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1. 发明授权

US07829652B2 Polyarylether composition and membrane 有权
标题翻译：聚芳醚组成和膜
公开(公告)号：US07829652B2
公开(公告)日：2010-11-09
申请号：US12183488
申请日：2008-07-31
申请人： Joyce Hung , Daniel Joseph Brunelle , Marianne Elisabeth Harmon , David Roger Moore , Joshua James Stone , Hongyi Zhou , Joseph Anthony Suriano
发明人： Joyce Hung , Daniel Joseph Brunelle , Marianne Elisabeth Harmon , David Roger Moore , Joshua James Stone , Hongyi Zhou , Joseph Anthony Suriano
IPC分类号： C08G2/00
CPC分类号： C08F283/08 , C08F283/06 , C08G65/4075 , C08G65/48 , C08G75/23 , C08G81/00 , C08G2650/40 , C08J5/2256 , C08J2371/12 , C08J2381/06 , C08J2387/00 , C08L51/08 , C08L53/00 , C08L71/00 , C08L81/06 , C08L2205/05 , H01M8/1025 , H01M8/1027 , H01M2300/0082 , C08L2666/02 , C08L81/00 , C08L2666/22
摘要： A composition including a polyarylether copolymer is provided. The copolymer includes a polyarylether backbone; and a sulfonated oligomeric group bonded to the polyarylether suitable for use as a cation conducting membrane. Method of bonding a sulfonated oligomeric group to the polyarylether backbone to form a polyarylether copolymer. The membrane may be formed from the polyarylether copolymer composition. The chain length of the sulfonated oligomeric group may be controlled to affect or control the ion conductivity of the membrane.
摘要翻译：提供了包含聚芳醚基共聚物的组合物。共聚物包括聚芳醚基骨架; 和与适合用作阳离子导电膜的聚芳醚结合的磺化低聚基团。将磺化低聚基团键合到聚芳醚基骨架以形成聚芳醚基共聚物的方法。膜可以由聚芳醚醚共聚物组合物形成。可以控制磺化低聚基团的链长度以影响或控制膜的离子传导性。

2. 发明授权

US06960641B2 Method of making block copolymers by solid state polymerization 有权
标题翻译：通过固态聚合制备嵌段共聚物的方法
公开(公告)号：US06960641B2
公开(公告)日：2005-11-01
申请号：US10743241
申请日：2003-12-22
申请人： Gregory Allen O'Neil , James Day , Daniel Joseph Brunelle , Joseph Anthony Suriano , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr.
发明人： Gregory Allen O'Neil , James Day , Daniel Joseph Brunelle , Joseph Anthony Suriano , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr.
IPC分类号： C08G81/00 , C08G63/64 , C08G63/80 , C08G64/00
CPC分类号： C08G63/64 , C08G63/80
摘要： A method of preparing block copolymers by solid state polymerization is described. A mixture of a partially crystalline polycarbonate having activated terminal aryloxy groups, for example terminal methyl salicyl groups, when heated together with an oligomeric polyester having reactive terminal hydroxy groups under solid state polymerization conditions affords block copolymers. The activated terminal aryloxy groups play a key role in preserving the block lengths of the starting materials. A control sample in which the partially crystalline polycarbonate lacks activated terminal aryloxy groups, for example polycarbonates substituted by phenol, affords a much lower molecular weight, more highly randomized copolymer product. The product block copolymers are useful as “weatherable” plastic materials.
摘要翻译：描述了通过固态聚合制备嵌段共聚物的方法。当在固态聚合条件下与具有反应性末端羟基的低聚聚酯一起加热时，具有活化的末端芳氧基的部分结晶的聚碳酸酯，例如末端甲基水杨酸酯的混合物得到嵌段共聚物。活化的末端芳氧基在保留原料的块长度方面起关键作用。其中部分结晶聚碳酸酯缺乏活化的末端芳氧基的对照样品，例如被苯酚取代的聚碳酸酯，得到低得多的分子量，更高度随机的共聚物产物。产品嵌段共聚物可用作“耐候性”塑料材料。

3. 发明申请

US20090163692A1 AROMATIC POLYETHERS 审中-公开
标题翻译：芳香聚醚
公开(公告)号：US20090163692A1
公开(公告)日：2009-06-25
申请号：US11962627
申请日：2007-12-21
申请人： David Roger Moore , Gary William Yeager , Daniel Joseph Brunelle , Marianne Elisabeth Harmon , Joyce Hung , Joseph Anthony Suriano , Hongyi Zhou
发明人： David Roger Moore , Gary William Yeager , Daniel Joseph Brunelle , Marianne Elisabeth Harmon , Joyce Hung , Joseph Anthony Suriano , Hongyi Zhou
IPC分类号： C08G75/02
CPC分类号： C08G65/40 , C07C317/14 , C07C317/22 , C07C317/44 , C08G65/4006 , C08G75/23
摘要： An aromatic polyether comprising structural units derived from a halosulfone sulfonate having structure (I): wherein R1 is a C3-C25 aromatic radical, a C3-C25 cycloaliphatic radical, or a C1-C10 aliphatic radical; M is hydrogen or a charge balancing cation; Y1 is independently at each occurrence a halogen; “t” is an integer having a value of 1 or 2; “s” is an integer having a value 0 to 3, “b” is an integer having a value 1 to 4; and “c” is an integer having a value 1 to 20. Also provided are methods of preparing the aromatic polyethers, and compositions including the aromatic polyethers.
摘要翻译：包含衍生自具有结构（I）的卤代磺酸盐的结构单元的芳族聚醚：其中R1是C3-C25芳族基团，C3-C25脂环族基团或C1-C10脂族基团; M是氢或电荷平衡阳离子; Y1在每次出现时独立地为卤素; “t”是1或2的整数; “s”为0〜3的整数，b为1〜4的整数， “c”是1至20的整数。还提供了制备芳族聚醚的方法和包括芳族聚醚的组合物。

4. 发明授权

US07514147B2 Formable thermoplastic multi-layer laminate, a formed multi-layer laminate, an article, and a method of making an article 有权
标题翻译：成型热塑性多层层压体，成形多层层压体，制品及制品的制造方法
公开(公告)号：US07514147B2
公开(公告)日：2009-04-07
申请号：US10748941
申请日：2003-12-30
申请人： Michael Shoen Davis , Martin Lindway , Michael T. Roland , Joseph Anthony Suriano , Hua Wang , Vicki Herzl Watkins , Georgios S. Zafiris , Hongyi Zhou
发明人： Michael Shoen Davis , Martin Lindway , Michael T. Roland , Joseph Anthony Suriano , Hua Wang , Vicki Herzl Watkins , Georgios S. Zafiris , Hongyi Zhou
IPC分类号： B32B27/08 , B32B27/30 , B32B27/32 , B32B27/36
CPC分类号： B32B27/08 , B32B5/18 , B32B7/12 , B32B25/08 , B32B25/14 , B32B27/18 , B32B27/28 , B32B27/36 , B32B27/365 , B32B37/153 , B32B2307/738 , B32B2319/00 , B32B2355/02 , B32B2369/00 , B32B2398/10 , B32B2398/20 , B32B2605/00 , Y10T428/26 , Y10T428/269 , Y10T428/31507 , Y10T428/31786 , Y10T428/31797 , Y10T428/31909 , Y10T428/31938
摘要： Disclosed is a formable thermoplastic multi-layer laminate comprising an outer layer comprising a polymer comprising resorcinol arylate polyester chain members, a middle layer comprising a thermoplastic polymer, an inner-tie layer comprising a thermoplastic polymer comprising a carbonate polymer and an acrylonitrile-styrene graft copolymer comprising at least one of an acrylonitrile-styrene-acrylate graft copolymer (ASA) or an acrylonitrile-butadiene-styrene graft copolymer (ABS), the middle layer being between the outer layer and the inner-tie layer and being in contact with both the outer layer and the inner-tie layer. Also disclosed are a formed multi-layer laminate and an article comprising the multi-layer laminate bonded to a substrate. A method of making the article is also disclosed.
摘要翻译：公开了一种可成形的热塑性多层层合物，其包含外层，其包含聚合物，所述聚合物包含间苯二酚芳基化物聚酯链构件，包含热塑性聚合物的中间层，包含碳酸酯聚合物的热塑性聚合物的内连接层和丙烯腈 - 苯乙烯接枝共聚物，其包含丙烯腈 - 苯乙烯 - 丙烯酸酯接枝共聚物（ASA）或丙烯腈 - 丁二烯 - 苯乙烯接枝共聚物（ABS）中的至少一种，中间层在外层和内连接层之间并与两者接触外层和内连层。还公开了一种形成的多层层合物和包含结合到基底的多层层压体的制品。还公开了制造该制品的方法。

5. 发明申请

US20080142418A1 FUNCTIONAL POLYARYLETHERS 失效
公开(公告)号：US20080142418A1
公开(公告)日：2008-06-19
申请号：US11611642
申请日：2006-12-15
申请人： Yanshi Zhang , Daniel Steiger , Joseph Anthony Suriano , Gary William Yeager
发明人： Yanshi Zhang , Daniel Steiger , Joseph Anthony Suriano , Gary William Yeager
IPC分类号： C08G75/00 , B01D61/00
CPC分类号： C08G65/40 , C08G65/48 , C08G75/23
摘要： Membranes comprising functional polyarylether having structural units of formula I are useful for hemodialysis and hemofiltration: wherein X is selected from Br, NR4R5, OOCR6, OR7, NR4CONR5R6, NR4COOR5R6 and combinations thereof; R1, R2 and R3 are independently at each occurrence CH2X, H, halo, cyano, nitro, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12aromatic radical or a combination thereof; R4 and R5 are independently H, a C1-10 aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical, or a combination thereof; R6 is H, a C2-10 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R7 is OCH2CH2(OCH2CH2)nOH or OOCCH2(OCH2CH2)nCH3; Z is a direct bond, O, S, SO, SO2, CO, phenylphospinyl oxide, alkenyl, alkynyl, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; a, b, and c are independently 1 or 2; and m, n and p are independently 0 or 1.

6. 发明申请

US20080000809A1 Membrane method of removing oil-soluble metals from hydrocarbons 审中-公开
标题翻译：从烃中除去油溶性金属的膜方法
公开(公告)号：US20080000809A1
公开(公告)日：2008-01-03
申请号：US11479322
申请日：2006-06-30
申请人： Hua Wang , Gary William Yeager , Joseph Anthony Suriano , Neil Edwin Moe
发明人： Hua Wang , Gary William Yeager , Joseph Anthony Suriano , Neil Edwin Moe
IPC分类号： C10G17/00 , C10G45/00
CPC分类号： C10G31/11 , B01D61/025 , B01D61/027 , B01D61/145 , B01D61/147 , B01D61/58
摘要： A method of removing an oil-soluble metal from a hydrocarbon feedstock comprises passing the hydrocarbon feedstock through a nanofiltration membrane or a reverse osmosis membrane to produce a permeate stream having at least a vanadium concentration less than an initial vanadium concentration in the hydrocarbon feedstock, and a retentate stream having at least a vanadium concentration greater than the initial vanadium concentration in the hydrocarbon feedstock.
摘要翻译：从烃原料中除去油溶性金属的方法包括使烃原料通过纳滤膜或反渗透膜，以产生至少钒浓度低于烃原料中的初始钒浓度的渗透物流，以及具有至少钒浓度大于烃原料中的初始钒浓度的滞留物料流。

7. 发明授权

US06559270B1 Weatherable block copolyestercarbonates and blends containing them, and method 有权
标题翻译：耐候性共聚酯碳酸酯和含有它们的混合物，以及方法
公开(公告)号：US06559270B1
公开(公告)日：2003-05-06
申请号：US09416529
申请日：1999-10-12
申请人： Tiberiu Mircea Siclovan , Jimmy Lynn Webb , Sterling Bruce Brown , Donald Joseph Buckley, Jr. , James Edward Pickett , Joseph Anthony Suriano , Paul Dean Sybert , Daniel Joseph Brunelle , Margaret Louise Blohm , Hongyi Zhou , Georgia Dris Fishburn
发明人： Tiberiu Mircea Siclovan , Jimmy Lynn Webb , Sterling Bruce Brown , Donald Joseph Buckley, Jr. , James Edward Pickett , Joseph Anthony Suriano , Paul Dean Sybert , Daniel Joseph Brunelle , Margaret Louise Blohm , Hongyi Zhou , Georgia Dris Fishburn
IPC分类号： C08G6401
CPC分类号： C08L67/00 , C08G63/64 , C08G63/78 , C08G64/18 , C08G2261/126 , C08K3/013 , C08L67/02 , C08L67/03 , C08L69/00 , C08L69/005 , C08L79/08 , F02B61/045
摘要： Block copolyestercarbonates may be prepared by first conducting a reaction between at least one of resorcinol or an alkyl- or haloresorcinol and at least one aromatic dicarboxylic acid dichloride, preferably isophthaloyl dichloride, terephthaloyl dichloride or a mixture thereof, to produce a hydroxy-terminated polyester intermediate, and then conducting a reaction of the intermediate with a carbonate precursor, preferably in the presence of a dihydroxy compound such as bisphenol A. The products have excellent physical properties, including a high degree of weatherability. They may be blended with other polymers such as polycarbonates, poly(alkylene carboxylates), polyarylates, polyetherimides, and addition polymers to improve the weatherability thereof.
摘要翻译：嵌段共聚酯碳酸酯可以通过首先在间苯二酚或烷基 - 或卤代间苯二酚和至少一种芳族二羧酸二氯化物，优选间苯二酰氯，对苯二甲酰氯或其混合物中的至少一种之间进行反应来制备，以产生羟基封端的聚酯中间体，然后进行中间体与碳酸酯前体的反应，优选在二羟基化合物如双酚A的存在下进行。产物具有优异的物理性能，包括高度的耐候性。它们可以与其他聚合物如聚碳酸酯，聚（亚烷基羧酸酯），聚芳酯，聚醚酰亚胺和加成聚合物共混以改善其耐候性。

8. 发明授权

US06291589B1 Thermally stable polymers, method of preparation, and articles made therefrom 有权
公开(公告)号：US06291589B1
公开(公告)日：2001-09-18
申请号：US09656208
申请日：2000-09-06
申请人： Daniel Joseph Brunelle , Joseph Anthony Suriano , Taeseok Jang , Tiberiu Mircea Siclovan , James Edward Pickett , Gregory Allen O'Neil
发明人： Daniel Joseph Brunelle , Joseph Anthony Suriano , Taeseok Jang , Tiberiu Mircea Siclovan , James Edward Pickett , Gregory Allen O'Neil
IPC分类号： C08L6702
CPC分类号： B32B27/08 , B32B27/06 , B32B27/18 , B32B27/20 , B32B27/36 , B32B27/365 , B32B2307/4026 , B32B2367/00 , B32B2369/00 , B32B2605/00 , C08G63/19 , C08G63/64 , C08G63/676 , C08G63/6956 , C08G63/79 , C08G63/85 , C08J7/047 , C08J2467/00 , C09D167/03 , F02B61/045 , Y10T428/1355 , Y10T428/1359 , Y10T428/25 , Y10T428/254 , Y10T428/2942 , Y10T428/31507 , Y10T428/31565 , Y10T428/31786
摘要： Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.

9. 发明授权

US08580341B2 Method of making composite membrane 有权
标题翻译：制造复合膜的方法
公开(公告)号：US08580341B2
公开(公告)日：2013-11-12
申请号：US12470606
申请日：2009-05-22
申请人： Hua Wang , Su Lu , Hua Li , Steven Thomas Rice , Joseph Anthony Suriano , Bing Zhang , Chen Wang , Lawrence Charles Costa , Steven John Harrold , David Allen Olson , Wenqing Peng
发明人： Hua Wang , Su Lu , Hua Li , Steven Thomas Rice , Joseph Anthony Suriano , Bing Zhang , Chen Wang , Lawrence Charles Costa , Steven John Harrold , David Allen Olson , Wenqing Peng
IPC分类号： B01D71/56
CPC分类号： B01D69/125 , B01D67/0006 , B01D71/56 , B01D2323/40 , Y10T428/249991
摘要： The present invention provides a composite membrane comprising a porous base membrane and a polyamide coating disposed on said porous base membrane, said polyamide coating comprising a C3-C8 cyclic carbonyl compound and a C1-C8 amide compound, said amide compound comprising at least one N—H moiety. In addition the present invention provides a method of preparing a composite membrane comprising contacting under interfacial polymerization conditions an organic solution comprising a polyacid halide with an aqueous solution comprising a polyamine, said contacting being carried out on a surface of a porous base membrane, said organic solution further comprising a C3-C8 cyclic carbonyl compound, said aqueous solution comprising a C1-C8 amide compound, said amide compound comprising at least one N—H moiety.
摘要翻译：本发明提供了一种复合膜，其包括多孔基膜和设置在所述多孔基膜上的聚酰胺涂层，所述聚酰胺涂层包含C3-C8环状羰基化合物和C1-C8酰胺化合物，所述酰胺化合物包含至少一个NH 部分。另外本发明提供一种制备复合膜的方法，包括在界面聚合条件下使包含多酰卤的有机溶液与包含多胺的水溶液接触，所述接触在多孔基膜的表面上进行，所述有机所述溶液还包含C 3 -C 8环状羰基化合物，所述水溶液包含C 1 -C 8酰胺化合物，所述酰胺化合物包含至少一个NH部分。

10. 发明授权

US07669720B2 Functional polyarylethers 失效
标题翻译：功能性聚芳醚
公开(公告)号：US07669720B2
公开(公告)日：2010-03-02
申请号：US11611642
申请日：2006-12-15
申请人： Yanshi Zhang , Daniel Steiger , Joseph Anthony Suriano , Gary William Yeager
发明人： Yanshi Zhang , Daniel Steiger , Joseph Anthony Suriano , Gary William Yeager
IPC分类号： B01D71/52 , B01D71/50 , B01D71/66 , B01D71/68 , C08G61/00
CPC分类号： C08G65/40 , C08G65/48 , C08G75/23
摘要： Membranes comprising functional polyarylether having structural units of formula I are useful for hemodialysis and hemofiltration: wherein X is selected from Br, NR4R5, OOCR6, OR7, NR4CONR5R6, NR4COOR5R6 and combinations thereof; R1, R2 and R3 are independently at each occurrence CH2X, H, halo, cyano, nitro, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12aromatic radical or a combination thereof; R4 and R5 are independently H, a C1-10 aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical, or a combination thereof; R6 is H, a C2-10 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R7 is OCH2CH2(OCH2CH2)nOH or OOCCH2(OCH2CH2)nCH3; Z is a direct bond, O, S, SO, SO2, CO, phenylphospinyl oxide, alkenyl, alkynyl, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; a, b, and c are independently 1 or 2; and m, n and p are independently 0 or 1.
摘要翻译：包含具有式I结构单元的官能聚芳醚的膜可用于血液透析和血液滤过：其中X选自Br，NR4R5，OOCR6，OR7，NR4CONR5R6，NR4COOR5R6及其组合; R 1，R 2和R 3各自独立地为CH 2，H，卤素，氰基，硝基，C 1 -C 12脂族基，C 3 -C 12环脂族基，C 3 -C 12芳族基或其组合; R 4和R 5独立地为H，C 1-10脂族基团，C 3 -C 12环脂族基团，C 3 -C 12芳族基团或其组合; R 6是H，C 2-10脂族基团，C 3 -C 12脂环族基团，C 3 -C 12芳族基团或其组合; R7是OCH2CH2（OCH2CH2）nOH或OOCCH2（OCH2CH2）nCH3; Z是直接键，O，S，SO，SO 2，CO，苯基氧化膦，烯基，炔基，C 1 -C 12脂族基，C 3 -C 12环脂族基，C 3 -C 12芳族基或其组合; a，b和c独立地为1或2; m，n和p独立地为0或1。

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