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1. 发明授权

US08080199B2 Interaction of microwaves with carbon nanotubes to facilitate modification 有权
标题翻译：微波与碳纳米管的相互作用以促进改性
公开(公告)号：US08080199B2
公开(公告)日：2011-12-20
申请号：US11840422
申请日：2007-08-17
申请人： James M. Tour , Christopher A. Dyke , Jason J. Stephenson , Boris I. Yakobson
发明人： James M. Tour , Christopher A. Dyke , Jason J. Stephenson , Boris I. Yakobson
IPC分类号： B29C35/08
CPC分类号： C04B35/453 , B82Y30/00 , C04B35/117 , C04B35/14 , C04B35/46 , C04B35/50 , C04B35/62645 , C04B35/803 , C04B35/83 , C04B2235/3229 , C04B2235/3284 , C04B2235/5288
摘要： The present invention is directed toward methods of crosslinking carbon nanotubes to each other using microwave radiation, articles of manufacture produced by such methods, compositions produced by such methods, and applications for such compositions and articles of manufacture. The present invention is also directed toward methods of radiatively modifying composites and/or blends comprising carbon nanotubes with microwaves, and to the compositions produced by such methods. In some embodiments, the modification comprises a crosslinking process, wherein the carbon nanotubes serve as a conduit for thermally and photolytically crosslinking the host matrix with microwave radiation.
摘要翻译：本发明涉及使用微波辐射将碳纳米管彼此交联的方法，通过这些方法生产的制品，通过这些方法制备的组合物，以及这些组合物和制品的应用。本发明还涉及将包含碳纳米管与微波的复合材料和/或共混物辐射改性的方法以及通过这些方法制备的组合物的方法。在一些实施方案中，修饰包括交联方法，其中碳纳米管用作用微波辐射热和光解交联宿主基质的导管。

2. 发明授权

US07704323B2 Metal-free silicon-molecule-nanotube testbed and memory device 失效
标题翻译：无金属硅分子纳米管测试和记忆装置
公开(公告)号：US07704323B2
公开(公告)日：2010-04-27
申请号：US11337456
申请日：2006-01-23
申请人： James M. Tour , Jianli He , Bo Chen , Austen K. Flatt , Jason J. Stephenson , Condell D. Doyle
发明人： James M. Tour , Jianli He , Bo Chen , Austen K. Flatt , Jason J. Stephenson , Condell D. Doyle
IPC分类号： C30B21/02
CPC分类号： G11C13/02 , B82Y10/00 , B82Y30/00 , G11C13/0014 , G11C13/025 , H01L27/283 , H01L51/0048 , H01L51/005 , H01L51/0052 , H01L51/0595
摘要： Work from several laboratories has shown that metal nanofilaments cause problems in some molecular electronics testbeds. A new testbed for exploring the electrical properties of single molecules has been developed to eliminate the possibility of metal nanofilament formation and to ensure that molecular effects are measured. This metal-free system uses single-crystal silicon and single-walled carbon nanotubes as electrodes for the molecular monolayer. A direct Si-arylcarbon grafting method is used. Use of this structure with π-conjugated organic molecules results in a hysteresis loop with current-voltage measurements that are useful for an electronic memory device. The memory is non-volatile for more than 3 days, non-destructive for more than 1,000 reading operations and capable of more than 1,000 write-erase cycles before device breakdown. Devices without π-conjugated molecules (Si—H surface only) or with long-chain alkyl-bearing molecules produced no hysteresis, indicating that the observed memory effect is molecularly relevant.
摘要翻译：几个实验室的工作表明，金属纳米丝在一些分子电子测试台中引起问题。已经开发了用于探索单分子的电性质的新试验台，以消除金属纳米丝形成的可能性并确保测量分子效应。该无金属系统使用单晶硅和单壁碳纳米管作为分子单层的电极。使用直接的Si-芳基碳接枝方法。这种结构与共轭有机分子的结合产生了对电子存储器件有用的电流 - 电压测量的滞后回路。存储器非易失性超过3天，对于超过1,000次读取操作是非破坏性的，并且在器件故障之前能够进行超过1,000次写擦除周期。不具有共轭分子（仅含Si-H表面）或具有长链烷基的分子的器件不产生滞后，表明观察到的记忆效应具有分子相关性。

3. 发明申请

US20080169061A1 INTERACTION OF MICROWAVES WITH CARBON NANOTUBES TO FACILITATE MODIFICATION 有权
标题翻译：微波与碳纳米管的相互作用进行改性
公开(公告)号：US20080169061A1
公开(公告)日：2008-07-17
申请号：US11840422
申请日：2007-08-17
申请人： James M. Tour , Christopher A. Dyke , Jason J. Stephenson , Boris I. Yakobson
发明人： James M. Tour , Christopher A. Dyke , Jason J. Stephenson , Boris I. Yakobson
IPC分类号： B01J19/12 , B32B37/00 , H05B6/64
CPC分类号： C04B35/453 , B82Y30/00 , C04B35/117 , C04B35/14 , C04B35/46 , C04B35/50 , C04B35/62645 , C04B35/803 , C04B35/83 , C04B2235/3229 , C04B2235/3284 , C04B2235/5288
摘要： The present invention is directed toward methods of crosslinking carbon nanotubes to each other using microwave radiation, articles of manufacture produced by such methods, compositions produced by such methods, and applications for such compositions and articles of manufacture. The present invention is also directed toward methods of radiatively modifying composites and/or blends comprising carbon nanotubes with microwaves, and to the compositions produced by such methods. In some embodiments, the modification comprises a crosslinking process, wherein the carbon nanotubes serve as a conduit for thermally and photolytically crosslinking the host matrix with microwave radiation.
摘要翻译：本发明涉及使用微波辐射将碳纳米管彼此交联的方法，通过这些方法生产的制品，通过这些方法制备的组合物，以及这些组合物和制品的应用。本发明还涉及将包含碳纳米管与微波的复合材料和/或共混物辐射改性的方法以及通过这些方法制备的组合物的方法。在一些实施方案中，修饰包括交联方法，其中碳纳米管用作用微波辐射热和光解交联宿主基质的导管。

4. 发明授权

US07625988B2 Flame retardant polymers having pendant groups related to bisphenol-C and monomers for synthesis thereof 失效
标题翻译：具有与双酚C相关的侧基的阻燃聚合物及其合成用单体
公开(公告)号：US07625988B2
公开(公告)日：2009-12-01
申请号：US10560291
申请日：2004-06-18
申请人： James M. Tour , Joshua L. Jurs , Jason J. Stephenson
发明人： James M. Tour , Joshua L. Jurs , Jason J. Stephenson
IPC分类号： C08F12/00 , C08F18/00 , C08F18/20
CPC分类号： C09K21/14 , C07C29/40 , C07C37/001 , C07C37/16 , C07C39/367 , C07C39/373 , C07C67/14 , C07C69/653 , C07C233/15 , C07C233/27 , C07C271/28 , C08F12/34 , C08F36/20 , C08G59/30 , C07C33/46
摘要： The present invention is directed to novel flame retardant monomers and polymers, wherein the flame retardant properties of the polymers are provided by functionality in pendant groups attached to a polymer backbone (as opposed to the polymer backbone itself possessing flame retardant properties. The present invention is also directed to methods of making such polymers and monomers, and articles of manufacture incorporating such monomers and polymers.
摘要翻译：本发明涉及新型阻燃剂单体和聚合物，其中聚合物的阻燃性质由连接于聚合物骨架的侧基中的官能团提供（与具有阻燃性能的聚合物主链本身相反，本发明是也涉及制备这种聚合物和单体的方法，以及掺入这种单体和聚合物的制品。

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