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1. 发明授权

US08541639B2 Process for producing para-xylene 失效
标题翻译：生产对二甲苯的方法
公开(公告)号：US08541639B2
公开(公告)日：2013-09-24
申请号：US13594286
申请日：2012-08-24
申请人： John Di-Yi Ou , John R. Porter
发明人： John Di-Yi Ou , John R. Porter
IPC分类号： C07C5/27
CPC分类号： C07C5/2729 , C07C5/22 , C07C5/222 , C07C7/12 , C07C7/14 , C07C15/08
摘要： A process for producing a PX-rich product, the process comprising: (a) providing a PX-depleted stream; (b) isomerizing at least a portion of the PX-depleted stream to produce an isomerized stream having a PX concentration greater than the PX-depleted stream and a benzene concentration of less than 1,000 ppm and a C9+ hydrocarbons concentration of less than 5,000 ppm; and (c) separating the isomerized stream by selective adsorption.
摘要翻译：一种富含PX的产物的方法，该方法包括：（a）提供PX-贫化的物流; （b）将至少一部分PX-贫化物流异构化以产生PX浓度大于PX-贫化物流的异构化物流，且苯浓度小于1,000ppm，C9 +烃浓度小于5,000ppm; 和（c）通过选择性吸附分离异构化流。

2. 发明授权

US08344197B2 Production of para-xylene by the methylation of benzene and/or toluene 有权
标题翻译：通过苯和/或甲苯的甲基化生产对二甲苯
公开(公告)号：US08344197B2
公开(公告)日：2013-01-01
申请号：US12894778
申请日：2010-09-30
申请人： James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
发明人： James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
IPC分类号： C07C2/66
CPC分类号： C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： In a process for the production of para-xylene, methanol is preheated to a first temperature, an aromatic feedstock comprising toluene and/or benzene is preheated to a second temperature and the preheated methanol and aromatic feedstocks are fed to a reactor at a first methanol to aromatic feedstock molar ratio. The preheated aromatic feedstock is contacted with the preheated methanol under alkylation conditions in the reactor in the presence of a catalyst so that the methanol reacts with the aromatic feedstock to produce an effluent comprising para-xylene. During the reaction, a temperature is measured within the reactor and is compared with a predetermined optimal temperature. The methanol to aromatic feedstock molar ratio is then adjusted in a manner to reduce any difference between the measured and predetermined optimal temperatures in the reactor.
摘要翻译：在制备对二甲苯的方法中，将甲醇预热至第一温度，将包含甲苯和/或苯的芳族原料预热至第二温度，并将预热的甲醇和芳族原料以第一个甲醇与芳烃原料摩尔比。预热的芳族原料在催化剂存在下在反应器中在烷基化条件下与预热的甲醇接触，使得甲醇与芳族原料反应以产生包含对二甲苯的流出物。在反应期间，在反应器内测量温度并与预定的最佳温度进行比较。然后以降低反应器中测量的和预定的最佳温度之间的任何差异的方式调节甲醇与芳族原料的摩尔比。

3. 发明授权

US08273934B2 Process for producing para-xylene 有权
标题翻译：生产对二甲苯的方法
公开(公告)号：US08273934B2
公开(公告)日：2012-09-25
申请号：US12612007
申请日：2009-11-04
申请人： John Di-Yi Ou , John R. Porter
发明人： John Di-Yi Ou , John R. Porter
IPC分类号： C07C5/27
CPC分类号： C07C5/2729 , C07C5/22 , C07C5/222 , C07C7/12 , C07C7/14 , C07C15/08
摘要： A process for producing a PX-rich product, the process comprising: (a) providing a PX-depleted stream; (b) isomerizing at least a portion of the PX-depleted stream to produce an isomerized stream having a PX concentration greater than the PX-depleted stream and a benzene concentration of less than 1,000 ppm and a C9+ hydrocarbons concentration of less than 5,000 ppm; and (c) separating the isomerized stream by selective adsorption.
摘要翻译：一种富含PX的产物的方法，该方法包括：（a）提供PX-贫化的物流; （b）将至少一部分PX-贫化物流异构化以产生PX浓度大于PX-贫化物流的异构化物流，且苯浓度小于1,000ppm，C9 +烃浓度小于5,000ppm; 和（c）通过选择性吸附分离异构化流。

4. 发明申请

US20100152508A1 Process for Producing Para-Xylene 有权
标题翻译：生产对二甲苯的方法
公开(公告)号：US20100152508A1
公开(公告)日：2010-06-17
申请号：US12612007
申请日：2009-11-04
申请人： John Di-Yi Ou , John R. Porter
发明人： John Di-Yi Ou , John R. Porter
IPC分类号： C07C5/00
CPC分类号： C07C5/2729 , C07C5/22 , C07C5/222 , C07C7/12 , C07C7/14 , C07C15/08
摘要： A process for producing a PX-rich product, the process comprising: (a) providing a PX-depleted stream; (b) isomerizing at least a portion of the PX-depleted stream to produce an isomerized stream having a PX concentration greater than the PX-depleted stream and a benzene concentration of less than 1,000 ppm and a C9+ hydrocarbons concentration of less than 5,000 ppm; and (c) separating the isomerized stream by selective adsorption.
摘要翻译：一种富含PX的产物的方法，该方法包括：（a）提供PX-贫化的物流; （b）将至少一部分PX-贫化物流异构化以产生PX浓度大于PX-贫化物流的异构化物流，且苯浓度小于1,000ppm，C9 +烃浓度小于5,000ppm; 和（c）通过选择性吸附分离异构化流。

5. 发明授权

US07683233B2 Process for producing para-xylene 失效
标题翻译：生产对二甲苯的方法
公开(公告)号：US07683233B2
公开(公告)日：2010-03-23
申请号：US11894187
申请日：2007-08-20
申请人： John Di-Yi Ou , Sebastian C. Reyes , Bal K. Kaul , Wenyih Frank Lai , Brenda A. Raich , Charanjit S. Paur
发明人： John Di-Yi Ou , Sebastian C. Reyes , Bal K. Kaul , Wenyih Frank Lai , Brenda A. Raich , Charanjit S. Paur
IPC分类号： C07C7/13
CPC分类号： C07C7/13 , C07C15/08
摘要： In a process for producing a para-xylene enriched product from a gaseous mixture comprising at least para-xylene, meta-xylene and ortho-xylene, the gaseous mixture is contacted with an adsorbent capable of selectively adsorbing para-xylene and comprising a crystalline molecular sieve having an average crystal size between about 0.5 micron and about 20 microns. The contacting is conducted at a temperature and pressure such that at least part of the para-xylene in the mixture is adsorbed by the adsorbent to produce a para-xylene-depleted effluent stream. The para-xylene is then desorbed from said adsorbent and collected to form a para-xylene enriched stream. The adsorption and desorption steps are repeated for a plurality of cycles, such that the time between successive contacting steps is no more than 10 seconds.
摘要翻译：在从至少包含对二甲苯，间二甲苯和邻二甲苯的气体混合物生产对二甲苯富集产物的方法中，气态混合物与能够选择性吸附对二甲苯并且包含结晶分子平均晶体尺寸在约0.5微米至约20微米之间的筛子。接触在温度和压力下进行，使得混合物中的至少部分对二甲苯被吸附剂吸附，以产生对二甲苯贫乏的流出物流。然后将对二甲苯从所述吸附剂中解吸并收集以形成对二甲苯富集流。吸附和解吸步骤重复多个循环，使得连续接触步骤之间的时间不超过10秒。

6. 发明授权

US07626065B2 Process for producing para-xylene 有权
标题翻译：生产对二甲苯的方法
公开(公告)号：US07626065B2
公开(公告)日：2009-12-01
申请号：US12196515
申请日：2008-08-22
申请人： John Di-Yi Ou , Harold W. Helmke, Jr. , John R. Porter
发明人： John Di-Yi Ou , Harold W. Helmke, Jr. , John R. Porter
IPC分类号： C07C5/27
CPC分类号： C07C5/2729 , C07C5/2732 , C07C7/13 , C07C15/08
摘要： A process for producing a PX-rich product comprises (a) separating a feedstock containing C8 hydrocarbons to produce a C8 hydrocarbons rich stream; (b) separating at least a first portion of the C8 hydrocarbons rich stream to produce a first PX-rich stream and a first PX-depleted stream; (c) isomerizing at least a portion of the first PX-depleted stream to produce a first isomerized stream having a higher PX concentration than the first PX-depleted stream; (d) separating a second portion of the C8 hydrocarbons rich stream and/or at least a portion of the first isomerized stream to produce a second PX-rich stream and a second PX-depleted stream; (e) isomerizing at least a portion of the second PX-depleted stream to produce a second isomerized stream having a higher PX concentration than the second PX-depleted stream; (f) recovering at least a portion of at least one of the first and second PX-rich streams as PX-rich product; and (g) supplying at least a portion of at least one of the first isomerized stream, the second isomerized stream, the first PX-rich stream, and the second PX-rich stream to the separating (a).
摘要翻译：制备富PX产品的方法包括（a）分离含有C8烃的原料以产生富含C8烃的物流; （b）分离至少第一部分的富碳氢化合物流以产生第一富含PX的物流和第一个PX-贫化的物流; （c）将至少一部分第一PX-贫化物流异构化以产生具有比第一个PX-贫化物流更高的PX浓度的第一异构化物流; （d）分离第二部分的富碳氢化合物流和/或第一异构化物流的至少一部分以产生第二富含PX的物流和第二个PX-贫化的物流; （e）将至少一部分第二PX-贫化物流异构化以产生具有比第二个PX-贫化物流更高的PX浓度的第二异构化物流; （f）回收至少一部分第一和第二富含PX的物流中的一部分作为富含PX的产物; 和（g）将至少一部分第一异构化物流，第二异构化物流，第一富含PX的物流和第二富含PX的物流的至少一部分供应至分离物（a）。

7. 发明申请

US20090057200A1 Production of an upgraded stream from steam cracker tar by ultrafiltration 有权
标题翻译：通过超滤从蒸汽裂解焦油生产升级的流
公开(公告)号：US20090057200A1
公开(公告)日：2009-03-05
申请号：US11980162
申请日：2007-10-30
申请人： Daniel P. Leta , Edward W. Corcoran , Eric B. Sirota , Stephen M. Cundy , Kirk C. Nadler , John Di-Yi Ou , Paul F. Keusenkothen
发明人： Daniel P. Leta , Edward W. Corcoran , Eric B. Sirota , Stephen M. Cundy , Kirk C. Nadler , John Di-Yi Ou , Paul F. Keusenkothen
IPC分类号： C10G9/00
CPC分类号： C10G55/04 , C10G31/11
摘要： This invention relates to a process of producing an upgraded product stream from steam cracker tar feedstream suitable for use in refinery or chemical plant processes or for utilization in fuel oil sales or blending. This process utilizes an ultrafiltration process for separating the steam cracker tar constituents resulting in a high recovery, low-energy process with improved separation and product properties.
摘要翻译：本发明涉及一种从适用于炼油厂或化工厂工艺的蒸汽裂解塔焦油原料生产升级产品流的方法或用于燃料油销售或混合的方法。该方法利用超滤方法分离蒸汽裂解焦油成分，导致高回收率，低能量的方法，具有改进的分离和产物性能。

8. 发明授权

US07153807B2 Catalysts for selective hydrogenation of alkynes and alkadienes 有权
标题翻译：用于烯烃和链烯二烯的选择性氢化的催化剂
公开(公告)号：US07153807B2
公开(公告)日：2006-12-26
申请号：US10379495
申请日：2003-03-04
申请人： Michel Molinier , John Di-Yi Ou , Michael A. Risch
发明人： Michel Molinier , John Di-Yi Ou , Michael A. Risch
IPC分类号： B01J27/22 , B01J27/224 , B01J21/08 , B01J23/56 , B01J23/44
CPC分类号： B01J23/66 , B01J21/04 , B01J23/46 , B01J23/462 , B01J23/468 , B01J23/50 , B01J23/60 , B01J23/892 , C10G45/36 , C10G45/38 , C10G45/40
摘要： Catalysts have been discovered that are useful in hydrogenation reactions, and particularly for the selective hydrogenation of acetylene and/or methyl acetylene (MA) and/or propadiene (PD) in light olefin-rich feedstreams. These catalysts can selectively hydrogenate acetylene with less selectivity to making oligomers (green oil) as compared with existing commercial catalysts, particularly palladium catalysts. These catalysts are non-palladium catalysts, and have three different constituents that are metal or metal-based components. The metal of the first constituent may be nickel or platinum, the metal of the second constituent may be from Groups 1–10, and the metal of the third constituent may be from Groups 11–12, where the Groups are of the Periodic Table of Elements (new IUPAC notation).
摘要翻译：已经发现可用于氢化反应的催化剂，特别是用于在轻质富烯烃进料流中乙炔和/或甲基乙炔（MA）和/或丙二烯（PD）的选择性氢化。与现有的商业催化剂，特别是钯催化剂相比，这些催化剂可以选择性地氢化乙炔，从而制备低聚物（绿油）的选择性较低。这些催化剂是非钯催化剂，并且具有金属或金属基组分的三种不同组分。第一成分的金属可以是镍或铂，第二成分的金属可以是1-10族，第三成分的金属可以是11-12族，其中该基团是周期表的元素（新的IUPAC符号）。

9. 发明授权

US07038097B2 Dual bed process using two different catalysts for selective hydrogenation of acetylene and dienes 失效
标题翻译：使用两种不同的催化剂对乙炔和二烯烃进行选择性氢化的双床方法
公开(公告)号：US07038097B2
公开(公告)日：2006-05-02
申请号：US10379274
申请日：2003-03-04
申请人： Michel Molinier , John Di-Yi Ou , Michael A. Risch , John Scott Buchanan
发明人： Michel Molinier , John Di-Yi Ou , Michael A. Risch , John Scott Buchanan
IPC分类号： C07C5/05 , C07C5/08 , C07C5/09
CPC分类号： C10G45/32 , C10G65/06
摘要： It has been discovered that a dual bed process using two different catalysts for the selective hydrogenation of acetylene and/or methyl acetylene (MA) and/or propadiene (PD) in a light olefin-rich feedstream can be accomplished with less selectivity to making oligomers (green oil) as compared with existing commercial technologies, if a low oligomers selectivity catalyst is used first in the process. A palladium catalyst may be used as a second, sequential catalyst to further hydrogenate acetylene and/or MAPD while consuming at least a portion of the balance of the hydrogen present. The first catalyst should be different from the second catalyst.
摘要翻译：已经发现，使用两种不同催化剂在轻烯烃进料流中选择性氢化乙炔和/或甲基乙炔（MA）和/或丙二烯（PD）的双床方法可以以较少的制备低聚物的选择性来实现（绿色油）与现有的商业技术相比，如果在该过程中首先使用低低聚物选择性催化剂。可以使用钯催化剂作为第二顺序催化剂，以进一步氢化乙炔和/或MAPD，同时消耗存在的氢的余量的至少一部分。第一催化剂应与第二催化剂不同。

10. 发明授权

US06376733B1 Process for production of paraxylene 失效
标题翻译：对二甲苯生产工艺
公开(公告)号：US06376733B1
公开(公告)日：2002-04-23
申请号：US08591064
申请日：1996-01-25
申请人： John Michael Ferraro , Robert Michael Osman , John Di-Yi Ou , Graeme Ian Cox , James Richardson Lattner , Kenneth Ray Clem
发明人： John Michael Ferraro , Robert Michael Osman , John Di-Yi Ou , Graeme Ian Cox , James Richardson Lattner , Kenneth Ray Clem
IPC分类号： C07C7144
CPC分类号： C07C15/08 , C07C7/005 , Y02P20/52
摘要： This invention relates to a process and a chemical plant for the production primarily of paraxylene. In particular the process and chemical plant utilise zeolite membranes for enhanced paraxylene production.
摘要翻译：本发明涉及主要用于对二甲苯生产的方法和化学设备。特别是工艺和化学工厂利用沸石膜来增强对二甲苯生产。

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