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    • 1. 发明授权
    • Ink compositions
    • 油墨组合物
    • US5587405A
    • 1996-12-24
    • US471449
    • 1995-06-06
    • Ban TanakaHiroki NiiKosaku YamadaHideo KushidaTakashi MiyaShuichi KoshioTadashi Hayakawa
    • Ban TanakaHiroki NiiKosaku YamadaHideo KushidaTakashi MiyaShuichi KoshioTadashi Hayakawa
    • B41M1/30B41M7/00C08F2/48C09D11/10C08F2/46
    • C09D11/101B41M1/30B41M7/0081Y10S260/38
    • A radiation-curable ink composition contains a vehicle mixture comprising: (A) at least one linear polyester oligomer and/or polymer substantially free of an acid group and free of a polymerizable double bond in a molecule, wherein 1 to 10 double bonds are pendent from the linear polyester chain, and/or mixture thereof, (B) at least one single double bond-containing carboxylic acid wherein the acid has at least one acid group, and/or carboxylic ester of the said acid, and/or carboxylic amide of the said acid, and/or mixture thereof, (C) a double bond-containing polycarboxylic ester, wherein 2 to 10 acid groups are present and at least 2 double bonds are pendent from the ester having 2 to 10 acid groups, (D) at least one double bond-containing fluorinated carboxylic ester, and/or block copolymer comprising a fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and/or block copolymer comprising a siloxane group-containing polymer segment and a (meth)acrylic polymer segment, and/or mixture thereof, (E) a double bond-containing carboxylic ester, having at least 2 double bonds and free of an acid group, provided that it is excluded from the above-mentioned ingredient (A), and (F) at least one single double bond-containing carboxylic ester and/or amide and/or imide free of an acid group, and/or mixture thereof, wherein the acid value of the vehicle mixture is from 5 to 100, is provided. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.
    • 可辐射固化油墨组合物含有载体混合物,其包含:(A)至少一种基本上不含酸基并且在分子中不含可聚合双键的直链聚酯低聚物和/或聚合物,其中1至10个双键是侧链 和/或其混合物,(B)至少一种含有至少一个酸基团的单双键的羧酸,和/或所述酸的羧酸酯和/或羧酸酰胺 的所述酸和/或其混合物,(C)含双键的多元羧酸酯,其中存在2至10个酸基团,并且至少2个双键从具有2至10个酸基团的酯(D )至少一种含双键的氟化羧酸酯和/或包含含氟烷基的聚合物链段和(甲基)丙烯酸类聚合物链段的嵌段共聚物,和/或包含含硅氧烷基团的聚合物链段和/ (甲基)丙烯酸酯 (E)具有至少2个双键并且不含酸基团的双键的羧酸酯,其不包括在上述成分(A)中,和 (F)至少一种含有单个含双键的羧酸酯和/或不含酸基团的酰胺和/或酰亚胺,和/或其混合物,其中车辆混合物的酸值为5至100。 油墨可用于在特定的热塑性产品上显示和装饰商品名称,设计,注释,条形码等,并且固化的油墨膜易于与碱性水溶液分离。
    • 2. 发明授权
    • Printed thermoplastic resin products and method for printing such
products
    • 印刷热塑性树脂产品及印刷方法
    • US5712022A
    • 1998-01-27
    • US488408
    • 1995-06-07
    • Ban TanakaHiroki NiiKosaku YamadaHideo KushidaTakashi MiyaShuichi KoshioTadashi Hayakawa
    • Ban TanakaHiroki NiiKosaku YamadaHideo KushidaTakashi MiyaShuichi KoshioTadashi Hayakawa
    • B41M1/30C09D11/10B32B27/00
    • C09D11/101B41M1/30Y10T428/1352Y10T428/24802Y10T428/3154Y10T428/31551Y10T428/31663Y10T428/31797Y10T428/31931Y10T428/31935
    • An easily regeneratable printed thermoplastic resin product is provided by printing it with a specific radiation-curable ink composition and curing the printed ink with radiation to form a cured ink film thereon. The ink composition comprises a vehicle mixture containing: (A) at least one linear polyester oligomer and/or polymer substantially free of an acid group and a polymerizable double bond on the linear polyester chain wherein 1 to 10 double bonds are pendent from the linear polyester chain, and/or mixture thereof, (B) at least one single double bond-containing carboxylic acid and/or ester and/or amide wherein the acid has at least one acid group, and/or mixture thereof, (C) a double bond-containing polycarboxylic ester wherein 2 to 10 acid groups are present and at least 2 double bonds are pendent from the carboxylic ester having 2 to 10 acid groups, (D) at least one double bond-containing fluorinated carboxylic ester, and/or block copolymer comprising a fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and/or block copolymer comprising a siloxane group-containing polymer segment and a (meth)acrylic polymer segment, and/or mixture thereof, (E) a double bond-containing carboxylic ester, having at least 2 double bonds and free of an acid group, provided that it is excluded from the above-mentioned ingredient (A), and (F) at least one single double bond-containing carboxylic ester and/or amide and/or imide free of an acid group, and/or mixture thereof, wherein the acid value of the vehicle mixture is from 5 to 100. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.
    • 通过用特定的可辐射固化油墨组合物印刷并通过辐射固化印刷油墨以在其上形成固化的油墨膜来提供易于再生的印刷热塑性树脂产品。 油墨组合物包含载体混合物,其包含:(A)至少一种线性聚酯链上基本上不含酸基团和可聚合双键的线性聚酯低聚物和/或聚合物,其中1至10个双键与直链聚酯 链和/或其混合物,(B)至少一种含单个双键的羧酸和/或酯和/或酰胺,其中酸具有至少一个酸基,和/或其混合物,(C)双 含有2〜10个酸基且至少2个双键与具有2〜10个酸基的羧酸酯侧基,(D)至少一个含双键的氟化羧酸酯和/或嵌段 包含含氟基烷基的聚合物链段和(甲基)丙烯酸类聚合物链段的共聚物和/或包含含硅氧烷基团的聚合物链段和(甲基)丙烯酸类聚合物链段的嵌段共聚物和/或其混合物,(E) 一个双重的 具有至少2个双键且不含酸基团的含L键的羧酸酯,条件是其不包括在上述成分(A)中,和(F)至少一种含有单个双键的羧酸酯和 /或不含酸基的酰胺和/或酰亚胺,和/或其混合物,其中车辆混合物的酸值为5至100.油墨可用于显示和装饰商品名称,设计,说明注释,条 代码等,并且固化的油墨膜易于与碱性水溶液分离。