失效
标题翻译：适用于室外应用的稳定的共聚酯组合物
公开(公告)号：US4524165A
公开(公告)日：1985-06-18
申请号：US544035
申请日：1983-10-24
申请人： Harry R. Musser , Thomas H. Strickland , Joseph S. Zannucci
发明人： Harry R. Musser , Thomas H. Strickland , Joseph S. Zannucci
IPC分类号： C08K5/00 , C08K5/3435 , C08K5/3462 , C08K5/34 , C08K5/07 , C08K5/10
CPC分类号： C08K5/3435 , C08K5/00 , C08K5/3462
摘要： Disclosed are stabilized polyester compositions having significantly improved weatherability. These polyesters consist of copolyesterethers derived from a dicarboxylic acid component comprising about 80-100 mole % 1,4-cyclohexanedicarboxylic acid having a trans isomer content of at least 70% and about 0-20 mole % of a second dicarboxylic acid and a glycol component comprising about 70-95 mole % 1,4-cyclohexanedimethanol and about 5-30 mole % of a polyalkylene ether glycol having a molecular weight of about 600 to about 3000. The copolyesterether compositions further comprise a stabilizing effective amount of the combination of (1) at least one hindered phenolic antioxidant, (2) at least one ultraviolet light stabilizing compound compatible with said copolyesterether and (3) at least one hindered amine light stabilizing compound having the formulae ##STR1## the groups shown as R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from various substituents.
摘要翻译：公开了具有显着改善的耐候性的稳定的聚酯组合物。这些聚酯由衍生自二羧酸组分的共聚酯组成，所述二羧酸组分包含约80-100摩尔％的反式异构体含量为至少70％和约0-20摩尔％的第二二羧酸和二醇组分的1,4-环己烷二羧酸其包含约70-95摩尔％的1,4-环己烷二甲醇和约5-30摩尔％的分子量为约600至约3000的聚亚烷基醚二醇。共聚内酯组合物还包含稳定有效量的（1 ）至少一种受阻酚抗氧化剂，（2）至少一种与所述共聚酯相容的紫外线稳定化合物和（3）至少一种具有下式的受阻胺光稳定化合物：，R 2，R 3和R 4各自独立地选自各种取代基。

6. 发明授权

US4127501A Polychromophoric ultraviolet stabilizers and their use in organic compositions 失效
标题翻译：多色紫外线稳定剂及其在有机组合物中的应用
公开(公告)号：US4127501A
公开(公告)日：1978-11-28
申请号：US713000
申请日：1976-08-09
申请人： Richard H. S. Wang , Joseph S. Zannucci
发明人： Richard H. S. Wang , Joseph S. Zannucci
IPC分类号： A61K8/49 , A61Q17/04 , C08K5/01 , C08K5/353 , C09K15/30 , C09K15/20 , C07D249/18 , C07D277/82 , C08K5/35
CPC分类号： C08K5/353 , A61K8/49 , A61K8/492 , A61K8/4946 , A61K8/496 , A61Q17/04 , A61K2800/438
摘要： The invention relates to polychromophoric compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the polychromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
摘要翻译：本发明涉及已被发现是有效的紫外线稳定剂的多色性化合物。本发明还涉及含有稳定量的多色荧光组合物以防止这种降解的紫外线可降解有机组合物。这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中，涂覆在模塑制品，薄膜或挤出纤维的外部上。

7. 发明授权

US4073745A Multichromophoric benzotriazole ultraviolet stabilizers and their use in organic compositions 失效
标题翻译：多色性苯并三唑紫外线稳定剂及其在有机组合物中的应用
公开(公告)号：US4073745A
公开(公告)日：1978-02-14
申请号：US687080
申请日：1976-05-14
申请人： Richard H. S. Wang , Joseph S. Zannucci
发明人： Richard H. S. Wang , Joseph S. Zannucci
IPC分类号： C07D249/20 , C08K5/3442 , C08K5/3475 , C09K15/30 , C09K15/32 , C08K5/34
CPC分类号： C08K5/3442 , C07D249/20 , C08K5/3475 , C09K15/30
摘要： The invention relates to multichromophoric compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the multichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
摘要翻译：本发明涉及已被发现是有效的紫外线稳定剂的多色素化合物。本发明还涉及含有稳定量的多色母体组合物以防止这种降解的紫外可降解有机组合物。这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中，涂覆在模塑制品，薄膜或挤出纤维的外部上。

8. 发明授权

US3961975A Titanium dioxide pigmented cellulosic polymer compositions with improved visible and ultraviolet light stability 失效
标题翻译：具有改善的可见和超紫外光稳定性的二氧化钛掺杂的纤维素聚合物组合物
公开(公告)号：US3961975A
公开(公告)日：1976-06-08
申请号：US539193
申请日：1975-01-07
申请人： Joseph S. Zannucci , Gerald R. Lappin
发明人： Joseph S. Zannucci , Gerald R. Lappin
IPC分类号： C08K5/13 , C08K5/132 , C08K5/3475 , C08L1/08 , C08L1/14
CPC分类号： C08K5/132 , C08K3/22 , C08K5/00 , C08K5/13 , C08K5/3475
摘要： The zinc or manganese salt of a 3,5-di-tert-alkyl-4-hydroxybenzoic acid, in combination with either a 2-hydroxybenzophenone or a 2-(2H-benzotriazol-2-yl)phenol provide highly effective synergistic stabilizer systems for TiO.sub.2 -pigmented cellulosic polymers.

9. 发明授权

US4418002A Melamine group containing ultraviolet stabilizers and their use in organic compositions II 失效
标题翻译：含有紫外线稳定剂的三聚氰胺组合物及其在有机组合物中的应用II
公开(公告)号：US4418002A
公开(公告)日：1983-11-29
申请号：US413907
申请日：1982-09-01
申请人： Joseph S. Zannucci , Wayne P. Pruett
发明人： Joseph S. Zannucci , Wayne P. Pruett
IPC分类号： C08K5/3492 , C08K5/35 , C09K15/30 , C09K15/20 , C08K5/16
CPC分类号： C09K15/30 , C08K5/34926 , C08K5/35
摘要： The invention relates to melamine group containing compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing an amount of a melamine group containing compounds to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may be incorporated into the organic compositions such as polymers by adding to the polymer melt or dissolved in the polymer dope, coated on the exterior of the shaped or molded article, film or extruded fiber.
摘要翻译：本发明涉及已发现是有效的紫外线稳定剂的含三聚氰胺基团的化合物。本发明还涉及含有一定量的含三聚氰胺基团的化合物以防止这种降解的紫外可降解有机组合物。这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。这些紫外线稳定剂可以通过加入到聚合物熔体中或溶解在聚合物涂料中而被包被到有机组合物如聚合物中，涂覆在成型或模塑制品，膜或挤出纤维的外部上。

10. 发明授权

US4355080A Polyester-acrylic composite sheet having improved weatherability 失效
标题翻译：具有改善的耐候性的聚酯 - 丙烯酸复合片材
公开(公告)号：US4355080A
公开(公告)日：1982-10-19
申请号：US239784
申请日：1981-03-02
申请人： Joseph S. Zannucci
发明人： Joseph S. Zannucci
IPC分类号： B32B27/08 , B32B27/18 , B32B27/36
CPC分类号： B32B27/08 , Y10T428/31797 , Y10T428/31935
摘要： Disclosed are polyester substrates or sheets laminated with an acrylic film and having exceptionally improved resistance to surface deterioration on weathering. These laminates are especially suited for use in applications such as windows, signs, solar collectors, green house covers and the like which are subject to extended periods of outdoor exposure. Typical polyesters include modified poly(ethylene terephthalate), and modified poly(1,4-cyclohexylenedimethylene terephthalate) such as those of terephthalic acid with ethylene glycol and 1,4-cyclohexanedimethanol, e.g., poly(69/31 molar-ethylene/1,4-cyclohexylenedimethylene terephthalate) and poly(65/35 molar-1,4-cyclohexylenedimethylene/ethylene terephthalate). The acrylic polymer films suitable forlamination to the polyester sheeting are homopolymers and copolymers prepared from either or both of the monomers H.sub.2 C.dbd.CHCO.sub.2 R and H.sub.2 C.dbd.C(CH.sub.3)CO.sub.2 R.sup.1 wherein R and R.sup.1 are each selected from C.sub.1 -C.sub.12 linear or branched alkyl groups.
摘要翻译：公开了聚酯基材或层压有丙烯酸薄膜的片材，并且在耐候性方面具有特别改善的耐表面变质性。这些层压板特别适用于经过长时间室外暴露的应用，例如窗户，标志，太阳能收集器，温室盖等。典型的聚酯包括改性聚（对苯二甲酸乙二醇酯）和对苯二甲酸与乙二醇和1,4-环己烷二甲醇的改性聚（1,4-环己烯二亚甲基对苯二甲酸酯），例如聚（69/31摩尔乙烯/ 对苯二甲酸4-环己烯二甲酯）和聚（65/35摩尔-1,4-亚环己基亚甲基/对苯二甲酸乙二醇酯）。适用于聚酯薄膜层压的丙烯酸聚合物薄膜是由单体H 2 C = CHCO 2 R和H 2 C = C（CH 3）CO 2 R中的一种或两种制备的均聚物和共聚物，其中R和R 1各自选自C 1 -C 12直链或支链烷基。

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