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    • 6. 发明授权
    • Process for producing high brightness clays utilizing magnetic
beneficiation and calcining
    • 利用磁选和煅烧生产高亮度粘土的方法
    • US4419228A
    • 1983-12-06
    • US406074
    • 1982-08-06
    • Jerry A. CookGary L. Cobb
    • Jerry A. CookGary L. Cobb
    • B03B1/00B03B1/04B03B9/00B03C1/00B03D1/008B03D1/02
    • B03B9/00B03B1/04B03C1/00B03C1/002B03D1/008B03D1/02B03D2201/02B03D2203/04
    • A method is disclosed for separating titaniferous and ferruginous discolorants from a crude kaolin clay. A dispersed aqueous slurry of the clay is formed containing a deflocculant and a fatty acid collecting agent, and the slurry is conditioned to coat the discolorants with the collecting agent to thereby render the discolorants hydrophobic. A system of sub-micron sized magnetic ferrite seeding particles, the surfaces of which have been rendered hydrophobic, is thereupon added to the slurry. The seeded slurry is mixed to coalesce the hydrophobic-surfaced discolorants with the hydrophobic-surfaced seeding particles, and the slurry is then subjected to a froth flotation, which removes substantial quantities of the discolorants and seeding partices coalesced therewith, and also removes excess seeding particles and excess collecting agent. The floatation-beneficiated slurry is then subjected to a magnetic separation by passing the slurry through a porous ferromagnetic matrix positioned in a magnetic field, having an intensity of at least 0.5 kilogauss, to remove further quantities of the discolorants and seeding particles associated therewith, and to remove seeding particles unassociated with said discolorants. The product from said magnetic separation may then be calcined at a temperature of at least 1500.degree. F. to yield an exceptionally high brightness, low abrasion product.
    • 公开了一种用于从粗高岭土粘土中分离含钛和铁质脱色剂的方法。 形成含有抗絮凝剂和脂肪酸收集剂的粘土的分散的水性浆液,并且用收集剂对浆料进行调色以使变色剂变得疏水。 随后将其表面疏水化的亚微米尺寸的磁性铁氧体接种颗粒体系添加到浆料中。 将接种的浆料混合以使疏水表面的脱色剂与疏水表面的接种颗粒结合,然后对浆料进行泡沫浮选,其除去大量的与其结合的着色剂和播种颗粒,并且还除去多余的接种颗粒 和多余的收集剂。 然后通过使浆料通过位于磁场中的多孔铁磁矩阵(具有至少0.5千字节的强度)以去除进一步量的与其相关的着色剂和接种颗粒,然后使浮选精选的浆料进行磁分离,以及 去除与所述脱色剂无关的种子颗粒。 然后可以在至少1500°F的温度下对来自所述磁性分离的产物进行煅烧,以产生特别高的亮度,低磨损产物。
    • 7. 发明授权
    • Glass manufacture using dense, unsintered, granular alkaline earth metal
carbonates
    • 使用致密,未烧结,颗粒状碱土金属碳酸盐的玻璃制造
    • US4888308A
    • 1989-12-19
    • US233376
    • 1988-08-18
    • Charles Adams, Jr.Jerry A. Cook
    • Charles Adams, Jr.Jerry A. Cook
    • C01F11/18C03C1/02C03C6/04H01J9/24
    • C03C1/026C01F11/18C01F11/186H01J9/244C01P2004/50C01P2004/61C01P2004/62C01P2006/10
    • A glass manufacturing process using a granular, free-flowing form of alkaline earth metal carbonate, e.g., barium or strontium carbonate, is disclosed. The alkaline earth metal carbonate has a relatively high bulk density and is made without sintering, grinding, or briquetting. The carbonate is prepared from a fine particle size material by the following steps:(a) forming a suspension of the carbonate in water with enough deflocculating agent, e.g., sodium polyacrylate or sodium hexametaphosphate, to substantially completely deflocculate the carbonate;(b) drying the resulting suspension, at a temperature that is elevated, but without heating the carbonate to its sintering point, for example, by spray drying in a spray drier operating at an inlet temperature in the range of about 400.degree. to 600.degree. C., to obtain a granular material primarily passing 10 mesh and held on a 150 mesh screen (Tyler); and(c) heating the granular material to about 600.degree. to 700.degree. C., which causes it to shrink, thereby increasing its bulk density by at least about 5 percent, preferably at least 10 or 20 percent.The resultant alkaline earth metal carbonate is easier to dissolve in the glass melt than are prior art forms, and it is relatively dust-free and easy to handle. The process is especially useful for making television face plates.
    • 公开了使用颗粒状,自由流动形式的碱土金属碳酸盐例如钡或碳酸锶的玻璃制造方法。 碱土金属碳酸盐具有较高的堆积密度,并且不经烧结,研磨或压块制成。 通过以下步骤由细粒度材料制备碳酸盐:(a)用足够的抗絮凝剂(例如聚丙烯酸钠或六偏磷酸钠)形成碳酸盐在水中的悬浮液,以使碳酸盐基本上完全抗絮凝; (b)在升高的温度下干燥所得到的悬浮液,但不将碳酸盐加热到其烧结点,例如通过在入口温度为约400至600℃的喷雾干燥器中喷雾干燥。 C.获得主要通过10目并保持在150目筛(Tyler)上的粒状材料; 和(c)将颗粒材料加热至约600至700℃,这导致其收缩,从而将其堆积密度增加至少约5%,优选至少10%或20%。 所得到的碱土金属碳酸盐比现有技术形式更容易溶解在玻璃熔体中,并且它相对无尘且易于处理。 该过程对于制作电视面板特别有用。
    • 8. 发明授权
    • Method of forming dense, unsintered, granular alkaline earth metal
carbonates
    • 形成致密的,未烧结的颗粒状碱土金属碳酸盐的方法
    • US4888161A
    • 1989-12-19
    • US223386
    • 1988-07-25
    • Charles Adams, Jr.Jerry A. Cook
    • Charles Adams, Jr.Jerry A. Cook
    • C01F11/18C03C1/02
    • C01F11/186C03C1/026C01P2004/50C01P2004/62C01P2006/10C01P2006/11
    • A method of converting fine particle size alkaline earth metal carbonate, e.g., barium or strontium carbonate, into a free-flowing granular form with relatively high bulk density, without sintering, grinding, or briquetting, is disclosed. It involves the following steps:(a) forming a suspension of the carbonate in water with enough deflocculating agent, e.g., sodium polyacrylate or sodium hexametaphosphate, to substantially completely deflocculate the carbonate;(b) drying the resultant suspension at a temperature that is elevated, but without heating the carbonate to its sintering point, for example by spray drying in a spray drier operating at an inlet temperature in the range of about 400.degree. to 600.degree. C., to obtain a granular material primarily passing 10 mesh and held on a 150 mesh screen (Tyler); and(c) heating the granular material to about 600.degree. to 700.degree. C., which causes it to shrink, thereby increasing its bulk density by at least about 5%, preferably at least 10 or 20 percent.The product is especially useful as an additive for glass used to make television face plates.
    • 公开了一种将细颗粒大小的碱土金属碳酸盐例如钡或碳酸锶转化成具有较高堆积密度的自由流动的颗粒形式而不进行烧结,研磨或压块的方法。 它包括以下步骤:(a)用足够的抗絮凝剂(例如聚丙烯酸钠或六偏磷酸钠)形成碳酸盐在水中的悬浮液,以使碳酸盐基本上完全抗絮凝; (b)在升高的温度下干燥所得悬浮液,但不将碳酸盐加热至其烧结点,例如通过在约400℃至600℃的入口温度下操作的喷雾干燥器中喷雾干燥。 ,以获得主要通过10目并保持在150目筛(Tyler)上的颗粒材料; 和(c)将颗粒材料加热至约600℃至700℃,这导致其收缩,从而将其堆积密度增加至少约5%,优选至少10%或20%。 该产品特别适用于制作电视面板的玻璃添加剂。
    • 10. 发明授权
    • Magnetic beneficiation of clays utilizing magnetic seeding and flotation
    • 使用磁力播种和浮选的粘土的磁选
    • US4343694A
    • 1982-08-10
    • US180976
    • 1980-08-25
    • Jerry A. CookGary L. Cobb
    • Jerry A. CookGary L. Cobb
    • B03B1/00B03B1/04B03B9/00B03C1/00B03C1/01B03D1/008B03D1/02
    • B03B1/04B03B9/00B03C1/002B03C1/01B03D1/008B03D1/02B03D1/023B03D2201/02
    • A method is disclosed for separating titaniferous and ferruginous discolorants from a crude kaolin clay. A dispersed aqueous slurry of the clay is formed containing a deflocculant and a fatty acid collecting agent, and the slurry is conditioned to coat the discolorants with the collecting agent to thereby render the discolorants hydrophobic. A system of sub-micron sized magnetic ferrite seeding particles, the surfaces of which have been rendered hydrophobic, is thereupon added to the slurry. The seeded slurry is mixed to coalesce the hydrophobic-surfaced discolorants with the hydrophobic-surfaced seeding particles, and the slurry is then subjected to a froth flotation, which removes substantial quantities of the discolorants and seeding particles coalesced therewith, and also removes excess seeding particles and excess collecting agent. The flotation-beneficiated slurry is then subjected to a magnetic separation by passing the slurry through a porous ferromagnetic matrix positioned in a magnetic field, having an intensity of at least 0.5 kilogauss, to remove further quantities of the discolorants and seeding particles associated therewith, and to remove seeding particles unassociated with said discolorants.
    • 公开了一种用于从粗高岭土粘土中分离含钛和铁质脱色剂的方法。 形成含有抗絮凝剂和脂肪酸收集剂的粘土的分散的水性浆液,并且用收集剂对浆料进行调色以使变色剂变得疏水。 随后将其表面疏水化的亚微米尺寸的磁性铁氧体接种颗粒体系添加到浆料中。 将接种的浆料混合以将疏水表面的脱色剂与疏水表面的接种颗粒结合在一起,然后对该浆料进行泡沫浮选,其除去大量的与其结合的脱色剂和接种颗粒,并且还除去多余的接种颗粒 和多余的收集剂。 然后通过使浆料通过位于磁场中的多孔铁磁矩阵(具有至少0.5千字节的强度)以除去更多量的与其相关联的脱色剂和接种颗粒,然后将浮选精选的浆料进行磁分离,以及 去除与所述脱色剂无关的种子颗粒。