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    • 1. 发明授权
    • Hydrogen stabilizers for vinyl ether-based coating systems
    • 乙烯基醚类涂料体系用氢稳定剂
    • US5491178A
    • 1996-02-13
    • US293613
    • 1994-08-19
    • Raymond J. SwedoGeorge D. GreenJames R. Snyder
    • Raymond J. SwedoGeorge D. GreenJames R. Snyder
    • C08F2/50C08F290/14C09D4/06C08K5/134C08K5/098C08K5/36C08L67/00
    • C08F290/141C09D4/06
    • This invention relates to vinyl ether-based coatings for which properties such as color stability, thermal stability, mechanical stability, hydrolytic stability, and resistance to embrittlement may be maintained and properties hydrogen generation and blocking are minimized. The coatings comprise a vinyl ether-containing composition polymerizable by actinic, gamma ray, or electron beam radiation comprising: (a) an oligomer or a mixture of oligomers which are monofunctional, multifunctional, or a mixture of both monofunctional and multifunctional and which have a reactive functionality chosen from the group consisting of epoxy, acrylate, vinyl ether, maleate, or mixtures thereof; (b) monomers which are monofunctional, multifunctional, or a mixture of both monofunctional and multifunctional monomers and which have a reactive functionality chosen from the group consisting of epoxy, acrylate, vinyl ether, maleate, or mixtures thereof, wherein at least one of (a) or (b) must contain a vinyl ether functionality; (c) a photoinitiator, optionally including a sensitizer, chosen from the group consisting of a cationic photoinitiator and a radical photoinitiator; and (d) a thermal oxidation stabilizer. The composition also comprises additives including as hydrogen stabilizers; mixtures of hindered phenols, organic sulfides or disulfides, and transition metal salts of organic compounds.
    • 本发明涉及可以保持诸如颜色稳定性,热稳定性,机械稳定性,水解稳定性和耐脆性等性能的乙烯基醚类涂料,并且氢气产生和阻塞性能最小化。 涂层包含可通过光化学,γ射线或电子束辐射聚合的含乙烯基醚的组合物,其包含:(a)低聚物或低聚物的混合物,其是单官能的,多官能的或单官能的和多功能的混合物,并且具有 选自环氧基,丙烯酸酯,乙烯基醚,马来酸酯或其混合物的反应性官能团; (b)单官能单体,多官能单体或单官能单体和多官能单体的混合物,其具有选自环氧基,丙烯酸酯,乙烯基醚,马来酸酯或其混合物的反应性官能团的单体,其中至少一种( a)或(b)必须含有乙烯基醚官能团; (c)任选地包含敏化剂的光引发剂,其选自阳离子光引发剂和自由基光引发剂; 和(d)热氧化稳定剂。 该组合物还包括作为氢稳定剂的添加剂; 受阻酚,有机硫化物或二硫化物的混合物,以及有机化合物的过渡金属盐。
    • 4. 发明授权
    • Stabilizers for vinyl ether-based coating systems
    • 乙烯基醚基涂料体系稳定剂
    • US5514727A
    • 1996-05-07
    • US274671
    • 1994-07-13
    • George D. GreenJames R. SnyderRaymond J. Swedo
    • George D. GreenJames R. SnyderRaymond J. Swedo
    • C08F2/50C08F290/14C09D4/06C08K5/13C08K5/375C08L71/00
    • C08F290/141C09D4/06Y10S522/901
    • This invention relates to vinyl ether-based coatings for which properties such as color stability, thermal stability, mechanical stability, hydrolyric stability, and resistance to embrittlement may be maintained and properties hydrogen generation and blocking are minimized. The invention also relates to stabilizers which control these properties in the coatings. The coatings comprise a vinyl ether-containing composition polymerizable by actinic, gamma ray, or electron beam radiation comprising: (a) an oligomer or a mixture of oligomers which are monofunctional, multifunctional, or a mixture of both monofunctional and multifunctional and which have a reactive functionality chosen from the group consisting of epoxy, acrylate, vinyl ether, maleate, or mixtures thereof, (b) monomers which are monofunctional, multifunctional, or a mixture of both monofunctional and multifunctional monomers and which have a reactive functionality chosen from the group consisting of epoxy, acrylate, vinyl ether, maleate, or mixtures thereof, wherein at least one of (a) or (b) must contain a vinyl ether functionality; (c) a photoinitiator with an optional sensitizer, said photoinitiator which is chosen from the group consisting of a cationic photoinitiator and a radical photoinitiator; and (d) a thermal oxidation stabilizer. The composition also comprises additives comprising at least one additive chosen from the group consisting of: (e) a hydrogen stabilizer; (f) a light screen; (g) a color stabilizer; (h) a blocking stabilizer or slip agent; and (j) a coupling agent.
    • 本发明涉及乙烯基醚类涂料,其特性如颜色稳定性,热稳定性,机械稳定性,水解稳定性,耐脆性等特性可使氢气产生和阻塞性能最小化。 本发明还涉及在涂层中控制这些性质的稳定剂。 涂层包含可通过光化学,γ射线或电子束辐射聚合的含乙烯基醚的组合物,其包含:(a)低聚物或低聚物的混合物,其是单官能的,多官能的或单官能的和多功能的混合物,并且具有 选自环氧基,丙烯酸酯,乙烯基醚,马来酸酯或其混合物的反应性官能团,(b)单官能,多官能或单官能和多官能单体的混合物,并且具有选自下组的反应性官能团 由环氧,丙烯酸酯,乙烯基醚,马来酸酯或其混合物组成,其中(a)或(b)中的至少一个必须含有乙烯基醚官能团; (c)具有任选的敏化剂的光引发剂,所述光引发剂选自阳离子光引发剂和自由基光引发剂; 和(d)热氧化稳定剂。 所述组合物还包含添加剂,所述添加剂包含至少一种选自以下的添加剂:(e)氢稳定剂; (f)光屏; (g)颜色稳定剂; (h)阻塞稳定剂或滑爽剂; 和(j)偶联剂。
    • 7. 发明授权
    • Adhesion promoters for vinyl ether-based coating systems
    • 乙烯基醚基涂料体系的粘合促进剂
    • US5539014A
    • 1996-07-23
    • US293869
    • 1994-08-19
    • Raymond J. SwedoGeorge D. GreenJames R. Snyder
    • Raymond J. SwedoGeorge D. GreenJames R. Snyder
    • C08F2/50C08F290/14C09D4/06C09J135/08C08F216/12C08F230/08
    • C08F290/141C09D4/06
    • This invention relates to vinyl ether-based coatings for which properties such as color stability, thermal stability, mechanical stability, hydrolytic stability, and resistance to embrittlement may be maintained and properties hydrogen generation and blocking are minimized. The coatings comprise a vinyl ether-containing composition polymerizable by actinic, gamma ray, or electron beam radiation comprising: (a) an oligomer or a mixture of oligomers which are monofunctional, multifunctional, or a mixture of both monofunctional and multifunctional and which have a reactive functionality chosen from the group consisting of epoxy, acrylate, vinyl ether, maleate, or mixtures thereof; (b) monomers which are monofunctional, multifunctional, or a mixture of both monofunctional and multifunctional monomers and which have a reactive functionality chosen from the group consisting of epoxy, acrylate, vinyl ether, maleate, or mixtures thereof, wherein at least one of (a) or (b) must contain a vinyl ether functionality; (c) a photoinitiator, optionally including a sensitizer, chosen from the group consisting of a cationic photoinitiator and a radical photoinitiator; and (d) a thermal oxidation stabilizer. Adhesion to a substrate, particularly glass, is achieved by coupling agents including vinyl ether urethane siloxane compounds.
    • 本发明涉及可以保持诸如颜色稳定性,热稳定性,机械稳定性,水解稳定性和耐脆性等性能的乙烯基醚类涂料,并且氢气产生和阻塞性能最小化。 涂层包含可通过光化学,γ射线或电子束辐射聚合的含乙烯基醚的组合物,其包含:(a)低聚物或低聚物的混合物,其是单官能的,多官能的或单官能的和多功能的混合物,并且具有 选自环氧基,丙烯酸酯,乙烯基醚,马来酸酯或其混合物的反应性官能团; (b)单官能单体,多官能单体或单官能单体和多官能单体的混合物,其具有选自环氧基,丙烯酸酯,乙烯基醚,马来酸酯或其混合物的反应性官能团的单体,其中至少一种( a)或(b)必须含有乙烯基醚官能团; (c)任选地包含敏化剂的光引发剂,其选自阳离子光引发剂和自由基光引发剂; 和(d)热氧化稳定剂。 通过包括乙烯基醚氨基甲酸酯硅氧烷化合物在内的偶联剂来实现对基材,特别是玻璃的粘附。
    • 10. 发明授权
    • Coextruded multi-layer thermoplastic sheet material having one layer
with high modulus for repositioning tape-tab fasteners thereon,
absorbant articles and methods
    • 共挤出多层热塑性片材,具有高模量的层,用于在其上重新定位带状接头紧固件,吸收性物品和方法
    • US5147346A
    • 1992-09-15
    • US393646
    • 1989-08-14
    • Leopoldo V. CancioJames R. SnyderPai-Chuan Wu
    • Leopoldo V. CancioJames R. SnyderPai-Chuan Wu
    • A61F13/58B32B27/08
    • A61F13/58B32B27/08
    • Novel thermoplastic sheet materials, absorbant articles formed therewith and method of producing such sheet materials are disclosed. The novel thermoplastic sheet materials are soft and pliable having a high modulus, high impact resistance and tear strengths and enhanced tape adhesion. The novel thermoplastic sheet materials are formed directly during a coextrusion process which may thereafter include an embossing step. The novel, coextruded thermoplastic sheet materials comprise a plurality of coextruded layers having high modulus outer layers for permitting pressure-sensitive adhesive tape-tab fasteners to be positioned and repositioned thereon without losing substantial tape adhesion therebetween or tearing the sheet materials following their original attachments. The outer layers are formed with a first thermoplastic polymer, such as a polypropylene, having an effective modulus to resist tearing, yielding and deformation upon detaching tape-tab fasteners therefrom, and further having an effective bonding affinity to maintain tape adhesion after initial attachment. The other layer of the thermoplastic sheet materials is an inner layer(s) being formed with a second thermoplastic polymer, such as a polyethylene, to impart softness or low stiffness and effective impact resistance and tear strengths to the sheet materials. The novel thermoplastic sheet materials of the instant invention are suitable for use with articles which, for example, absorb body fluids, and are especially suitable for use as backsheet films in disposable diapers.
    • 公开了新型热塑性片材,与其形成的吸收性物品及其制造方法。 新型热塑性片材材料柔软且柔韧,具有高模量,高抗冲击性和撕裂强度,并增强胶带粘附力。 新型热塑性片材材料在共挤出工艺期间直接形成,其后可包括压花步骤。 新型共挤出的热塑性片材材料包括多个具有高模量外层的共挤出层,用于允许将压敏粘合带状突片紧固件定位并重新定位在其上,而不会在其之间丧失实质的带粘合力或者撕裂其原始附件之后的片材。 外层由第一热塑性聚合物(例如聚丙烯)形成,其具有有效模量,以抵抗撕裂,产生和变形,从而剥离带状突片紧固件,并且还具有有效的粘合亲合力以在初始附着后维持带粘合。 热塑性片材的另一层是形成有第二热塑性聚合物如聚乙烯的内层,以赋予片材柔软度或低刚度以及有效的耐冲击性和撕裂强度。 本发明的新型热塑性片材材料适用于例如吸收体液的物品,特别适用于一次性尿布中的底片膜。