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    • 1. 发明授权
    • Preparation of cationic surfactants containing ester group in molecules
    • 在分子中制备含酯基的阳离子表面活性剂
    • US06414170B1
    • 2002-07-02
    • US09744349
    • 2001-01-23
    • Dong-Il KimJeong-Wook HaTae-Seong KimMoon-Jeong Rang
    • Dong-Il KimJeong-Wook HaTae-Seong KimMoon-Jeong Rang
    • C07C23100
    • C07C213/04C07C219/06
    • The present invention relates to a method for preparing a cationic surfactant in which physical chemical characteristics such as softness, antistatic properties, etc. as well as biodegradability are quite excellent due to having an ester group and a hydrophilic hydroxyl group in its molecules. A cationic surfactant of the present invention is prepared by reacting tertiary amine drivatives, fatty acid, and epihalohydrin, and prepared simply by reacting esterification and quaternary reactions in one step with a high yield. The above cationic surfactant is a high grade alkyl quaternary ammonium compound as represented in General Formula (1), wherein R1 is a C1-C4 alkyl group; R2 is a C7-C21 linear or branched alkyl or alkenyl group; A is OCOR3, NHCOR3 or OH; R3 is a C7-C21 linear or branched alkyl or alkenyl group; X is a halogen atom; and n is an integral number from 2 to 6.
    • 本发明涉及一种阳离子表面活性剂的制备方法,其中由于在其分子中具有酯基和亲水性羟基,其物理化学特性如柔软性,抗静电性等以及生物降解性都非常优异。 本发明的阳离子表面活性剂是通过叔胺驱动剂,脂肪酸和表卤代醇反应制备的,并且通过酯化反应和季铵反应在一步中以高产率进行反应来制备。 上述阳离子表面活性剂是通式(1)表示的高级烷基季铵化合物,其中R1是C1-C4烷基; R2是C7-C21直链或支链烷基或烯基; A为OCOR 3,NHCOR 3或OH; R3是C7-C21直链或支链烷基或链烯基; X是卤原子; n为2〜6的整数。