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    • 1. 发明申请
    • PRODUCTION OF LIQUID HYDROCARBONS
    • 生产液体碳氢化合物
    • US20150060326A1
    • 2015-03-05
    • US14389817
    • 2013-04-05
    • IGTL TECHNOLOGY LTD
    • Richard John Hyman
    • C10L1/04
    • C10L1/04C10G2/332C10G2/343C10G35/04C10G45/58C10G2300/4081C10G2400/02C10G2400/04C10G2400/08C10G2400/20C10L1/06C10L1/08C10L2200/0438C10L2200/0446C10L2200/0492C10L2270/023C10L2270/026
    • The invention relates to a process for the conversion of hydrogen and one or more oxides of carbon to hydrocarbons, which process comprises: contacting hydrogen and one or more oxides of carbon with a catalyst in a reaction zone; removing from the reaction zone an outlet stream comprising unreacted hydrogen, unreacted one or more oxides of carbon and one or more hydrocarbons and feeding the outlet stream to a separation zone in which the outlet stream is divided into at least three fractions, in which; a first fraction predominantly comprises unreacted hydrogen, unreacted one or more oxides of carbon and hydrocarbons having from 1 to 4 carbon atoms; a second fraction predominantly comprises hydrocarbons having 5 to 9 carbon atoms, at least a portion of which hydrocarbons having from 5 to 9 carbon atoms are olefinic; and a third fraction predominantly comprises hydrocarbons having 10 or more carbon atoms; characterised in that at least a portion of the second fraction is recycled to the reaction zone.
    • 本发明涉及一种将氢和一种或多种碳氧化物转化成烃的方法,该方法包括:使氢和一种或多种碳氧化物与反应区中的催化剂接触; 从反应区域除去包含未反应的氢,未反应的一种或多种碳和一种或多种烃的氧化物的出口物流,并将出口物流输送到分离区,其中出口物流被分成至少三个馏分。 第一级分主要包括未反应的氢,未反应的一种或多种碳和碳原子数为1至4的氧化物; 第二部分主要包含具有5至9个碳原子的烃,其中至少一部分具有5至9个碳原子的烃是烯属的; 并且第三级分主要包含具有10个或更多个碳原子的烃; 其特征在于,所述第二级分的至少一部分被再循环至所述反应区。
    • 4. 发明申请
    • OLIGOMERISATION OF OLEFINS FOR THE PRODUCTION OF SYNTHETIC FUEL
    • 用于生产合成燃料的烯烃的低级化
    • US20150148573A1
    • 2015-05-28
    • US14402526
    • 2013-05-21
    • IGTL TECHNOLOGY LTD
    • Richard HymanAlfred Ecker
    • C10L1/04C07C2/12
    • C10L1/04C07C2/12C07C2529/06C10G50/00C10G69/126C10L1/08C10L2200/0469C10L2270/026C10L2270/04
    • The invention relates to a synthetic hydrocarbon fuel composition, and a process for making such a fuel composition, in which the fuel composition has the following properties: a) a boiling point distribution having (i) a 10% recovery of 205° C. or less and (ii) an end point of 300° C. or less; b) a freezing point of −47° C. or less; and c) a density at 15° C. of at least 775 kg/m3. A process for producing the fuel composition comprises the oligomerisation of olefins over an oligomerisation catalyst. In addition the invention relates to a process for producing hydrocarbons comprising contacting one or more olefins with an oligomerisation catalyst in a reaction zone under conditions sufficient to cause oligomerisation of olefins, and removing an outlet stream comprising products of olefin oligomerisation from the reaction zone, wherein the oligomerisation catalyst comprises a crystalline zeolite Brønsted acid catalyst, whose crystals comprise an inorganic oxide framework with an internal pore structure, and an external surface, in which the ratio of the number of Brønsted acid sites on the external surface compared to the internal pore structure is in the range of from 0.1 to 20% and/or the ratio of the surface area of the internal pore structure compared to the external crystal surface area is in the range of from 5 to 1000.
    • 本发明涉及一种合成烃燃料组合物及其制备方法,其中该燃料组合物具有以下特性:a)沸点分布,其具有(i)回收率为205℃的10%或 (ii)终点为300℃以下; b)-47℃或更低的凝固点; 和c)在15℃下的密度为至少775kg / m 3。 制备燃料组合物的方法包括在低聚催化剂上烯烃的低聚。 此外,本发明涉及一种生产烃的方法,包括在足以使烯烃低聚的条件下在反应区中使一种或多种烯烃与低聚催化剂接触,以及从反应区除去包含烯烃低聚产物的出口物流,其中 低聚催化剂包括结晶沸石布朗斯台德酸催化剂,其晶体包含具有内部孔结构的无机氧化物骨架和外表面,其中外表面上的布朗斯台德酸位数与内部孔结构相比的比率 在0.1〜20%的范围内和/或内部孔结构的表面积与外部晶体表面积的比例在5〜1000的范围内。