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1. 发明授权

US5618905A Partially methylated polyamines as epoxy curing agents 失效
标题翻译：部分甲基化多胺作为环氧固化剂
公开(公告)号：US5618905A
公开(公告)日：1997-04-08
申请号：US584937
申请日：1996-01-16
申请人： John A. Marsella , William E. Starner , Richard S. Myers
发明人： John A. Marsella , William E. Starner , Richard S. Myers
IPC分类号： C08G59/40 , C08G59/50 , C08L63/00 , C08G59/44
CPC分类号： C08G59/5006 , C08G59/50
摘要： A curable epoxy resin composition comprising a polyepoxide resin and an amine curative characterized in that the amine curative comprises a partially methylated polyalkylene polyamine having at least three amine nitrogens and at least two active amine hydrogens.
摘要翻译：一种可固化环氧树脂组合物，其包含聚环氧树脂和胺固化剂，其特征在于所述胺固化剂包含具有至少三个胺氮和至少两个活性胺氢的部分甲基化聚亚烷基多胺。

2. 发明授权

US4855425A Process for the selective synthesis of ethylene diamines 失效
标题翻译：选择性合成乙二胺的方法
公开(公告)号：US4855425A
公开(公告)日：1989-08-08
申请号：US187707
申请日：1988-04-29
申请人： John A. Marsella
发明人： John A. Marsella
IPC分类号： C07C209/16 , C07D295/023
CPC分类号： C07D295/023 , C07C209/16
摘要： The present invention is a process for the selective synthesis of alkanediamines by reacting a secondary amine with an alkanediol. High conversions and high selectivity for the production of alkanediamines is achieved by carrying out the reaction in the presence of a compound or complex of ruthenium in the absence of an organic phosphine co-catalyst.
摘要翻译：本发明是通过使仲胺与链烷二醇反应来选择性合成烷二胺的方法。通过在不存在有机膦助催化剂的情况下在钌化合物或络合物的存在下进行反应来实现烷基二胺的高转化率和高选择性。

3. 依法登记的发明

USH919H Process for producing polyamine boranes 失效
标题翻译：生产聚氨酯的方法
公开(公告)号：USH919H
公开(公告)日：1991-05-07
申请号：US388540
申请日：1989-08-02
申请人： John A. Marsella
发明人： John A. Marsella
IPC分类号： C07F5/00 , C07F5/02 , C07C69/76
CPC分类号： C07F5/022 , C07F5/00
摘要： This invention relates to a process for producing tertiarydiamine-boranes by reacting a tertiary diamine with a borohydride in the presence of a carboxylic or mineral acid source. Water is included in the reaction medium in a catalytic amount but insufficient for forming two phases. Excellent selectivity to tertiary diamine-boranes is achieved.

4. 发明授权

US4709034A Process for the synthesis of hydroxyalkyl amines and hydroxyalkyl piperazines 失效
标题翻译：用于合成羟烷基胺和羟基烷基哌嗪的方法
公开(公告)号：US4709034A
公开(公告)日：1987-11-24
申请号：US829680
申请日：1986-02-14
申请人： John A. Marsella
发明人： John A. Marsella
IPC分类号： C07D295/08 , C07D295/023 , C07D295/088 , C07D241/04
CPC分类号： C07D295/023 , C07D295/088
摘要： The present invention comprises a process for the synthesis of hydroxyalkyl amines, hydroxyalkyl piperazines, or alkyl piperazines from alkylene glycols and ammonia or alkyl amines using a substantially soluble transition metal carbonyl complex catalyst precursor.
摘要翻译：本发明包括使用基本上可溶的过渡金属羰基络合物催化剂前体从亚烷基二醇和氨或烷基胺合成羟烷基胺，羟基烷基哌嗪或烷基哌嗪的方法。

5. 发明授权

US5426157A Flexibilized polyepoxide resins incorporating poly-N-methylated secondary amines 失效
标题翻译：结合聚-N-甲基化仲胺的柔性聚环氧化物树脂
公开(公告)号：US5426157A
公开(公告)日：1995-06-20
申请号：US213647
申请日：1994-03-16
申请人： William E. Starner , John A. Marsella , Richard S. Myers
发明人： William E. Starner , John A. Marsella , Richard S. Myers
IPC分类号： C08G18/58 , C08G18/67 , C08G59/06 , C08G59/40 , C08G59/50 , C08L63/00 , C08G18/04
CPC分类号： C08G59/5006 , C08G18/672 , C08L63/00 , Y10S525/92
摘要： This invention relates to improved polyepoxide resins having enhanced physical and elastic properties. The polyepoxide resins comprise a polyepoxide resin based on a polyglycidyl ether of a phenolic-type compound and an acrylate-terminated urethane prepolymer. The improvement in the polyepoxide resin formulation comprises incorporating a polymethylated amine curative having two secondary amine hydrogens represented by the formula: ##STR1## wherein R is alkylene or polyalkylene polyamine having from 2 to 20 carbon atoms. The presence of the aliphatic amine reactive component along with the acrylate-terminated urethane prepolymer results in an epoxy resin having enhanced properties.
摘要翻译：本发明涉及具有增强的物理和弹性特性的改进的聚环氧化物树脂。聚环氧化物树脂包括基于酚类化合物的多缩水甘油醚和丙烯酸酯封端的氨基甲酸酯预聚物的聚环氧树脂。聚环氧化物树脂制剂的改进包括加入具有由下式表示的两个仲胺氢的聚甲基化胺固化剂：其中R是亚烷基或具有2至20个碳原子的聚亚烷基多胺。脂族胺反应性成分与丙烯酸酯封端的氨基甲酸酯预聚物的存在导致具有增强性能的环氧树脂。

6. 发明授权

US5149883A Preparation of aliphatic dihydroperoxides 失效
标题翻译：二氢二恶烷的制备
公开(公告)号：US5149883A
公开(公告)日：1992-09-22
申请号：US699422
申请日：1991-05-13
申请人： John A. Marsella , Reinaldo M. Machado
发明人： John A. Marsella , Reinaldo M. Machado
IPC分类号： C07C407/00 , C07C409/04
CPC分类号： C07C409/04 , C07C407/00
摘要： This invention relates to an improved process for preparing dihydroperoxyalkanes and, particularly, dimethyldihydroperoxyhexane. The improvement resides in utilizing a tetrahydrofuran derivative which is a liquid as a feedstock. This feedstock then is reacted with hydrogen peroxide in the presence of sulfuric acid to form the dihydroperoxide.

7. 发明授权

US5026929A Synthesis of highly fluorinated aromatic compounds 失效
标题翻译：高度氟化芳族化合物的合成
公开(公告)号：US5026929A
公开(公告)日：1991-06-25
申请号：US477289
申请日：1990-02-08
申请人： John A. Marsella , Guido P. Pez , Anne M. Coughlin
发明人： John A. Marsella , Guido P. Pez , Anne M. Coughlin
IPC分类号： C07C17/00
CPC分类号： C07C17/00
摘要： A process is disclosed for making a highly fluorinated aromatic compound by contacting a perfluorocycloalkane, such as perfluorodecahydronaphthalene, with a complex of a metal from Groups IA and IIA of the Periodic Table and an organic electron acceptor. The reaction is carried out in an organic solvent and under reducing conditions which are relatively moderate. Best results are obtained using a perfluorocycloalkane having 2-4 condensed rings and a complex of either sodium or lithium and benzophenone thereby making a perfluorinated condensed ring aromatic compound such as perfluoronaphthalene or perfluorophenanthrene.
摘要翻译：公开了通过使全氟环烷烃如全氟代十氢萘与元素周期表IA和IIA族金属络合物和有机电子受体接触来制备高度氟化的芳族化合物的方法。该反应在有机溶剂中并在相对温和的还原条件下进行。使用具有2-4个稠环的全氟环烷烃和钠或锂和二苯甲酮的络合物得到最佳结果，由此制得全氟化稠环芳族化合物如全氟萘或全氟菲。

8. 发明授权

US4745190A Selective synthesis of substituted amines 失效
标题翻译：取代胺的选择性合成
公开(公告)号：US4745190A
公开(公告)日：1988-05-17
申请号：US846375
申请日：1986-03-31
申请人： John A. Marsella
发明人： John A. Marsella
IPC分类号： C07D295/023 , C07D295/088 , C07D265/30 , C07C85/06 , C07D207/00
CPC分类号： C07D295/023 , C07D295/088
摘要： Selective mono- or di-amination of alkanediols is controllably obtained by catalytic reaction with secondary amines at moderate temperature and autogenous pressure, by selection of the catalyst employed. Ruthenium complexes compounded or admixed with selected organic phosphines, such as triphenylphosphine, favor high yields of alkanolamines, while ruthenium complexes in the absence of organic phosphines favor production of alkylenediamines. Iridium complexes with or without organic phosphines in admixture or chemical combination, also promote production of alkylenediamines.
摘要翻译：通过选择所用的催化剂，可以通过与仲胺在中等温度和自生压力下的催化反应可控地获得链烷二醇的选择性单 - 或二 - 胺化。与选择的有机膦如三苯基膦混合或混合的钌络合物有利于高产率的烷醇胺，而不存在有机膦的钌络合物有利于生产亚烷基二胺。具有或不含有机膦的铱络合物在混合或化学组合中也促进亚烷基二胺的生产。

9. 发明授权

US4680393A Process for the selective synthesis of tertiary alkanolamines 失效
标题翻译：选择性合成叔链烷醇胺的方法
公开(公告)号：US4680393A
公开(公告)日：1987-07-14
申请号：US861029
申请日：1986-05-08
申请人： John A. Marsella
发明人： John A. Marsella
IPC分类号： C07D295/088 , C07C85/06 , C07C91/06 , C07D295/08
CPC分类号： C07D295/088
摘要： The present invention is a process for the synthesis of tertiary alkanolamines by reacting a secondary amine with an alkanediol. High selectivity for the production of alkanolamines is achieved by carrying out the reaction in the presence of a compound or complex of ruthenium in chemical combination or in admixture with an organic phosphine ligand. The organic phosphine ligand is present in an amount such that the ratio of gram mole ligand/gram atom ruthenium is greater than 5.
摘要翻译：本发明是通过使仲胺与链烷二醇反应来合成叔链烷醇胺的方法。通过在化学组合的化合物或钌络合物或有机膦配体的混合物的存在下进行反应来实现对烷醇胺的生产的高选择性。有机膦配体的存在量使得克摩尔配体/克原子钌的比例大于5。

10. 发明授权

US4558157A Synthesis of dimethylformamide 失效
标题翻译：二甲基甲酰胺的合成
公开(公告)号：US4558157A
公开(公告)日：1985-12-10
申请号：US617305
申请日：1984-06-05
申请人： John A. Marsella , Guido P. Pez
发明人： John A. Marsella , Guido P. Pez
IPC分类号： C07C231/00 , C07C233/00 , C07C102/00
CPC分类号： C07C231/00 , C07C233/00
摘要： In the catalytic reaction of ammonia or formamide with CO and H.sub.2, exceptionally high yields of mono- and di-methyl formamide are obtained among the reaction products when the reaction is carried out in the presence of a platinum group catalyst soluble in the reaction medium, particularly a compound or complex of ruthenium or rhodium, employing a relatively non-volatile polar solvent which does not contain an active methyl function and which does not enter into the reaction producing formamide compounds. The pressure employed is in the range of 3000-8000 psi with a hydrogen partial pressure of at least 1500 psi, the preferred solvent being sulfolane.
摘要翻译：在氨或甲酰胺与CO和H 2的催化反应中，当在可溶于反应介质的铂族催化剂存在下进行反应时，在反应产物中获得了特别高的单 - 和二 - 甲基甲酰胺的产率，特别是钌或铑的化合物或络合物，其使用不含活性甲基官能团并且不进入生成甲酰胺化合物的反应的相对非挥发性极性溶剂。所用的压力在3000-8000psi的范围内，氢分压至少为1500psi，优选的溶剂是环丁砜。

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