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1. 发明申请

US20120217186A1 METHOD FOR PRODUCING LUBRICANT BASE OIL 有权
标题翻译：生产润滑油基油的方法
公开(公告)号：US20120217186A1
公开(公告)日：2012-08-30
申请号：US13391067
申请日：2010-08-06
申请人： Kazuaki Hayasaka , Hideki Ono , Yoshiyuki Nagayasu , Masahiro Taguchi , Hideshi Iki
发明人： Kazuaki Hayasaka , Hideki Ono , Yoshiyuki Nagayasu , Masahiro Taguchi , Hideshi Iki
IPC分类号： C10G73/38
CPC分类号： C10G65/02 , B01J21/066 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J29/7484 , B01J35/002 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/03 , C10G45/58 , C10G45/60 , C10G45/62 , C10G45/64 , C10G65/043 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M101/02 , C10M2203/1025 , C10M2205/173 , C10N2220/026 , C10N2220/027 , C10N2220/028 , C10N2220/031 , C10N2230/02 , C10N2230/10 , C10N2230/43 , C10N2240/10 , C10N2270/00 , C10N2220/022
摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.
摘要翻译：一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触存在分子氢以获得第二产生的油。第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。

2. 发明申请

US20120216449A1 METHOD FOR PRODUCING AVIATION FUEL OIL BASE AND AVIATION FUEL OIL COMPOSITION 有权
标题翻译：制造航空燃油油基和航空燃料油组合物的方法
公开(公告)号：US20120216449A1
公开(公告)日：2012-08-30
申请号：US13391727
申请日：2010-08-30
申请人： Kazuaki Hayasaka , Hideki Ono , Akira Koyama , Hideshi Iki
发明人： Kazuaki Hayasaka , Hideki Ono , Akira Koyama , Hideshi Iki
IPC分类号： C10L1/188
CPC分类号： B01J29/7484 , B01J23/85 , B01J23/883 , B01J29/7461 , B01J29/7492 , B01J29/85 , C10G3/46 , C10G3/49 , C10G3/50 , C10G45/64 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2400/08 , C10L1/04 , Y02P30/20
摘要： A method for producing an aviation fuel oil base includes obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6A of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.
摘要翻译：一种航空燃料油基料的制造方法，其特征在于，通过使来自动物或植物油脂的含氧烃化合物的原料与第一双官能催化剂接触而进行加氢处理，得到第一产生油，脱氢和氢化功能，其包括周期表第6A族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触来获得包含航空燃料油基的第二产生的油，该第二双功能催化剂包括周期性的第8族金属表和结晶固体酸性物质，在氢的存在下。

3. 发明申请

US20110237853A1 PROCESS FOR PRODUCING HYDROCARBON OIL 失效
标题翻译：生产油料油的工艺
公开(公告)号：US20110237853A1
公开(公告)日：2011-09-29
申请号：US13119310
申请日：2009-09-16
申请人： Tatsuo Hamamatsu , Hideki Ono , Yasutoshi Iguchi , Hideshi Iki , Yoshihiko Kinoshita
发明人： Tatsuo Hamamatsu , Hideki Ono , Yasutoshi Iguchi , Hideshi Iki , Yoshihiko Kinoshita
IPC分类号： C10G1/00
CPC分类号： C10G45/02 , C10G3/46 , C10G3/49 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/4018 , Y02P30/20
摘要： A method for manufacturing a hydrocarbon oil, comprising: a first step wherein a feedstock oil containing an oxygen-containing organic compound and a water-insoluble chlorine-containing compound is brought into contact with a hydrogenation catalyst comprising a support containing a porous inorganic oxide and one or more metals selected from Group VIA and Group VIII of the periodic table supported on the support in the presence of hydrogen to generate a hydrocarbon oil and water in a vapor state by the hydrodeoxygenation of an oxygen-containing organic compound and convert the water-insoluble chlorine-containing compound into a water-soluble chlorine-containing compound; a second step wherein the water in the reaction product of the first step is maintained in a vapor state and the reaction product of the first step is brought into contact with a nitrogen-containing Brønsted base compound which has a boiling point at normal pressure of 100° C. or less and is water-soluble to obtain a product to be treated; and a third step wherein the product to be treated is cooled to a temperature not higher than the temperature at which water in a vapor state is liquefied to form an aqueous phase containing a water-soluble chlorine-containing compound and a nitrogen-containing Brønsted base compound and then separate the aqueous phase from an oil to be treated to obtain a product oil containing a hydrocarbon oil.
摘要翻译：一种烃油的制造方法，包括：第一工序，其中含有含氧有机化合物的原料油和不溶于水的含氯化合物与含有多孔无机氧化物的载体的氢化催化剂接触，选自元素周期表第VIA族和第VIII族的一种或多种金属在氢气存在下负载在载体上以通过含氧有机化合物的加氢脱氧产生烃油和蒸气状态的水，不溶性含氯化合物变成水溶性含氯化合物; 第二步骤，其中第一步骤的反应产物中的水保持蒸气状态，并使第一步的反应产物与常压下的沸点为100的含氮布朗斯台德碱化合物接触 ℃或更低，并且是水溶性的，以获得待处理的产品; 以及第三步骤，其中待处理的产品被冷却到不高于蒸汽状态的水液化的温度的温度，以形成含有水溶性含氯化合物和含氮布朗斯台德碱的水相化合物，然后将水相与待处理的油分离，得到含有烃油的产物油。

4. 发明申请

US20110219677A1 PROCESS FOR PRODUCING AVIATION FUEL BASE OIL 有权
标题翻译：生产航空燃料基油的工艺
公开(公告)号：US20110219677A1
公开(公告)日：2011-09-15
申请号：US13130172
申请日：2009-11-19
申请人： Akira Koyama , Tatsuo Hamamatsu , Yasutoshi Iguchi , Hideshi Iki
发明人： Akira Koyama , Tatsuo Hamamatsu , Yasutoshi Iguchi , Hideshi Iki
IPC分类号： C10L1/00
CPC分类号： C10L1/04 , C10G3/00 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/30 , C10G2400/08 , Y02P30/20
摘要： The present invention provides a process of producing an aviation fuel base oil having excellent combustibility, oxidation stability and life cycle characteristics, hydrotreating in the presence of hydrogen a feedstock comprising an oxygen-containing hydrocarbon compound originating from an animal or vegetable fat (preferably an animal or vegetable fat that contains fatty acids each having 10 to 14 carbon atoms in the fatty acid carbon chain in the total amount of 60 percent by mass or more) and a sulfur-containing hydrocarbon compound. The present invention also provides a process for producing an aviation fuel base oil by blending such an aviation fuel base oil and an aviation fuel base oil produced by refining crude oil.
摘要翻译：本发明提供一种生产具有优异的燃烧性，氧化稳定性和寿命特性的航空燃料基础油的方法，在氢气存在下加氢处理包含源自动物或植物脂肪（优选动物）的含氧烃化合物或含有脂肪酸碳链中各自具有10〜14个碳原子的脂肪酸的植物油，总量为60质量％以上）和含硫烃化合物。本发明还提供了一种通过混合这种航空燃料基础油和通过精炼原油生产的航空燃料基础油来生产航空燃料基础油的方法。

5. 发明申请

US20090126264A1 Fuel Composition 有权
标题翻译：燃料组成
公开(公告)号：US20090126264A1
公开(公告)日：2009-05-21
申请号：US12294110
申请日：2007-02-22
申请人： Masanori Hirose , Hideshi Iki
发明人： Masanori Hirose , Hideshi Iki
IPC分类号： C10L1/18
CPC分类号： C10G47/16 , C10G2/00 , C10G45/08 , C10G65/14 , C10G69/04 , C10G2300/1022 , C10G2300/1096 , C10G2300/301 , C10L1/04
摘要： The present invention provides a fuel composition capable of suppressing reduction of fuel consumption, maintaining the excellent exhaust gas properties of a Fischer-Tropsch synthetic oil. The fuel composition comprises a Fischer-Tropsch synthetic oil and a petroleum-based hydrocarbon mixture A having the following properties (1) to (5) in an amount of 10 to 30 percent by volume on the basis of the total mass of the composition: (1) 15° C. density: 800 Kg/cm3 or greater and 900 Kg/m3 or less; (2) 10 volume % distillation temperature (T10): 150° C. or higher and 200° C. or lower; (3) 97 volume % distillation temperature (T97): 270° C. or lower; (4) aromatic content: 40 percent by volume or more and 70 percent by volume or less; and (5) sulfur content: 30 ppm by mass or less.
摘要翻译：本发明提供能够抑制燃料消耗的降低，维持费 - 托合成油优异的废气性能的燃料组合物。燃料组合物包含基于组合物的总质量的10至30体积％的具有以下性质（1）至（5）的费 - 托合成油和石油基烃混合物A：（1）15℃密度：800Kg / cm 3以上900kg / m 3以下; （2）10体积％蒸馏温度（T10）：150℃以上且200℃以下; （3）97体积％蒸馏温度（T97）：270℃以下; （4）芳香族含量：40体积％以上且70体积％以下; 和（5）硫含量：30质量ppm以下。

6. 发明授权

US07429550B2 Hydrogenation catalyst for hydrocarbon oil and process for hydrogenation using the catalyst 有权
标题翻译：用于烃油的氢化催化剂和使用该催化剂的氢化方法
公开(公告)号：US07429550B2
公开(公告)日：2008-09-30
申请号：US11567374
申请日：2006-12-06
申请人： Hideshi Iki , Kazuaki Hayasaka , Kazuo Fukazawa
发明人： Hideshi Iki , Kazuaki Hayasaka , Kazuo Fukazawa
IPC分类号： B01J21/12 , B01J27/18 , C10G47/18 , C10G47/20 , C10G45/12
CPC分类号： C10G49/04 , B01J23/85 , B01J23/882 , B01J23/883 , B01J27/182 , B01J27/19 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J37/0009 , B01J37/0203 , B01J37/03 , C10G49/08
摘要： A hydrogenation catalyst for a hydrocarbon oil, includes an inorganic porous support composed of at least the oxides of aluminum, phosphorus, and silicon, and supporting at least one active metal selected from the metals of Group 8 of the periodic table, at least one active metal selected from the metals of Group 6 of the periodic table, and phosphorus, the phosphorus chemical shift value of the inorganic support determined by 31P-CPMAS-NMR having the peak within the range of 0 to −20 ppm. The catalyst can achieve an extremely high level of hydrogenation wherein the hydrocarbon is decreased in sulfur content to 10 ppm by mass or less and in nitrogen content to 3 ppm by mass or less.
摘要翻译：用于烃油的氢化催化剂包括至少由铝，磷和硅的氧化物组成的无机多孔载体，并且支持选自元素周期表第8族金属中的至少一种活性金属，至少一种活性选自元素周期表第6族金属的金属和磷，由POD-NMR-NMR确定的无机载体的磷化学位移值，峰值在0至 - 20 ppm。催化剂可以实现极高的氢化水平，其中烃的含量降低到10质量ppm以下，氮含量降低到3质量ppm以下。

7. 发明授权

US09464250B2 Process for producing aviation fuel base oil 有权
标题翻译：生产航空燃料基油的工艺
公开(公告)号：US09464250B2
公开(公告)日：2016-10-11
申请号：US13130172
申请日：2009-11-19
申请人： Akira Koyama , Tatsuo Hamamatsu , Yasutoshi Iguchi , Hideshi Iki
发明人： Akira Koyama , Tatsuo Hamamatsu , Yasutoshi Iguchi , Hideshi Iki
IPC分类号： C10L1/00 , C10L1/04 , C10G3/00
CPC分类号： C10L1/04 , C10G3/00 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/30 , C10G2400/08 , Y02P30/20
摘要： The present invention provides a process of producing an aviation fuel base oil having excellent combustibility, oxidation stability and life cycle characteristics, hydrotreating in the presence of hydrogen a feedstock comprising an oxygen-containing hydrocarbon compound originating from an animal or vegetable fat (preferably an animal or vegetable fat that contains fatty acids each having 10 to 14 carbon atoms in the fatty acid carbon chain in the total amount of 60 percent by mass or more) and a sulfur-containing hydrocarbon compound. The present invention also provides a process for producing an aviation fuel base oil by blending such an aviation fuel base oil and an aviation fuel base oil produced by refining crude oil.
摘要翻译：本发明提供一种生产具有优异的燃烧性，氧化稳定性和寿命特性的航空燃料基础油的方法，在氢气存在下加氢处理包含源自动物或植物脂肪（优选动物）的含氧烃化合物或含有脂肪酸碳链中各自具有10〜14个碳原子的脂肪酸的植物油，总量为60质量％以上）和含硫烃化合物。本发明还提供了一种通过混合这种航空燃料基础油和通过精炼原油生产的航空燃料基础油来生产航空燃料基础油的方法。

8. 发明授权

US08784645B2 Process for producing hydrocarbon oil 失效
标题翻译：烃油生产工艺
公开(公告)号：US08784645B2
公开(公告)日：2014-07-22
申请号：US13119333
申请日：2009-09-16
申请人： Yasutoshi Iguchi , Tatsuo Hamamatsu , Hideki Ono , Akira Koyama , Hideshi Iki
发明人： Yasutoshi Iguchi , Tatsuo Hamamatsu , Hideki Ono , Akira Koyama , Hideshi Iki
IPC分类号： C10G3/00 , C10G65/02 , C10G65/04
CPC分类号： C10G3/46 , C10G3/49 , C10G3/50 , C10G45/04 , C10G45/06 , C10G45/08 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/207 , C10G2300/4006 , C10G2300/4012 , C10G2300/4081 , C10G2300/70 , C10G2400/02 , C10G2400/04 , C10G2400/08 , Y02P30/20
摘要： The method for manufacturing a hydrocarbon oil of the present invention comprises a first step wherein a plurality of reaction zones filled with a specific catalyst is disposed in series and a feedstock oil containing an oxygen-containing hydrocarbon compound derived from an animal or vegetable oil is supplied and hydrotreated under the conditions of a hydrogen pressure of 1 MPa or more and 10 MPa or less in each of the reaction zones; and a second step wherein hydrogen, hydrogen sulfide, carbon dioxide and water are removed from a product to be treated obtained in the first step to obtain a hydrocarbon oil. Among the plurality of reaction zones, the inlet temperature of the reaction zone disposed on the most upstream side is 150° C. or more and 250° C. or less, the inlet temperature of the second most upstream reaction zone or below is equal to or higher than the condensation temperature of water, and the outlet temperature of the reaction zone disposed on the most downstream side is 260° C. or more and 360° C. or less. The feedstock oil comprises a recycled oil containing a specific amount of a part of the hydrocarbon oil obtained in the second step and a specific amount of a sulfur-containing hydrocarbon compound.
摘要翻译：本发明的烃油的制造方法包括第一步骤，其中填充有特定催化剂的多个反应区域串联设置，并且供给含有源自动物或植物油的含氧烃化合物的原料油并在每个反应区中在氢气压力为1MPa以上且10MPa以下的条件下进行加氢处理; 第二步骤，从第一步骤中得到的待处理产物中除去氢，硫化氢，二氧化碳和水，得到烃油。在多个反应区域中，设置在最上游侧的反应区域的入口温度为150℃以上且250℃以下，第二上游反应区域以下的入口温度等于或高于水的冷凝温度，并且设置在最下游侧的反应区的出口温度为260℃以上且360℃以下。原料油包含含有特定量的第二步获得的一部分烃油的再循环油和特定量的含硫烃化合物。

9. 发明授权

US08551325B2 Process for producing hydrocarbon oil 失效
标题翻译：烃油生产工艺
公开(公告)号：US08551325B2
公开(公告)日：2013-10-08
申请号：US13119310
申请日：2009-09-16
申请人： Tatsuo Hamamatsu , Hideki Ono , Yasutoshi Iguchi , Hideshi Iki , Yoshihiko Kinoshita
发明人： Tatsuo Hamamatsu , Hideki Ono , Yasutoshi Iguchi , Hideshi Iki , Yoshihiko Kinoshita
IPC分类号： C10G45/02 , C07C1/20
CPC分类号： C10G45/02 , C10G3/46 , C10G3/49 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/4018 , Y02P30/20
摘要： A method for manufacturing a hydrocarbon oil, comprising: a first step wherein a feedstock oil containing an oxygen-containing organic compound and a water-insoluble chlorine-containing compound is brought into contact with a hydrogenation catalyst comprising a support containing a porous inorganic oxide and one or more metals selected from Group VIA and Group VIII of the periodic table supported on the support in the presence of hydrogen to generate a hydrocarbon oil and water in a vapor state by the hydrodeoxygenation of an oxygen-containing organic compound and convert the water-insoluble chlorine-containing compound into a water-soluble chlorine-containing compound; a second step wherein the water in the reaction product of the first step is maintained in a vapor state and the reaction product of the first step is brought into contact with a nitrogen-containing Brønsted base compound which has a boiling point at normal pressure of 100° C. or less and is water-soluble to obtain a product to be treated; and a third step wherein the product to be treated is cooled to a temperature not higher than the temperature at which water in a vapor state is liquefied to form an aqueous phase containing a water-soluble chlorine-containing compound and a nitrogen-containing Brønsted base compound and then separate the aqueous phase from an oil to be treated to obtain a product oil containing a hydrocarbon oil.
摘要翻译：一种烃油的制造方法，包括：第一工序，其中含有含氧有机化合物的原料油和不溶于水的含氯化合物与含有多孔无机氧化物的载体的氢化催化剂接触，选自元素周期表第VIA族和第VIII族的一种或多种金属在氢气存在下负载在载体上以通过含氧有机化合物的加氢脱氧产生烃油和蒸气状态的水，不溶性含氯化合物变成水溶性含氯化合物; 第二步骤，其中第一步骤的反应产物中的水保持蒸气状态，并使第一步的反应产物与常压下的沸点为100的含氮布朗斯台德碱化合物接触 ℃或更低，并且是水溶性的，以获得待处理的产品; 以及第三步骤，其中待处理的产品被冷却到不高于蒸汽状态的水液化的温度的温度，以形成含有水溶性含氯化合物和含氮布朗斯台德碱化合物，然后将水相与待处理的油分离，得到含有烃油的产物油。

10. 发明授权

US08303805B2 Process for producing gasoline base and gasoline 有权
标题翻译：生产汽油基油和汽油的工艺
公开(公告)号：US08303805B2
公开(公告)日：2012-11-06
申请号：US12681787
申请日：2008-10-06
申请人： Shigeto Hatanaka , Koji Shimada , Hideshi Iki
发明人： Shigeto Hatanaka , Koji Shimada , Hideshi Iki
IPC分类号： C10G45/06 , C10G45/08 , C10G65/02
CPC分类号： C10G11/00 , C10G45/02 , C10G45/04 , C10G65/04 , C10G69/04 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2400/02 , C10L1/06
摘要： The production process of the invention comprises a first step of hydrodesulfurizing of catalytically-cracked gasoline so as to result in an olefin hydrogenation rate of no greater than 25 mol % in the catalytically-cracked gasoline, a total sulfur content of no greater than 20 ppm by weight based on the product oil weight, a sulfur content derived from thiophenes and benzothiophenes of no greater than 5 ppm by weight and a sulfur content derived from thiacyclopentanes of no greater than 0.1 ppm by weight, and a second step of further hydrodesulfurizing of the product oil obtained by the first step so as to result in a total of no greater than 30 mol % for the olefin hydrogenation rate in the first step and the olefin hydrogenation rate in the second step, a total sulfur content of no greater than 10 ppm by weight based on the product oil weight, and a sulfur content derived from thiols of no greater than 5 ppm by weight.
摘要翻译：本发明的制造方法包括催化裂化汽油的加氢脱硫的第一步骤，使催化裂化汽油中的烯烃氢化率不大于25mol％，总硫含量不大于20ppm 基于产品油重量，来自噻吩和苯并噻吩的硫含量不大于5ppm重量，硫代环戊烷的硫含量不大于0.1ppm重量，第二步是进一步加氢脱硫通过第一步获得的产物油，以使第一步中的烯烃氢化速率和第二步中的烯烃氢化速率总共不大于30mol％，总硫含量不大于10ppm 基于产品油重量，和硫醇的硫含量不大于5重量ppm。

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