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1. 发明授权

US06380276B1 Metal complexes immobilized in porous organic hosts 失效
标题翻译：固定在多孔有机物中的金属配合物
公开(公告)号：US06380276B1
公开(公告)日：2002-04-30
申请号：US09229247
申请日：1999-01-12
申请人： Andrew Borovik , Anjal Sharma , John Krebs
发明人： Andrew Borovik , Anjal Sharma , John Krebs
IPC分类号： C08J900
CPC分类号： B01D53/565 , B01D53/02 , B01J20/223 , B01J20/268 , B01J31/1658 , B01J31/1815 , B01J31/2243 , B01J35/10 , B01J2531/0252 , B01J2531/845
摘要： Polymer-metal ion composites and methods are provided for reversibly binding target compounds using such composites. Broadly, the composites comprise an amorphous polymer matrix having a plurality of channels with metal ion-ligand complexes immobilized therein. The composites are formed by polymerizing a polymeric moiety with a metal complex template in the presence of a solvent. The template is formed of a metal ion having a ligand bonded thereto as well as to polymer matrix. The metal ion and ligand are selected to yield a composite having a particular chemical and/or physical environment around the metal sites, depending upon the desired end use. Preferred metal ions include ions of the transition metals. The composites can be contacted with target compounds for reversibly binding the compounds. Exemplary compounds include those selected from the group consisting of oxygen, carbon monoxide, carbon dioxide, compounds having an atom of P, S, or N, and mixtures thereof. The compound can be released from the composites at the desired time and location by heating the compound-containing composite.
摘要翻译：提供聚合物 - 金属离子复合材料和方法，以使用这种复合材料可逆地结合目标化合物。广泛地，复合材料包含具有固定有金属离子 - 配体配合物的多个通道的无定形聚合物基质。通过在溶剂存在下将聚合物部分与金属络合物模板聚合而形成复合材料。模板由与其结合的配体以及聚合物基质的金属离子形成。选择金属离子和配体以产生具有围绕金属位点的特定化学和/或物理环境的复合材料，这取决于所需的最终用途。优选的金属离子包括过渡金属的离子。可以将复合材料与目标化合物接触以可逆地结合化合物。示例性化合物包括选自氧，一氧化碳，二氧化碳，具有P，S或N原子的化合物及其混合物。可以通过加热含化合物的复合材料，在期望的时间和位置从复合材料中释放化合物。

2. 发明授权

US963506A Horse-overshoe. 失效
公开(公告)号：US963506A
公开(公告)日：1910-07-05
申请号：US1910549585
申请日：1910-03-16
申请人： JOHN KREBS , BOYD ANDREW
发明人： BOYD ANDREW
CPC分类号： A01L7/04

3. 发明授权

US06344492B1 Metal complexes immobilized organic in porous organic hosts 失效
标题翻译：金属络合物在多孔有机物中固定有机物
公开(公告)号：US06344492B1
公开(公告)日：2002-02-05
申请号：US09669010
申请日：2000-09-25
申请人： Andrew Borovik , Anjal Sharma , John Krebs
发明人： Andrew Borovik , Anjal Sharma , John Krebs
IPC分类号： C08J940
CPC分类号： B01D53/565 , B01D53/02 , B01J20/223 , B01J20/268 , B01J31/1658 , B01J31/1815 , B01J31/2243 , B01J35/10 , B01J2531/0252 , B01J2531/845
摘要： Polymer-metal ion composites and methods are provided for reversibly binding target compounds using such composites. Broadly, the composites comprise an amorphous polymer matrix having a plurality of channels with metal ion-ligand complexes immobilized therein. The composites are formed by polymerizing a polymeric moiety with a metal complex template in the presence of a solvent. The template is formed of a metal ion having a ligand bonded thereto as well as to polymer matrix. The metal ion and ligand are selected to yield a composite having a particular chemical and/or physical environment around the metal sites, depending upon the desired end use. Preferred metal ions include ions of the transition metals. The composites can be contacted with target compounds for reversibly binding the compounds. Exemplary compounds include those selected from the group consisting of oxygen, carbon monoxide, carbon dioxide, compounds having an atom of P, S, or N, and mixtures thereof. The compound can be released from the composites at the desired time and location by heating the compound-containing composite.
摘要翻译：提供聚合物 - 金属离子复合材料和方法，以使用这种复合材料可逆地结合目标化合物。广泛地，复合材料包含具有固定有金属离子 - 配体配合物的多个通道的无定形聚合物基质。通过在溶剂存在下将聚合物部分与金属络合物模板聚合而形成复合材料。模板由与其结合的配体以及聚合物基质的金属离子形成。选择金属离子和配体以产生具有围绕金属位点的特定化学和/或物理环境的复合材料，这取决于所需的最终用途。优选的金属离子包括过渡金属的离子。可以将复合材料与目标化合物接触以可逆地结合化合物。示例性化合物包括选自氧，一氧化碳，二氧化碳，具有P，S或N原子的化合物及其混合物。可以通过加热含化合物的复合材料，在期望的时间和位置从复合材料中释放化合物。

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