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    • 5. 发明授权
    • Shape anisotropic metal oxide nanoparticles and synthetic method thereof
    • 形状各向异性金属氧化物纳米粒子及其合成方法
    • US07122168B2
    • 2006-10-17
    • US10678047
    • 2003-10-01
    • Kyoungja WooJae-Pyoung AhnHae-Weon Lee
    • Kyoungja WooJae-Pyoung AhnHae-Weon Lee
    • C01G1/00C01G49/00
    • B82Y30/00C01G49/06C01P2002/72C01P2004/04C01P2004/64C01P2006/42Y10S977/773Y10S977/775Y10S977/777Y10S977/811
    • In a metal oxide nanoparticle and a synthetic method thereof, and in particular to maghemite (γ-Fe2O3) nanoparticles usable as a superhigh density magnetic recording substance by having good shape anisotropy and magnetic characteristics, hematite (α-Fe2O3) nanoparticles usable as a precursor to the maghemite or a catalyst, maghemite and hematite-mixed nanoparticles and a synthetic method thereof, the method for synthesizing metal oxide nanoparticles includes forming a reverse micelle solution by adding distilled water, a surfactant and a solvent to metallic salt not less than trivalent, precipitating and separating gel type amorphous metal oxide particles by adding proton scavenger to the reverse micelle solution; adjusting a molar ratio of metal oxide to the surfactant by washing the gel type amorphous metal oxide particles with a polar solvent; and crystallizing metal oxide nanoparticles through heating or reflux after dispersing the gel type amorphous metal oxide particles in a non-polar solvent having a high boiling point.
    • 在金属氧化物纳米颗粒及其合成方法中,特别涉及可用作超高密度磁记录物质的磁赤铁矿(γ-Fe 2 O 3 O 3)纳米颗粒,其具有良好的 形状各向异性和磁特性,可用作磁赤铁矿或催化剂的前体的赤铁矿(α-Fe 2 O 3 O 3)纳米颗粒和合成的赤铁矿 方法,合成金属氧化物纳米粒子的方法包括:通过向不同于三价的金属盐中加入蒸馏水,表面活性剂和溶剂形成反胶束溶液,通过向反相中加入质子清除剂沉淀和分离凝胶型无定形金属氧化物颗粒 胶束溶液; 通过用极性溶剂洗涤凝胶型无定形金属氧化物颗粒来调节金属氧化物与表面活性剂的摩尔比; 以及在将凝胶型无定形金属氧化物颗粒分散在具有高沸点的非极性溶剂中之后通过加热或回流结晶金属氧化物纳米颗粒。