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    • 5. 发明授权
    • Method for removing scale from metallic substrates
    • 从金属基底去除垢的方法
    • US3996062A
    • 1976-12-07
    • US608823
    • 1975-08-28
    • Jack G. FrostLarry D. MartinWilliam P. Banks
    • Jack G. FrostLarry D. MartinWilliam P. Banks
    • C02F5/14C23G1/14F28G9/00C23G1/00
    • C02F5/14C23G1/14F28G9/00
    • Iron containing scale is removed from a metallic substrate by contacting the scale with a composition which is an aqueous solution consisting essentially of at least 0.5 weight percent of a polyphosphonic acid, or an alkali metal or amine salt of such acid, with the acid being selected from the group of acids having the formulae: ##STR1## where R.sub.1 is selected from the class consisting of C.sub.1 -C.sub.12 alkyl groups, and the group ##STR2## and ##STR3## where R.sub.2 is selected from the class consisting of --H, --PO.sub.3 H.sub.2, C.sub.1 -C.sub.12 alkyl groups, and the group ##STR4## The scale is removed from the metallic substrate by contacting THE DESCRIBED SCALE-BEARING SUBSTRATE WITH THE DESCRIBED COMPOSITION AT SELECTED TEMPERATURE AND PH conditions, and over a controlled time period and iron concentration in the composition so that the formation of an undesirable polymeric precipitate in the cleaning solution is avoided. Formation of the precipitate is also avoided by adding ammonium bifluoride to the composition.
    • 通过使水垢与基本上由至少0.5重量%的多膦酸或这种酸的碱金属或胺盐组成的水溶液与选择酸的组合物相接触,从金属底物中除去含铁垢 来自具有下式的酸组:其中R 1选自C 1 -C 12烷基,和(2)组,其中R 2选自类 由-H,-PO 3 H 2,C 1 -C 12烷基和基团组成。通过在描述的温度和pH条件下将描述的标准载体基材与描述的组合物接触,并通过在 控制时间段和组合物中的铁浓度,从而避免在清洁溶液中形成不期望的聚合物沉淀物。 通过向组合物中加入二氟化铵也可以避免形成沉淀物。
    • 10. 发明授权
    • Method for treating chelant solutions to remove metals in solution
    • 处理溶液中螯合剂溶液去除金属的方法
    • US5160631A
    • 1992-11-03
    • US740544
    • 1991-08-05
    • Jack G. FrostKenneth J. Snyder
    • Jack G. FrostKenneth J. Snyder
    • C02F1/02C02F1/52C02F9/00
    • C02F9/00C02F1/025C02F1/5236C02F2101/20Y10S210/912Y10S210/913
    • A process for removing at least a portion of any iron, copper, nickel and chromium ions that are chelated by a alkylenepolyamine polyacetic acid or salt in an aqueous liquid waste. The process comprises the steps of (a) adjusting the pH of the liquid to above about 10; (b) adding sufficient sodium sulfide to react with at least a portion of the copper ions; (c) separating precipitated iron and copper compounds; (d) adding nitric acid to adjust the pH to the range of about 6 to 8; (e) adding sufficient sodium nitrite to the liquid to react with at least a portion of the nickel and chromium present; (f) heating the liquid to above about 575.degree. F. for at least about 15 minutes to facilitate precipitation of nickel and chromium; and (g) separating precipitated solids to leave a non-hazardous filtrate.
    • 一种除去在含水废液中被亚烷基多胺多乙酸或盐螯合的任何铁,铜,镍和铬离子的至少一部分的方法。 该方法包括以下步骤:(a)将液体的pH调节至大约10; (b)加入足够的硫化钠以与至少一部分铜离子反应; (c)分离沉淀的铁和铜化合物; (d)加入硝酸以将pH调节至约6至8的范围; (e)向液体中加入足够的亚硝酸钠以与存在的镍和铬的至少一部分反应; (f)将液体加热至约575°F至少约15分钟以促进镍和铬的沉淀; 和(g)分离沉淀的固体以留下非危险的滤液。