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    • 3. 发明授权
    • Method for forming coated monocrystalline products
    • 形成涂层单晶产品的方法
    • US5180463A
    • 1993-01-19
    • US454343
    • 1989-12-21
    • Jacques Le MoigneAnnette ThierryPierre Guerder
    • Jacques Le MoigneAnnette ThierryPierre Guerder
    • G02F1/35C08F38/00C30B23/02G02F1/355G02F1/361
    • G02F1/3615C30B23/02C30B29/58Y10S117/915Y10S117/919
    • A polydiacetylene coating layer deposited upon an organic microcrystal. The coating has a large, uniform surface area which is monoriented and without cracks. The preferred embodiment utilizes for the monomer a layer of [1,6-di- n(carbazolyl)-2,4-hexadiyne] deposited by epitaxy onto an acid orthophthalate monocrystal of an alkali metal, ammonium or thallium. The process of the invention comprises cleaving the acid orthophthalate monocrystal along its (001) plane; depositing a diacetylenic monomer onto the cleaved face of the crystal by heat evaporation under vacuum conditions, and polymerizing the monomer upon the crystal face. The coated layer may thereafter be removed from the crystalline substrate by applying a composition such as, e.g., cabon or an acrylic polymer onto the coating to form a backing therefore and separating the resultant monoriented film from the crystal by at least partially immersing the coated crystal in water.
    • 沉积在有机微晶上的聚二乙炔涂层。 涂层具有大的均匀的表面积,其单面且没有裂纹。 优选的实施方案通过外延将单层的一层[1,6-二(咔唑基)-2,4-己二炔)用于碱金属,铵或铊的酸性邻苯二甲酸酯单晶上。 本发明的方法包括沿其(001)面切割酸邻苯二甲酸酐单体; 在真空条件下通过热蒸发将二乙炔单体沉积在晶体的切割面上,并在晶面上聚合单体。 此后可以通过将例如卡顿或丙烯酸类聚合物的组合物施加到涂层上以形成背衬,从而将涂层从结晶基底上除去,从而将所得单取向膜与晶体分开,至少部分地将涂覆的晶体 在水里。