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1. 发明授权

US06677448B1 Method for reactivating a catalyst for cyclizing hydrolysis of an aminonitrile into a lactam and use of the regenerated catalyst for making lactams 失效
标题翻译：使催化剂再活化以使氨基腈水解成内酰胺的方法，以及使用再生催化剂制备内酰胺
公开(公告)号：US06677448B1
公开(公告)日：2004-01-13
申请号：US09744157
申请日：2001-06-11
申请人： Jean-Pierre Brunelle , Christophe Nedez
发明人： Jean-Pierre Brunelle , Christophe Nedez
IPC分类号： B01J3812
CPC分类号： C07D201/08 , B01J38/12 , Y02P20/584
摘要： The present invention relates to a process for regenerating a catalyst for the cyclizing hydrolysis of an aminonitrile for the manufacture of lactams. It relates more particularly to the regeneration of the solid catalysts used in the processes for producing lactams by the cyclizing hydrolysis of aminonitriles. This regeneration process consists in treating the spent catalyst or the catalyst at the end of the cycle at a temperature of between 300° C. and 600° C. with an oxidizing atmosphere.
摘要翻译：本发明涉及用于再生用于制备内酰胺的氨腈的环化水解催化剂的方法。更具体地涉及通过氨基腈的环化水解制备内酰胺的方法中所用的固体催化剂的再生。该再生方法包括在循环结束时在300℃至600℃的温度下用氧化气氛处理废催化剂或催化剂。

2. 发明授权

US06559333B1 Method for purifying aliphatic aminonitriles 失效
标题翻译：脂肪族氨基腈的纯化方法
公开(公告)号：US06559333B1
公开(公告)日：2003-05-06
申请号：US09673299
申请日：2001-01-25
申请人： Jean-Pierre Brunelle , Philippe Leconte , Philippe Marion
发明人： Jean-Pierre Brunelle , Philippe Leconte , Philippe Marion
IPC分类号： C07C25524
CPC分类号： C07C253/34 , C07C255/58
摘要： The present invention relates to a process for the purification of aliphatic aminonitriles and more particularly of 6-aminocapronitrile. It consists more specifically in subjecting 6-aminocapronitrile to a hydrogenation with molecular hydrogen in the presence of a catalyst comprising at least one metal chosen from palladium, platinum, ruthenium, osmium, iridium or rhodium and a promoter agent or a preconditioning in order to improve the selectivity of the hydrogenation.
摘要翻译：本发明涉及一种纯化脂族氨基腈，更特别是6-氨基己腈的方法。其更具体地涉及在含有至少一种选自钯的金属的催化剂的存在下，使6-氨基己腈与分子氢进行氢化反应，铂，钌，锇，铱或铑以及促进剂或预处理，以提高氢化的选择性。

3. 发明授权

US06479658B1 Method for cyclizing hydrolysis of an aminonitrile compound into lactam 有权
标题翻译：使氨腈化合物水解成内酰胺的方法
公开(公告)号：US06479658B1
公开(公告)日：2002-11-12
申请号：US09744210
申请日：2001-06-04
申请人： Jean-Pierre Brunelle , Aline Seigneurin , Lionel Sever
发明人： Jean-Pierre Brunelle , Aline Seigneurin , Lionel Sever
IPC分类号： C07D22308
CPC分类号： C07D201/08
摘要： The invention relates to a process for the cyclizing hydrolysis of an aminonitrile compound into a lactam in the presence of a catalyst. The invention relates more particularly to a process for the cyclizing hydrolysis of an aminonitrile compound in the presence of a macroporous particulate catalyst obtained by deposition/impregnation of an oxygenated compound onto a macroporous support such as alumina. The invention applies in particular to the preparation of &egr;-caprolactam by cyclizing hydrolysis of aminocapronitrile.
摘要翻译：本发明涉及一种在催化剂存在下使氨基腈化合物环化成内酰胺的方法。本发明涉及一种在大孔颗粒催化剂存在下环化氨基腈化合物的水解方法，该方法由将氧合化合物沉积/浸渍到大孔载体如氧化铝上。本发明特别适用于通过环化氨基己腈的水解制备ε-己内酰胺。

4. 发明授权

US4492770A Catalyst and use thereof in treating internal combustion engine exhaust gases 失效
标题翻译：催化剂及其在处理内燃机废气中的用途
公开(公告)号：US4492770A
公开(公告)日：1985-01-08
申请号：US330007
申请日：1981-12-11
申请人： Gilbert Blanchard , Jean-Pierre Brunelle , Michel Prigent
发明人： Gilbert Blanchard , Jean-Pierre Brunelle , Michel Prigent
IPC分类号： B01D53/86 , B01D53/94 , B01J23/89 , B01J37/02 , B01J23/10 , B01J23/42 , B01J23/44 , B01J23/72
CPC分类号： B01D53/945 , B01J23/8926 , B01J23/894 , B01J37/024 , Y02T10/22
摘要： Provided is an improved catalyst and a process employing same in the treatment of exhaust gases generated by internal combustion engines. The catalyst comprises a support and an active phase comprising copper, cerium and/or iron, at least one metal selected from the group consisting of platinum and palladium, and at least one metal selected from the group consisting of iridium and rhodium. The catalyst is particularly active in the removal of carbon monoxide, unburned hydrocarbons and nitrogen oxides generally present in the exhaust gases of an internal combustion engine.
摘要翻译：提供了一种改进的催化剂及其在处理由内燃机产生的废气中使用的催化剂和方法。催化剂包括载体和包含铜，铈和/或铁的活性相，选自铂和钯的至少一种金属和选自铱和铑的至少一种金属。催化剂在通常存在于内燃机的排气中的一氧化碳，未燃烧的烃和氮氧化物的除去方面特别有活性。

5. 发明授权

US4426319A Catalyst for treatment of exhaust gases from internal combustion engines 失效
标题翻译：用于处理内燃机废气的催化剂
公开(公告)号：US4426319A
公开(公告)日：1984-01-17
申请号：US355184
申请日：1982-03-05
申请人： Gilbert Blanchard , Jean-Pierre Brunelle , Michel Prigent
发明人： Gilbert Blanchard , Jean-Pierre Brunelle , Michel Prigent
IPC分类号： B01D53/94 , B01J23/00 , B01J23/86 , B01J23/89 , B01J37/02 , B01J23/10 , B01J23/62
CPC分类号： B01D53/945 , B01J23/8906 , B01J23/894 , B01J37/024 , Y02T10/22
摘要： The exhaust gases from internal combustion engines are catalytically oxidized/reduced, to remove CO, unburned hydrocarbons and NO.sub.x therefrom, utilizing an improved stable and long-lived catalyst which comprises (1) a support substrate, e.g., a monolithic or particulate support, and (2) an active phase deposited thereon, said active phase (2) comprising (i) cerium, (ii) iron, (iii) at least one of the metals gallium and/or yttrium, (iv) at least one of the metals platinum and/or palladium, and (v) at least one of the metals iridium and/or rhodium.
摘要翻译：来自内燃机的废气被催化氧化/还原，以利用改进的稳定且长寿命的催化剂除去CO，未燃碳氢化合物和NOx，其包括（1）支撑衬底，例如整体或颗粒状载体，以及（2）沉积在其上的活性相，所述活性相（2）包含（i）铈，（ii）铁，（iii）金属镓和/或钇中的至少一种，（iv）至少一种金属铂和/或钯，和（v）金属铱和/或铑中的至少一种。

6. 发明授权

US4378307A Pollution control catalyst for internal combustion engine exhaust system/catalytic converter 失效
标题翻译：内燃机排气系统/催化转化器污染控制催化剂
公开(公告)号：US4378307A
公开(公告)日：1983-03-29
申请号：US187761
申请日：1980-09-16
申请人： Jean-Pierre Brunelle , Philippe Courty , Michel Prigent , Bernard Raynal
发明人： Jean-Pierre Brunelle , Philippe Courty , Michel Prigent , Bernard Raynal
IPC分类号： B01D53/86 , B01D53/94 , B01J23/89 , B01J23/10 , B01J23/42 , B01J23/44 , B01J23/74
CPC分类号： B01D53/945 , B01J23/894 , Y02T10/22
摘要： A pollution control catalyst for a catalytic converter comprising the exhaust system of an internal combustion engine, said catalyst including a refractory oxide support, and an activated phase therefor comprised of 0.3 to 7% by weight cerium based upon the weight of said support, 0.1 to 3.5% by weight iron, also based upon the weight of said support, at least one platinum or palladium metal, and at least one iridium or rhodium metal.
摘要翻译：一种用于催化转化器的污染控制催化剂，其包括内燃机的排气系统，所述催化剂包括难熔氧化物载体，以及其活性相，其包含基于所述载体重量的0.3至7重量％的铈，0.1至 3.5重量％的铁，也基于所述载体的重量，至少一种铂或钯金属和至少一种铱或铑金属。

7. 发明授权

US4255359A Non-polluting oxyhydrochlorination process 失效
标题翻译：无污染的氢氯化过程
公开(公告)号：US4255359A
公开(公告)日：1981-03-10
申请号：US28380
申请日：1979-04-09
申请人： Jean-Pierre Brunelle
发明人： Jean-Pierre Brunelle
IPC分类号： B01J23/00 , B01J23/40 , C01B7/01 , C07C17/00 , C07C17/15 , C07C17/156 , C07C17/38 , C07C19/045 , C07C67/00 , C07C21/00
CPC分类号： C07C17/38 , B01J23/40 , C01B7/01 , C07C17/15 , C07C17/156
摘要： A non-polluting oxyhydrochlorination process is provided in which the residual gaseous effluents are purified by catalytic oxidation in the presence of a catalyst comprising platinum and/or iridium deposited on a special alumina support of eta crystallographic structure and then washing the effluent before being discharged into the atmosphere.The process of the invention is particularly applicable to a residual effluent containing essentially carbon monoxide, carbon dioxide, ethylene, 1,2-dichloroethane, and at least one chlorinated hydrocarbon from among the group consisting of chloroform, carbon tetrachloride, ethyl chloride, 1,1-dichloroethane, 1,1,1- and 1,1,]-trichloroethanes, 1,1,2,2- and 1,1,1,2- tetrachloroethanes, vinyl chloride, 1,1- and 1,2-dichloroethylenes, trichloroethylene, perchloroethylene and chloral.
摘要翻译：提供了一种无污染的含氧氯化方法，其中残留的气态流出物在催化剂的存在下通过催化剂进行纯化，所述催化剂包含沉积在特殊氧化铝载体上的铂和/或铱结构的催化剂，然后在排出之前洗涤流出物气氛。本发明的方法特别适用于基本上含有一氧化碳，二氧化碳，乙烯，1,2-二氯乙烷和至少一种氯仿，氯仿，四氯化碳，氯乙烷，1,1-二氯乙烷， 1,1-二氯乙烷，1,1,1- 1,1,1-三氯乙烷，1,1,2,2-和1,1,1,2-四氯乙烷，氯乙烯，1,1-和1,2-二氯乙烷，二氯乙烯，三氯乙烯，全氯乙烯和氯醛。

8. 发明授权

US4138443A Hydrodealkylation of alkylaromatic hydrocarbons 失效
标题翻译：烷基芳烃的加氢脱烷基化
公开(公告)号：US4138443A
公开(公告)日：1979-02-06
申请号：US808312
申请日：1977-06-20
申请人： Jean-Pierre Brunelle
发明人： Jean-Pierre Brunelle
IPC分类号： B01J23/00 , B01J23/89 , B01J35/10 , C07B61/00 , C07C1/00 , C07C4/18 , C07C15/00 , C07C67/00 , C07C3/58
CPC分类号： B01J35/10 , B01J23/89 , C07C4/18 , B01J35/1019 , B01J35/1042 , C07C2521/04 , C07C2523/06 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755
摘要： A process for hydrodealkylating alkyl-substituted aromatic hydrocarbons, e.g., toluene, by reaction with hydrogen in the absence of water vapor under relatively mild reaction conditions, and a catalyst therefor are disclosed. The process is effected at a temperature of from about 450.degree. and 650.degree. C., preferably from about 520.degree. to 620.degree. C., and pressures of from about 1 to about 30, preferably from about 5 to about 20 bar, and a liquid hourly space velocity of from about 1 to about 10, preferably from about 3 to about 8, in the presence of a catalyst which comprises a metal combination of rhodium and at least one metal selected from the group consisting of copper, nickel, cobalt, iron, and zinc, and a support comprising activated alumina having a specific surface of between about 100 and about 350 m.sup.2 /g and a total pore volume of from about 0.5 to about 0.8 cm.sup.3 /g.The activated alumina support may comprise agglomerates of active alumina obtainable by dehydrating alumina hydrate in a stream of hot gas. The agglomerates also may be previously autoclaved in an acid or neutral aqueous medium.
摘要翻译：公开了通过在相对温和的反应条件下在不存在水蒸汽的情况下与氢反应而将烷基取代的芳族烃例如甲苯加氢脱烷基化的方法及其催化剂。该方法在约450℃和650℃，优选约520℃至620℃的温度和约1至约30℃，优选约5至约20巴的温度下进行，在催化剂的存在下，液体时空速为约1至约10，优选约3至约8，所述催化剂包含铑和至少一种选自铜，镍，钴，铁和锌，以及包含活性氧化铝的载体，其具有约100至约350m 2 / g的比表面积和约0.5至约0.8cm 3 / g的总孔体积。

9. 发明授权

US4857296A CeO catalytic desulfurization of industrial gases 失效
标题翻译： CeO催化脱硫工业气体
公开(公告)号：US4857296A
公开(公告)日：1989-08-15
申请号：US136989
申请日：1987-12-23
申请人： Jean-Pierre Brunelle , Patrice Nortier , Eric Quemere
发明人： Jean-Pierre Brunelle , Patrice Nortier , Eric Quemere
IPC分类号： B01D53/86 , B01J21/16 , B01J23/10 , B01J27/053 , C01B17/04 , C01B17/16
CPC分类号： C01B17/165 , B01D53/8603 , B01J23/10 , C01B17/0434 , C01B17/0456
摘要： The desulfurization of industrial gases by the catalytic conversion of contaminating sulfur values therein, comprising, e.g., either Claus process or hydrolysis of organosulfur compounds, is carried out in the presence of an effective amount of a cerium oxide-based catalyst.
摘要翻译：通过催化转化其中的污染硫值，包括例如克劳斯法或有机硫化合物的水解，工业气体的脱硫在有效量的氧化铈类催化剂的存在下进行。

10. 发明授权

US4581343A Process for the preparation of a pollution control catalyst for internal combustion engine exhaust system/catalytic converter 失效
标题翻译：内燃机排气系统/催化转化器污染控制催化剂的制备工艺
公开(公告)号：US4581343A
公开(公告)日：1986-04-08
申请号：US610498
申请日：1984-05-15
申请人： Gilbert Blanchard , Jean-Pierre Brunelle , Richard Doziere , Emmanuel Goldenberg , Michel Prigent
发明人： Gilbert Blanchard , Jean-Pierre Brunelle , Richard Doziere , Emmanuel Goldenberg , Michel Prigent
IPC分类号： B01D53/86 , B01D53/94 , B01J23/56 , B01J23/63 , B01J37/16 , B01J37/18 , B01J23/10 , B01J23/62 , B01J23/64 , B01J23/70
CPC分类号： B01D53/945 , B01J23/63 , B01J37/16 , Y02T10/22
摘要： A pollution control catalyst for a catalytic converter in the exhaust system of an internal combustion engine, which catalyst comprises a support impregnated with (i) at least one platinum group precious metal, and with (ii) cerium base metal, or a combination of cerium and at least one other base metal, is facilely prepared by (1) impregnating a catalyst support with precursor compounds of said cerium base metal, or of said cerium base metal and of at least one other base metal, (2) activating said impregnated support, under a neutral or oxidizing atmosphere, at a temperature ranging from 120.degree. to 800.degree. C., (3) impregnating said catalyst support with precursor compounds of said at least one platinum group precious metal, together with a delayed-action organic reducing agent, inactive under cold conditions, which effects reduction of said platinum group precious metal precursor compounds, but not of any cerium or other base metal precursor compounds, under the conditions of the step (4) below, and (4) activating said impregnated catalyst, also under a neutral or oxidizing atmosphere, at a temperature ranging from 300.degree. to 800.degree. C.
摘要翻译：一种用于内燃机排气系统中的催化转化器的污染控制催化剂，该催化剂包括浸渍有（i）至少一种铂族贵金属和（ii）铈贱金属或铈组合的载体和至少一种其它贱金属，通过（1）用催化剂载体浸渍所述铈贱金属或所述铈贱金属和至少一种其它贱金属的前体化合物来容易地制备，（2）活化所述浸渍的载体在中性或氧化性气氛下，在120℃至800℃的温度下，（3）用所述至少一种铂族贵金属的前体化合物浸渍所述催化剂载体以及延迟作用的有机还原剂在寒冷条件下无活性，其在锡的条件下还原所述铂族贵金属前体化合物而不是任何铈或其它贱金属前体化合物 p（4），以及（4）在中性或氧化性气氛下，在300〜800℃的温度下活化所述浸渍的催化剂。

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