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1. 发明授权

US06541562B1 Aqueous paint composition 失效
标题翻译：水性漆组合物
公开(公告)号：US06541562B1
公开(公告)日：2003-04-01
申请号：US09677882
申请日：2000-10-03
申请人： Ryuichi Aoki , Tadashi Hatakeyama , Hiroharu Sasaki , Kazuyoshi Tsuneta
发明人： Ryuichi Aoki , Tadashi Hatakeyama , Hiroharu Sasaki , Kazuyoshi Tsuneta
IPC分类号： C08L8300
CPC分类号： C09D201/10 , C09D183/10 , C08L2666/44
摘要： An aqueous paint composition comprising: (i) an aqueous dispersion obtained by neutralizing with a neutralizing agent a hydrolytic condensation reaction product of (a) 100 parts by weight of an organosilane of the formula (1) R1nSi(OR2)4-n, wherein R1 is a C1-8 organic group, R2 is a C1-5 alkyl group, and n is 1 or 2, and/or its partially hydrolyzed condensate, with (b) from 5 to 200 parts by weight of a silyl group-containing vinyl resin having hydrolyzable silyl groups or silyl groups having silicon atoms bonded to hydroxyl groups and having an acid value of from 20 to 150 mgKOH/g, and adding water thereto, (ii) an amino group-containing alkoxysilane compound, and (iii) an epoxy group-containing compound.
摘要翻译：一种水性涂料组合物，其包含：（i）通过用中和剂中和（a）100重量份式（1）的有机硅烷R 1 n Si（OR 2）4-n的水解缩合反应产物得到的水分散体，其中 R 1为C 1-8有机基团，R 2为C 1-5烷基，n为1或2，和/或其部分水解缩合物，（b）5〜200重量份含甲硅烷基具有可水解的甲硅烷基的乙烯基树脂或具有与羟基键合的硅原子并具有20〜150mgKOH / g的酸值的甲硅烷基，向其中加入水，（ii）含氨基的烷氧基硅烷化合物，和（iii）含环氧基的化合物。

2. 发明授权

US4177174A Epoxy resin composition cured by reaction product of phenol carboxylic acids with polyamino compounds 失效
标题翻译：环氧树脂组合物由苯酚羧酸与聚氨基化合物的反应产物固化
公开(公告)号：US4177174A
公开(公告)日：1979-12-04
申请号：US795125
申请日：1977-05-09
申请人： Masaaki Hayashi , Kazuyoshi Tsuneta , Hiroshi Takada , Nobuhiro Kenmotsu , Hiroharu Sasaki
发明人： Masaaki Hayashi , Kazuyoshi Tsuneta , Hiroshi Takada , Nobuhiro Kenmotsu , Hiroharu Sasaki
IPC分类号： C08G59/62 , C08G59/44
CPC分类号： C08G59/625
摘要： An epoxy resin coating composition comprising (i) an epoxy resin containing in the molecule at least 2 epoxy groups and (ii) a reaction product formed by condensing an amino compound containing in the molecule at least 2 nitrogen atoms and active hydrogen atoms bonded thereto with 5 to 30% by weight, based on said amino compound, of at least one compound selected from the group consisting of phenol-carboxylic acids and esters thereof.
摘要翻译：一种环氧树脂涂料组合物，其包含（i）在分子中含有至少2个环氧基的环氧树脂和（ii）通过将分子中含有至少2个氮原子的氨基化合物和与其键合的活性氢原子缩合而形成的反应产物，基于所述氨基化合物的5至30重量％的至少一种选自酚 - 羧酸及其酯的化合物。

3. 再颁专利

USRE31985E Aqueous dispersion type thermosetting coating composition 失效
标题翻译：水分散型热固性涂料组合物
公开(公告)号：USRE31985E
公开(公告)日：1985-09-17
申请号：US407284
申请日：1982-08-11
申请人： Masaaki Hayashi , Hiroharu Sasaki , Kazuyoshi Tsuneta
发明人： Masaaki Hayashi , Hiroharu Sasaki , Kazuyoshi Tsuneta
IPC分类号： C08F299/04 , C08G63/54 , C09D157/04
CPC分类号： C08G63/54 , C08F299/0478 , C09D157/04
摘要： Disclosed in an aqueous dispersion type thermosetting coating composition which comprises fine thermosetting resin particles composed of (A) a polyester resin having a specific hydroxyl value and (B) a copolymer resin, which are dispersed in the presence of (C) a surface active agent and/or a thickener in (D) a necessary amount of water.

4. 发明授权

US06410655B1 Resin composition for aqueous paint 有权
公开(公告)号：US06410655B1
公开(公告)日：2002-06-25
申请号：US09731721
申请日：2000-12-08
申请人： Masayoshi Okubo , Shinya Sakaguchi , Atsushi Takamatsu , Hiroharu Sasaki , Kazuyoshi Tsuneta
发明人： Masayoshi Okubo , Shinya Sakaguchi , Atsushi Takamatsu , Hiroharu Sasaki , Kazuyoshi Tsuneta
IPC分类号： C08F26502
摘要： A resin composition for an aqueous paint containing different phase structure emulsion particles obtained by multi-stage emulsion polymerization as a binder, wherein the different phase structure emulsion particles have an outermost phase formed by an emulsion polymer of an ethylenic unsaturated monomer, having a glass transition temperature of from −50° C. to 10° C., and satisfy the following conditions (1) to (3): (1) the emulsion polymer forming the outermost phase contains from 1 to 20 mass % of an ethylenic unsaturated monomer having at least one of a polyethylene glycol chain and a polypropylene glycol chain, (2) at least one phase of inner phases from the outermost phase of the different phase structure emulsion particles comprises an emulsion polymer of an ethylenic unsaturated monomer having a glass transition temperature of from 30° C. to 110° C., and (3) the binder has a minimum film-forming temperature of at most 10° C.

5. 发明授权

US6034161A Cold-setting aqueous emulsion paint 失效
标题翻译：冷凝水性乳液漆
公开(公告)号：US6034161A
公开(公告)日：2000-03-07
申请号：US88710
申请日：1998-06-02
申请人： Tetsuo Nakamura , Hiroharu Sasaki , Kazuyoshi Tsuneta , Sadakazu Hokamura
发明人： Tetsuo Nakamura , Hiroharu Sasaki , Kazuyoshi Tsuneta , Sadakazu Hokamura
IPC分类号： C08F290/06 , C09D4/06 , C09D5/00 , C09D133/14 , C09D167/07 , C08K3/22 , C08K3/34
CPC分类号： C09D133/14
摘要： A cold-setting aqueous emulsion paint comprising a pigment and an aqueous emulsion resin consisting essentially of a copolymer of (a) a polymerizable monomer of the formula (I): ##STR1## wherein R is a hydrogen atom or a methyl group, and n is 1 or 2, (b) a polymerizable monomer having a carboxyl group and an ethylenic double bond, and (c) a polymerizable monomer having an ethylenic double bond copolymerizable with the above polymerizable monomers (a) and (b).
摘要翻译：一种冷固水性乳液漆，其包含颜料和水性乳液树脂，其基本上由（a）式（I）的可聚合单体的共聚物组成：其中R是氢原子或甲基，n是1或 2，（b）具有羧基和烯属双键的可聚合单体，和（c）可与上述可聚合单体（a）和（b）共聚的具有烯属双键的可聚合单体。

6. 发明授权

US4525499A Non-aqueous dispersion type resin composition 失效
标题翻译：非水分散型树脂组合物
公开(公告)号：US4525499A
公开(公告)日：1985-06-25
申请号：US611144
申请日：1984-05-17
申请人： Masaaki Hayashi , Hiroharu Sasaki
发明人： Masaaki Hayashi , Hiroharu Sasaki
IPC分类号： C08F2/08 , C08F2/14 , C08L67/06 , C09D3/64 , C09D3/80 , C09D5/02
CPC分类号： C08F2/08 , Y10S524/923
摘要： A non-aqueous dispersion type resin composition comprising (I) a non-polar or slightly polar aliphatic hydrocarbon solvent as a dispersion medium, and (II) particles stably dispersed in the dispersion medium, wherein each of said particles is composed of:(A) from 20 to 70% by weight of a disperse particle made of (a) a polyester-modified vinyl copolymer containing a hydroxyl group, (b) a vinyl copolymer containing a hydroxyl group or (c) a vinyl ester-modified vinyl copolymer containing a hydroxyl group, and(B) from 80 to 30% by weight of a vinyl resin dispersion stabilizer surrounding the disperse particle as a protective layer, which has a component compatible with the disperse particle or is chemically bonded thereto and which is solvated by the dispersion medium, said dispersion stabilizer being composed of (i) an N-alkoxymethylated monomer of an .alpha., .beta.-monoethylenically unsaturated carboxylic acid amide and (ii) an .alpha., .beta.-monoethylenically unsaturated monomer other than the monomer (i), and said dispersion medium is capable of dissolving the dispersion stabilizer and incapable of dissolving the disperse particles.
摘要翻译：一种非水分散型树脂组合物，其包含（I）作为分散介质的非极性或极性极性的脂族烃溶剂和（II）稳定分散在分散介质中的颗粒，其中每个所述颗粒由以下组成：（A ）20〜70重量％的由（a）含有羟基的聚酯改性的乙烯基共聚物制成的分散粒子，（b）含有羟基的乙烯基共聚物或（c）乙烯基酯改性的乙烯基共聚物，其含有羟基，和（B）80〜30重量％的围绕作为保护层的分散粒子的乙烯基树脂分散稳定剂，其具有与分散粒子相容的化学键合或化学键合的组分，并由所述分散稳定剂由（i）α，β-单烯属不饱和羧酸酰胺的N-烷氧基甲基化单体和（ii）其它的α，β-单烯属不饱和单体组成并且所述分散介质能够溶解分散稳定剂并且不能溶解分散颗粒。

7. 发明授权

US4296014A Aqueous dispersion type thermosetting coating composition 失效
标题翻译：水分散型热固性涂料组合物
公开(公告)号：US4296014A
公开(公告)日：1981-10-20
申请号：US104447
申请日：1979-12-17
申请人： Masaaki Hayashi , Hiroharu Sasaki , Kazuyoshi Tsuneta
发明人： Masaaki Hayashi , Hiroharu Sasaki , Kazuyoshi Tsuneta
IPC分类号： C08F299/04 , C08G63/54 , C09D157/04 , C08L67/06
CPC分类号： C08G63/54 , C08F299/0478 , C09D157/04
摘要： Disclosed in an aqueous dispersion type thermosetting coating composition which comprises fine thermosetting resin particles composed of (A) a polyester resin having a specific hydroxyl value and (B) a copolymer resin, which are dispersed in the presence of (C) a surface active agent and/or a thickener in (D) a necessary amount of water.
摘要翻译：本发明涉及由（A）具有特定羟值的聚酯树脂和（B）共聚物树脂组成的精细热固性树脂颗粒的水性分散型热固性涂料组合物中，（C）表面活性剂和/或增稠剂（D）必需量的水。

8. 发明授权

US4067838A Chelate-forming aqueous resin composition 失效
标题翻译：螯合物形成水性树脂组合物
公开(公告)号：US4067838A
公开(公告)日：1978-01-10
申请号：US657593
申请日：1976-02-12
申请人： Masaaki Hayashi , Kazuyoshi Tsuneta , Hiroharu Sasaki , Hiroshi Takada
发明人： Masaaki Hayashi , Kazuyoshi Tsuneta , Hiroharu Sasaki , Hiroshi Takada
IPC分类号： C08G59/50 , C08G59/58 , C08L37/00 , C08L63/02 , C08L63/04 , C08L63/08
CPC分类号： C08G59/58 , C08G59/5093
摘要： A chelate-forming two-pack type aqueous resin composition comprising (i) an aqueous dispersion of a resin containing in the molecule at least 2 epoxy groups and (ii) a reaction product formed between an amino curing agent containing in the molecule at least 2 nitrogen atoms and active hydrogen atoms bonded thereto and protocatechuic acid and/or gallic acid is disclosed.
摘要翻译：一种螯合形成双组分型水性树脂组合物，其包含（i）在分子中含有至少2个环氧基的树脂的水性分散体和（ii）在分子中含有至少2个的氨基固化剂之间形成的反应产物公开了氮原子和与之结合的活性氢原子和原儿茶酸和/或没食子酸。

9. 发明授权

US06538062B2 Resin composition for aqueous paint 失效
标题翻译：水性涂料用树脂组合物
公开(公告)号：US06538062B2
公开(公告)日：2003-03-25
申请号：US09883254
申请日：2001-06-19
申请人： Shinya Sakaguchi , Atsushi Takamatsu , Hiroharu Sasaki , Kazuyoshi Tsuneta
发明人： Shinya Sakaguchi , Atsushi Takamatsu , Hiroharu Sasaki , Kazuyoshi Tsuneta
IPC分类号： C08L3300
CPC分类号： C08L51/003 , C08F257/02 , C08F265/06 , C08F291/00 , C09D151/003 , C08F2/22 , C08L2666/02
摘要： A resin composition for an aqueous paint, which comprises (a) a binder composed of different phase structure emulsion particles obtained by multi-stage emulsion polymerization, and (b) a compound having at least two hydrazide groups in its molecule, wherein the different phase structure emulsion particles have an outermost phase formed of an emulsion polymer which is an emulsion polymer of an ethylenic unsaturated monomer, having a glass transition temperature of from −50° C. to 15° C., and the following conditions (1) to (3) are satisfied: (1) the emulsion polymer forming the outermost phase contains from 1 to 25 mass % of an ethylenic unsaturated monomer having a carbonyl group, (2) at least one phase located inside the outermost phase of the different phase structure emulsion particles, is formed of an emulsion polymer of an ethylenic unsaturated monomer, having a glass transition temperature of from 50° C. to 150° C., and (3) the binder has a minimum film-forming temperature of at most 30° C.
摘要翻译：一种水性涂料用树脂组合物，其包含（a）由通过多阶段乳液聚合获得的不同相结构乳液颗粒组成的粘合剂，和（b）在其分子中具有至少两个酰肼基团的化合物，其中所述不同相结构乳液颗粒具有由乳液聚合物形成的最外相，乳液聚合物是玻璃化转变温度为-50℃至15℃的烯属不饱和单体的乳液聚合物，以及以下条件（1）至（ 3）满足：（1）形成最外层的乳液聚合物含有1〜25质量％的具有羰基的烯键式不饱和单体，（2）位于不同相结构乳液的最外相中的至少一相颗粒由玻璃化转变温度为50℃至150℃的烯属不饱和单体的乳液聚合物形成，（3）粘合剂的成膜温度为最多30°C

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