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    • 2. 发明授权
    • Emulsion compositions
    • 乳液组合物
    • US6054493A
    • 2000-04-25
    • US222662
    • 1998-12-30
    • James H. Bush
    • James H. Bush
    • B01F17/00C09K3/00
    • C09K3/00B01F17/005
    • Emulsion compositions comprise an aqueous phase, an organic phase, and an emulsifying amount of an emulsifier composition comprising:the reaction product of an amine (C) characterized by the presence within its structure of at least one H--N group and an intermediate formed in the reaction of(A) at least one olefinic compound containing at least one group of the formula ##STR1## and (B) at least one carboxylic reactant selected from the group consisting of compounds of the formulaR.sup.3 C(O)(R.sup.4).sub.n C(O)OR.sup.5 (III) wherein each of R.sup.3 and R.sup.5 is independently H or a hydrocarbyl group, R.sup.4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof and optionally, from about 0.5 to about 2 moles, per mole of (B), of(D) at least one aldehyde or ketone.
    • 乳液组合物包含水相,有机相和乳化剂组合物,其包含:胺(C)的反应产物,其特征在于其结构内存在至少一个HN基团和在反应中形成的中间体 (A)至少一种含有至少一个下式的烯属化合物和(B)至少一种选自式R 3 C(O)(R 4)nC(O)OR 5(III)的化合物的羧酸反应物) 其中R 3和R 5各自独立地为H或烃基,R 4为二价亚烃基,n为0或1,其反应性源和任选地约0.5至约2摩尔每摩尔(B), 的(D)至少一种醛或酮。
    • 3. 发明授权
    • Compositions containing combinations of surfactants and derivatives of
succinic acylating agent or hydroxyaromatic compounds and methods of
using the same
    • 包含表面活性剂和琥珀酰化剂或羟基芳族化合物的衍生物的组合的组合物及其使用方法
    • US5330662A
    • 1994-07-19
    • US852872
    • 1992-03-17
    • Richard W. JahnkeLawrence J. KocurekJames H. Bush
    • Richard W. JahnkeLawrence J. KocurekJames H. Bush
    • B01F17/00C09K8/28C09K8/36E21B43/00C09K7/02
    • B01F17/005B01F17/0085C09K8/28C09K8/36Y10S507/925
    • This invention relates to a composition comprising a mixture of a brine and a liquid hydrocarbon, and (A) an emulsifying amount of (i) at least one reaction product of a hydrocarbyl-substituted succinic acylating agent, and at least one of (a) ammonia, (b) an alcohol, or (c) an amine, or at least one salt of the reaction product; or (ii) at least one reaction product of a hydroxyaromatic compound, an aldehyde, and an amine, and (B) at least one surfactant selected from the group consisting of a polyoxyalkylene amine, a polyoxyalkylene amide, a polyoxyalkylene alcohol, a polyoxyalkylene phenol, a polyoxyalkylene ester, a fatty acid salt, an amine or an alkaline earth or transition metal sulfonate, or a reaction product of a hydroxyamine or a polyalkylenepolyamine with an acylating agent selected from the group consisting of a fatty monocarboxylic acylating agents, a dicarboxylic acylating agent other than a succinic acylating agent, and a tricarboxylic acylating agent. The compositions of the present invention have beneficial emulsion and viscosity properties. These compositions are useful in drilling, working and completing well bore holes. The compositions of the present invention have beneficial viscosity, pumping and suspension properties. These compositions are stable. The surfactants of the compositions act as wetting agents for barites and organophilic clays. The surfactants may also act as an emulsifier as well as a wetting agent.
    • 本发明涉及包含盐水和液体烃的混合物的组合物,和(A)乳化量的(i)至少一种烃基取代的琥珀酰化剂的反应产物和(a)的至少一种, 氨,(b)醇,或(c)胺,或至少一种反应产物的盐; 或(ii)羟基芳族化合物,醛和胺的至少一种反应产物,和(B)至少一种表面活性剂,其选自聚氧化烯胺,聚氧化烯酰胺,聚氧化烯醇,聚氧化烯苯酚 ,聚氧化烯酯,脂肪酸盐,胺或碱土金属或过渡金属磺酸盐,或羟胺或聚亚烷基多胺与酰化剂的反应产物,所述酰化剂选自脂肪单羧酸酰化剂,二羧酰化剂 琥珀酰化剂以外的其它试剂和三羧酸酰化剂。 本发明的组合物具有有利的乳液和粘度特性。 这些组合物可用于钻孔,加工和完井孔。 本发明的组合物具有有益的粘度,泵送和悬浮性能。 这些组合物是稳定的。 组合物的表面活性剂作为重晶石和亲有机粘土的润湿剂。 表面活性剂也可以用作乳化剂以及润湿剂。
    • 4. 发明授权
    • Flotation composition using a mixture of collectors
    • 使用收集器混合物的浮选组合物
    • US5147572A
    • 1992-09-15
    • US775335
    • 1991-10-11
    • James H. Bush
    • James H. Bush
    • B03D1/004B03D1/012B03D1/014
    • B03D1/014B03D1/012B03D2201/02B03D2203/02
    • The present invention relates to improved flotation composition comprising a mixture of (A) at least one metal salt of a phosphorus acid represented by the Formula: ##STR1## wherein each R.sub.1 is independently a hydrocarbyl, hydrocarbyloxy of hydrocarbylthio group having from 1 to about 18 carbon atoms, each X is independently oxygen or sulfur, and the lowest oxidation state of the metal is plus two, and (B) at least one dithiocarbamate represented by the formula: ##STR2## wherein each R.sub.2 is independently hydrogen, a hydrocarbyl group having from 1 to about 18 carbon atoms, or R.sub.2 taken together with R.sub.3 and the nitrogen atom form a five, six or seven member heterocyclic group; each R.sub.3 is independently a hydrocarbyl group having from 1 to about 18 carbon atoms, or R.sub.3 taken together with R.sub.2 and the nitrogen atom form a five, six or seven member heterocyclic group; and R.sub.4 is a hydrocarbylene group having from 1 to about 10 carbon atoms.
    • 本发明涉及改进的浮选组合物,其包含(A)至少一种由式(I)表示的磷酸的至少一种金属盐的混合物,其中每个R 1独立地为烃基,烃基硫代烃基具有1 至约18个碳原子,每个X独立地为氧或硫,并且金属的最低氧化态为加二,和(B)至少一种由下式表示的二硫代氨基甲酸盐:其中每个R 2独立地为 氢,具有1至约18个碳原子的烃基,或R 2与R 3和氮原子一起形成五,六或七元杂环基; 每个R 3独立地是具有1至约18个碳原子的烃基,或R 3与R 2一起并且氮原子形成5,6或7元杂环基; 并且R 4是具有1至约10个碳原子的亚烃基。