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    • 2. 发明授权
    • Oil shale retorting process
    • 油页岩蒸馏过程
    • US4530752A
    • 1985-07-23
    • US622638
    • 1984-06-20
    • Roland F. DeeringHugh W. GowdyArnold E. Kelley
    • Roland F. DeeringHugh W. GowdyArnold E. Kelley
    • C10G1/00C10G1/02C10B53/06
    • C10G1/006C10G1/002C10G1/02
    • Oil shale solids are pyrolyzed or retorted by contact with a non-oxidizing recycle gas in a first retorting zone to produce an effluent containing pyrolysis products and pyrolyzed oil shale solids. Liquid and gaseous product hydrocarbons are recovered from the effluent of the first retorting zone. The pyrolyzed oil shale solids are contacted with an oxygen-containing gas in a combustion zone under conditions such that at least a portion of the organic material in the pyrolyzed solids is burned to produce hot, decarbonized solids and a hot flue gas. At least a portion of the gases in the effluent from the first retorting zone is contacted in the substantial absence of molecular oxygen with a portion of the hot, decarbonized solids produced in the combustion zone in the presence of added hydrocarbon-containing fines, preferably oil shale fines, in a second retorting zone such that the gases are heated and the fines are pyrolyzed to produce pyrolyzed fines and pyrolysis products containing gases and vapors. The gases and vapors in the effluent from the second retorting zone are then recycled to the first retorting zone where they serve as the hot, non-oxidizing recycle gas.
    • 油页岩固体通过与第一蒸馏区中的非氧化循环气体接触而被热解或蒸馏以产生含有热解产物和热解油页岩固体的流出物。 从第一蒸煮区的流出物回收液态和气态产物烃。 在使得热解固体中的至少一部分有机材料燃烧以产生热脱碳固体和热烟道气的条件下,使热解油页岩固体与燃烧区中的含氧气体接触。 在基本不存在分子氧的情况下,来自第一蒸馏区的流出物中的至少一部分气体在燃烧区中产生的一部分热的脱碳固体在加入的含烃微粒存在下接触,优选为油 页岩细碎在第二个蒸煮区,使得气体被加热并且细粉被热解以产生含有气体和蒸气的热解的细粉和热解产物。 然后将来自第二蒸馏区的流出物中的气体和蒸气再循环到第一蒸馏区,在那里它们用作热的非氧化循环气体。