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    • 3. 发明授权
    • Reducing hydrogen consumption in hydrotreating petroleum fractions
    • 降低加氢处理石油馏分中的氢消耗
    • US3997427A
    • 1976-12-14
    • US644184
    • 1975-12-24
    • Jackson EngNoel J. Gaspar
    • Jackson EngNoel J. Gaspar
    • B01J23/881C01B3/38C01B3/40C10G45/04C10G45/08C10G37/06
    • C10G45/08B01J23/881C01B3/38C01B3/40C10G45/04C01B2203/1052Y02P20/52
    • A process for hydrotreating middle distillate fraction petroleum feed stocks wherein hydrogen requirements for the hydrotreater are reduced by first passing the feed stock and steam to a steam hydroconversion zone over a dual function catalyst comprising molybdenum on a chromium supported on ferric oxide support or on a high surface area alumina support. In the steam hydroconversion zone a portion of the feed reacts with the steam to produce hydrogen via a steam reforming reaction. This hydrogen is used in situ to saturate a substantial portion of the olefins and remove some of the sulfur compounds present in the feed stock, thereby partially refining same. The partially refined feed is then passed to a hydrotreating zone for further treatment with greatly reduced hydrogen requirements in said hydrotreating zone.
    • 一种用于加氢处理中间馏分馏分石油原料的方法,其中通过首先使原料和蒸汽通过双重功能催化剂将蒸汽加热转化到蒸汽加氢转化区,减少加氢处理器的氢需求,所述双重功能催化剂包含在负载在氧化铁载体上的铬上的钼或高 表面积氧化铝载体。 在蒸汽加氢转化区中,一部分进料与蒸汽反应,通过蒸汽重整反应产生氢气。 这种氢原位使用以使大部分烯烃饱和并除去存在于原料中的一些硫化合物,从而部分地将其纯化。 然后将部分精制的进料进入加氢处理区进行进一步处理,在所述加氢处理区中氢气需求大大降低。