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    • 1. 发明授权
    • Electrochemical cells
    • 电化学细胞
    • US5230968A
    • 1993-07-27
    • US699810
    • 1991-05-13
    • Roger J. BonesDavid TeagleMarion R. RanceJohan CoetzerJames H. Duncan
    • Roger J. BonesDavid TeagleMarion R. RanceJohan CoetzerJames H. Duncan
    • H01M4/64H01M2/18H01M10/39
    • H01M2/18H01M10/39
    • A laterally compressed envelope of solid electrolyte material is provided for use as an electrode holder in an electrochemical cell. It has two opposed major faces sealed together along at least part of the periphery of the envelope, each major face being provided by a sheet of said solid electrolyte material. Each sheet is provided on its inner surface with a plurality of ribs or corrugations extending alongside one another, each rib or corrugation of each said sheet crossing over a plurality of the ribs or corrugations of the other said sheet. The envelope has an internal volume, between the sheets, defined at least in part by grooves or valleys between the ribs or crests of the corrugations. Each part of said internal volume is in communication with each other part of said internal volume. The invention also provides a method of making the envelope, and an electrochemical cell in which the envelope forms an electrode holder.
    • 提供固体电解质材料的侧向压缩外壳,用作电化学电池中的电极保持器。 它具有两个相对的主面,沿着外壳的至少一部分周边密封在一起,每个主面由一片固体电解质材料提供。 每个片材在其内表面上设置有多个沿着彼此延伸的肋或波纹,每个所述片的每个肋或波纹跨越另一个所述片的多个肋或波纹。 该封套在片之间具有至少部分地由波纹的肋或波纹之间的凹槽或谷部限定的片之间的内部容积。 所述内部容积的每个部分与所述内部容积的彼此部分连通。 本发明还提供了一种制造该封套的方法,以及一种电化学电池,其中该封套形成电极支架。
    • 3. 发明授权
    • Method of making beta
    • 制造β“ - 氧化铝的方法
    • US4732741A
    • 1988-03-22
    • US866057
    • 1986-05-21
    • James H. DuncanPeter BarrowArnold Van ZylAngus I. Kingon
    • James H. DuncanPeter BarrowArnold Van ZylAngus I. Kingon
    • C01F7/02C04B35/113C01F7/06
    • C01F7/028C04B35/113C01P2002/32C01P2002/72C01P2004/51C01P2006/40
    • A method of making beta"-alumina comprises dispersing in a precursor of aluminum oxide a member of the group comprising sodium oxide and its precursors, and dispersing in the precursor of aluminum oxide a spinel stabilizer which is a member of the group comprising spinel-forming oxides and the precursors thereof, to form a mixture. The mixture is then heated to a temperature at which at least some of the precursor of aluminum oxide is converted to beta"-alumina. The precursor of aluminum oxide is one which, when calcined in air by itself, has a calcination product which, when subjected to X-ray diffraction, displays a predetermined X-ray diffraction trace. The X-ray diffraction trace is one whose peak with the highest intensity in the 2 (theta) range of 44.degree.-48.degree. and whose peak with the highest intensity in the 2 (theta) range of 63.degree.-69.degree. respectively have maximum intensities and integrated intensities which comply with equations (I) and (II):A/S is greater than 0.03 (I);andB/S is greater than 0.04 (II).
    • 制备β“ - 氧化铝的方法包括将氧化铝的前体分散在包含氧化钠及其前体的组分中,并分散在氧化铝的前体中,尖晶石稳定剂是包含尖晶石的组分的尖晶石稳定剂, 形成氧化物及其前体以形成混合物。 然后将混合物加热至至少一些氧化铝前体转化为β“ - 氧化铝的温度。 氧化铝的前体是当在空气中自身煅烧时具有煅烧产物,当进行X射线衍射时,其显示预定的X射线衍射迹线。 X射线衍射曲线是在44°-48°的2(θ)范围内具有最高强度的峰,其在63°-69°的2θ(θ)范围内具有最高强度的峰分别具有最大值 强度和集成强度符合方程(I)和(II):A / S大于0.03(I); B / S大于0.04(II)。
    • 6. 发明授权
    • Manufacture of beta-alumina artifacts
    • 制造β-氧化铝假象
    • US4913754A
    • 1990-04-03
    • US252500
    • 1988-09-30
    • James H. DuncanRodney J. Stead
    • James H. DuncanRodney J. Stead
    • C04B35/113H01M10/39
    • H01M10/3918C04B35/113
    • The invention provides a method of making a composite beta-alumina artifact, such as a separator tube for an electrochemical cell, comprising two beta-alumina portions which are sealed together in a sealing zone, namely an inner portion and an outer portion which extends peripherally around the inner portion and embraces it in the sealing zone. The method comprises pressing the inner and outer portions from powders which, when sintered, shrink and form integral beta-alumina artifacts. The portions are then arranged so that the outer portion extends around the inner portion and embraces it in a sealing zone. The portions are then sintered to cause them to seal together hermetically in the sealing zone while converting each of the portions into a beta-alumina artifact. The portions are made so that the outer portion undergoes a greater degree of shrinkage during sintering than the inner portion and the portions are pressed so that the spacing between the portions where the outer portion extends around and embraces the inner portion is such that, upon sintering, the outer portion shrinks on to the inner portion to provide a hermetic peripheral seal between the portions.
    • 本发明提供一种制备复合β-氧化铝伪影的方法,例如用于电化学电池的隔离管,包括两个β-氧化铝部分,密封区域密封在一起,即在外围延伸的内部部分和外部部分 围绕内部部分并将其包围在密封区域中。 该方法包括将粉末的内部和外部部分压制成粉末,其在烧结时收缩并形成整体的β-氧化铝假象。 然后将这些部分布置成使得外部部分围绕内部部分延伸并且将其包围在密封区域中。 然后将这些部分烧结,使得它们在密封区中密封在一起,同时将每个部分转变为β-氧化铝伪影。 制造这些部分使得外部部分在烧结期间比内部部分发生更大程度的收缩,并且部分被按压,使得外部部分围绕并包围内部部分的部分之间的间隔使得在烧结时 ,外部部分收缩到内部部分,以在这些部分之间提供密封的周边密封。
    • 8. 发明授权
    • Electrochemical cell
    • 电化学细胞
    • US5187029A
    • 1993-02-16
    • US700390
    • 1991-05-08
    • Johan CoetzerJames H. Duncan
    • Johan CoetzerJames H. Duncan
    • H01M2/18H01M10/39
    • H01M10/39H01M2/18
    • The invention provides a high temperature rechargeable electrochemical power storage cell comprising a cell housing defining a cathode compartment containing a cathode and containing an anode structure located within the cathode compartment and comprising a plurality of holders filled with active anode material which is molten at the operating temperature of the cell. The anode structure defines a conduit containing active anode material and the holders are flattened in shape and spaced along the conduit in series from one another. The interior of each holder is in communication with the conduit and each holder has a pair of oppositely outwardly facing major faces extending transversely to the conduit and comprising a material which is a conductor of the active anode material. The cathode occupies the spaces between the holders and the cell includes a reservoir for active anode material in communication with the conduit, the reservoir in all states of charge of the cell being at least partially filled with active anode material.
    • 本发明提供了一种高温可再充电电化学蓄电池,其包括限定包含阴极的阴极室并且包含位于阴极室内的阳极结构的电池壳体,并且包括填充有在工作温度下熔化的活性阳极材料的多个保持器 的细胞。 阳极结构限定了含有活性阳极材料的管道,并且保持器的形状被平坦化并且彼此间隔开地沿管道间隔开。 每个保持器的内部与导管连通,并且每个保持器具有横向于导管延伸的一对相对向外的主表面,并且包括作为活性阳极材料的导体的材料。 阴极占据保持器之间的空间,并且电池包括用于与导管连通的活性阳极材料的储存器,所述电池的所有充电状态的储存器至少部分地填充有活性阳极材料。