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    • 1. 发明授权
    • Preferential chlorination of alumina in kaolinitic ores
    • 高岭石矿中优先氯化氧化铝
    • US4139602A
    • 1979-02-13
    • US814834
    • 1977-07-11
    • Ronald WyndhamJohn C. Terry
    • Ronald WyndhamJohn C. Terry
    • C01F7/56C01F7/60
    • C01F7/60
    • The present invention provides a novel process for the preferential chlorination of alumina over silica in the carbo-chlorination of kaolinitic ores to produce aluminum chloride. The process comprises introducing small amounts of alkali metal compounds with oxyanions into the carbo-chlorination process. Preferred embodiments are directed to particular compounds of alkali metals with oxyanions selected from the group consisting of carbonates, sulfates, hydroxides, oxides, phosphates, and the like. The present invention results in significantly reduced energy, manufacturing, and equipment costs and thus represents a breakthrough in the utilization of domestic ores such as kaolinitic clay for the production of aluminum chloride or alumina through oxidation of the aluminum chloride.
    • 本发明提供了一种用于在高岭石矿石的碳氯化中优先氧化二氧化硅以制备氯化铝的新方法。 该方法包括将少量含有阴离子的碱金属化合物引入到碳氯化方法中。 优选的实施方案涉及具有选自碳酸盐,硫酸盐,氢氧化物,氧化物,磷酸盐等的含氧阴离子的碱金属的具体化合物。 本发明导致能量,制造和设备成本的显着降低,因此代表了通过氧化氯化铝来生产氯化铝或氧化铝的高岭土等家用矿石的利用的突破。