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    • 1. 发明授权
    • Polymerizable composition
    • 可聚合组合物
    • US08247471B2
    • 2012-08-21
    • US12725657
    • 2010-03-17
    • Hideki YarimizuHideki TokuiHiroto Minamisawa
    • Hideki YarimizuHideki TokuiHiroto Minamisawa
    • C08F20/10C08F4/76
    • C09D4/00A61K6/083A61K6/0835C09J4/00C08F220/00C08L33/04
    • To provide a dental adhesive composition which does not decrease preservation stability when reacting with acidity for acquiring dental adhesive property, even though using a filler having X-ray imaging property, and does not need the conventional mixing and kneading of two or more components, the dental adhesive composition includes (a) a (meth)acrylate compound having an acid group, and (b) aluminosilicate glass powder containing Sr and/or Ba and/or Ca, and the dental adhesive composition further includes a filler and (c) a photopolymerization catalyst, where the filler does not substantially make a neutralization reaction with the (meth)acrylate compound having an acid group as the (a) component because a filler content is 15% by weight or less in terms of oxide of Al2O3, and those coexist is one.
    • 为了提供一种牙科粘合剂组合物,即使使用具有X射线成像特性的填料,也不需要常规的两种或多种组分的混合和捏合,即使与用于获得牙科粘合性的酸度反应而不会降低保存稳定性, 牙科粘合剂组合物包含(a)具有酸基的(甲基)丙烯酸酯化合物,和(b)含有Sr和/或Ba和/或Ca的铝硅酸盐玻璃粉末,并且所述牙科粘合剂组合物还包含填料和(c) 光聚合催化剂,其中填料与具有酸基的(甲基)丙烯酸酯化合物作为(a)成分基本上不进行中和反应,因为填料含量以Al 2 O 3的氧化物计为15重量%以下, 共存是一个。
    • 2. 发明授权
    • Polymerizable composition
    • 可聚合组合物
    • US08247470B2
    • 2012-08-21
    • US12728711
    • 2010-03-22
    • Hideki YarimizuHideki TokuiHiroto Minamisawa
    • Hideki YarimizuHideki TokuiHiroto Minamisawa
    • A61K6/083C08K3/40
    • C09J4/06A61K6/083A61K6/0835A61K6/09C08F4/40C08L33/00C08L75/16
    • To provide a polymerizable composition having more excellent preservation stability of pastes than a conventional composition using a combination of a copper compound, cumene hydroperoxide, and N-acetylthiourea, and having a polymerization curing time which does not change with time, that is, does not delay or quicken from a time set for a product even though the composition is stored, the polymerizable composition includes a first paste and a second paste, wherein the first paste includes a polymer of α-β unsaturated monocarboxylic acid or α-β unsaturated dicarboxylic acid, water, and a hydroperoxide as a peroxide, and the second paste includes a (meth)acrylate compound not having an acid group, fluoroaluminosilicate glass powder, a thiourea derivative as a reducing material, and a vanadium compound as a polumerization accelerator.
    • 为了提供具有比铜化合物,氢过氧化枯烯和N-乙酰基硫脲组合的常规组合物更优异的糊剂保存稳定性的聚合性组合物,并且具有不随时间变化的聚合固化时间,即不 延迟或加速,即使存在组合物,可聚合组合物包括第一糊剂和第二糊剂,其中第一糊剂包括α-淀粉的聚合物; 不饱和一元羧酸或α- 不饱和二羧酸,水和作为过氧化物的氢过氧化物,第二糊剂包括不具有酸基的(甲基)丙烯酸酯化合物,氟铝硅酸盐玻璃粉末,作为还原剂的硫脲衍生物和作为聚合促进剂的钒化合物 。
    • 4. 发明申请
    • TOOTH-ADHESIVE COMPOSITION
    • 牙膏组合物
    • US20110046256A1
    • 2011-02-24
    • US12835216
    • 2010-07-13
    • Hideki YarimizuHideki TokuiSayaka Nagao
    • Hideki YarimizuHideki TokuiSayaka Nagao
    • A61K6/00
    • A61K6/0023C08L33/10
    • To provide a tooth-adhesive composition not causing lowering of preservation stability due to a reaction between a filler having a X-ray imaging property and an acid component in the composition, and not having necessity for mixing and kneading of components separated in two or more packages unlike a conventional case, the tooth-adhesive composition includes (a) a (meth)acrylate compound having an acid group, (b) a filler which is an alumino-silicate glass powder including Sr and/or Ba and/or Ca, and (c) a photopolymerization catalyst, where the filler does not substantially react with the (meth)acrylate compound having an acid group, which is the a) component, by making Al2O3 content to be 15% or less by weight in terms of oxides, and these (a), (b), and (c) components co-exist in one pack.
    • 为了提供一种牙膏组合物,不会由于在组合物中具有X射线成像特性的填料和酸成分之间的反应而导致保存稳定性降低,并且不需要混合和捏合在两个或更多个中分离的组分 所述牙胶组合物包含(a)具有酸基的(甲基)丙烯酸酯化合物,(b)作为包含Sr和/或Ba和/或Ca的铝硅酸盐玻璃粉末的填料, 和(c)光聚合催化剂,其中通过使氧化铝的Al 2 O 3含量为15重量%以下,填充剂基本上不与具有酸基团的(甲基)丙烯酸酯化合物即a)成分反应 ,这些(a),(b)和(c)成分共存在一个包装中。
    • 5. 发明申请
    • DENTAL CEMENT
    • 牙科水泥
    • US20080015279A1
    • 2008-01-17
    • US11774759
    • 2007-07-09
    • Hideki TOKUIHideki YarimizuDaisuke OtaTakuya MoriHisashi Nakaseko
    • Hideki TOKUIHideki YarimizuDaisuke OtaTakuya MoriHisashi Nakaseko
    • A61K6/083
    • A61K6/083C08L33/00C08L43/02
    • A dental cement comprises a first paste including a (meth)acrylate monomer having an acid group, the (meth)acrylate monomer not having an acid group, having two or less of hydroxyl groups and/or amino groups and having a molecular weight of 160 or more, the filler having a specific average particle size and being inactive to the (meth)acrylate monomer having an acid group, and the amine compound as a accelerator for the undermentioned polymerizing catalyst; and the second paste including a (meth)acrylate monomer not having an acid group, having two or less of hydroxyl groups and/or amino groups and having a molecular weight of 160 or more, a filler having a specific particle size, and an organic aromatic compound having at least one —SO2— group and the peroxide as a polymerizing catalyst, thereby providing a dental cement large flexural strength, adhesiveness to dentin, small hygroscopic expansion, and low solubility.
    • 牙科水泥包括含有具有酸基的(甲基)丙烯酸酯单体的第一糊剂,不具有酸基的(甲基)丙烯酸酯单体,具有两个或多个羟基和/或氨基并且分子量为160 或更多,具有特定平均粒径并且对具有酸基的(甲基)丙烯酸酯单体无活性的填料和作为下述聚合催化剂的促进剂的胺化合物; 所述第二糊剂包含不具有酸基的(甲基)丙烯酸酯单体,具有2个以下羟基和/或氨基,分子量为160以上,具有特定粒径的填料和有机物 具有至少一个-SO 2 - 基的芳族化合物和作为聚合催化剂的过氧化物,从而提供牙科粘合剂大的弯曲强度,对牙本质的粘附性,小吸湿膨胀和低溶解度。
    • 6. 发明授权
    • Seat reclining apparatus
    • 座椅斜倚装置
    • US07255398B2
    • 2007-08-14
    • US11115878
    • 2005-04-27
    • Hideki TokuiAkira Nemoto
    • Hideki TokuiAkira Nemoto
    • B60N2/02
    • B60N2/2358B60N2/20B60N2/2356B60N2/2362B60N2205/50
    • A seat reclining apparatus is provided with a neutral position returning means which holds a link lever at a forward reclining operating position, and releases the holding of the link lever in the case that a seat back is shifted from a forward reclined position side to a neutral position within a reclining range. The neutral position returning means shifts a cam plate by a spring in such a manner as to hole the position of the link lever at a lever rotating position while the link lever rotates a releasing lever fixed to a center shaft of a reclining lock mechanism together therewith so as to release a lock of the reclining lock mechanism, and shifts the cam plate to an original position against the spring by a cam releasing means so as to return the link lever to an original position, in the case that the forward reclining seat back 3 is shifted to the neutral position.
    • 座椅倾斜装置设置有中立位置返回装置,该中立位置返回装置在前倾斜操作位置处保持连杆,并且在座椅靠背从前倾斜位置侧移动到中立位置的情况下释放连杆的保持 位于倾斜范围内。 中立位置返回装置通过弹簧使凸轮板移动,使得连杆在位于杆旋转位置的位置开孔,同时连杆将旋转固定在倾斜锁定机构的中心轴上的释放杆一起旋转 以便释放倾斜锁定机构的锁定,并且通过凸轮释放装置将凸轮板移动到原来的位置以使弹簧恢复到初始位置,在前倾斜座椅靠背 3移动到中立位置。
    • 7. 发明申请
    • INITIATORS IN TWO COMPONENTS, AND POLYMERIZABLE COMPOSITION USING THE SAME
    • 两种组分中的引发剂和使用该组合物的可聚合组合物
    • US20100204421A1
    • 2010-08-12
    • US12704883
    • 2010-02-12
    • Hideki YarimizuHideki TokuiHisashi Nakaseko
    • Hideki YarimizuHideki TokuiHisashi Nakaseko
    • C08F20/10C09K3/00
    • C08F4/28A61K6/083C08F4/40C08L33/04
    • To provide initiators in two components having no discoloring after polymerization and excellent polymerization-curability under the existence of water, and provide a polymerizable composition using the initiators in two components. The initiators in two components is for polymerizing and curing a (meth)acrylate compound, and the initiator includes (a) a peroxide being compatible or soluble with water, (b) an aromatic sulfinic acid compound, (c) a tert-amine compound, and (d) water. The polymerizable composition uses the initiators in two components. Particularly, preferably, the polymerizable composition includes a first component and a second component. The first component comprising (a) a peroxide being compatible or soluble with water, and a (meth)acrylate compound, and the second component includes (b) an aromatic sulfinic acid compound, (c) a tert-amine compound, and (d) water.
    • 为了在聚合后没有变色的两个组分提供引发剂,并且在水存在下具有优异的聚合固化性,并且使用两种组分中的引发剂提供可聚合组合物。 两种组分中的引发剂用于聚合和固化(甲基)丙烯酸酯化合物,并且引发剂包括(a)与水相容或可溶的过氧化物,(b)芳香族亚磺酸化合物,(c)叔胺化合物 ,(d)水。 可聚合组合物使用两种组分的引发剂。 特别地,优选地,可聚合组合物包括第一组分和第二组分。 第一组分包含(a)与水相容或可溶的过氧化物和(甲基)丙烯酸酯化合物,和第二组分包括(b)芳香族亚磺酸化合物,(c)叔胺化合物和(d ) 水。
    • 8. 发明申请
    • POLYMERIZABLE COMPOSITION
    • 可聚合组合物
    • US20100240797A1
    • 2010-09-23
    • US12725657
    • 2010-03-17
    • Hideki YARIMIZUHideki TokuiHiroto Minamisawa
    • Hideki YARIMIZUHideki TokuiHiroto Minamisawa
    • A61K6/00
    • C09D4/00A61K6/083A61K6/0835C09J4/00C08F220/00C08L33/04
    • To provide a dental adhesive composition which does not decrease preservation stability when reacting with acidity for acquiring dental adhesive property, even though using a filler having X-ray imaging property, and does not need the conventional mixing and kneading of two or more components, the dental adhesive composition includes (a) a (meth)acrylate compound having an acid group, and (b) aluminosilicate glass powder containing Sr and/or Ba and/or Ca, and the dental adhesive composition further includes a filler and (c) a photopolymerization catalyst, where the filler does not substantially make a neutralization reaction with the (meth)acrylate compound having an acid group as the (a) component because a filler content is 15% by weight or less in terms of oxide of Al2O3, and those coexist is one.
    • 为了提供一种牙科粘合剂组合物,即使使用具有X射线成像特性的填料,也不需要常规的两种或多种组分的混合和捏合,即使与用于获得牙科粘合性的酸度反应而不会降低保存稳定性, 牙科粘合剂组合物包含(a)具有酸基的(甲基)丙烯酸酯化合物,和(b)含有Sr和/或Ba和/或Ca的铝硅酸盐玻璃粉末,并且所述牙科粘合剂组合物还包含填料和(c) 光聚合催化剂,其中填料与具有酸基的(甲基)丙烯酸酯化合物作为(a)成分基本上不进行中和反应,因为填料含量以Al 2 O 3的氧化物计为15重量%以下, 共存是一个。
    • 9. 发明申请
    • Seat reclining apparatus
    • 座椅斜倚装置
    • US20060091712A1
    • 2006-05-04
    • US11115878
    • 2005-04-27
    • Hideki TokuiAkira Nemoto
    • Hideki TokuiAkira Nemoto
    • B60N2/02
    • B60N2/2358B60N2/20B60N2/2356B60N2/2362B60N2205/50
    • A seat reclining apparatus is provided with a neutral position returning means which holds a link lever at a forward reclining operating position, and releases the holding of the link lever in the case that a seat back is shifted from a forward reclined position side to a neutral position within a reclining range. The neutral position returning means shifts a cam plate by a spring in such a manner as to hole the position of the link lever at a lever rotating position while the link lever rotates a releasing lever fixed to a center shaft of a reclining lock mechanism together therewith so as to release a lock of the reclining lock mechanism, and shifts the cam plate to an original position against the spring by a cam releasing means so as to return the link lever to an original position, in the case that the forward reclining seat back 3 is shifted to the neutral position.
    • 座椅倾斜装置设置有中立位置返回装置,该中立位置返回装置在前倾斜操作位置处保持连杆,并且在座椅靠背从前倾斜位置侧移动到中立位置的情况下释放连杆的保持 位于倾斜范围内。 中立位置返回装置通过弹簧使凸轮板移动,使得连杆在位于杆旋转位置的位置开孔,同时连杆将旋转固定在倾斜锁定机构的中心轴上的释放杆一起旋转 以便释放倾斜锁定机构的锁定,并且通过凸轮释放装置将凸轮板移动到原来的位置以使弹簧恢复到初始位置,在前倾斜座椅靠背 3移动到中立位置。
    • 10. 发明申请
    • POLYMERIZABLE COMPOSITION
    • 可聚合组合物
    • US20100249266A1
    • 2010-09-30
    • US12728711
    • 2010-03-22
    • Hideki YarimizuHideki TokuiHiroto Minamisawa
    • Hideki YarimizuHideki TokuiHiroto Minamisawa
    • A61L24/06
    • C09J4/06A61K6/083A61K6/0835A61K6/09C08F4/40C08L33/00C08L75/16
    • To provide a polymerizable composition having more excellent preservation stability of pastes than a conventional composition using a combination of a copper compound, cumene hydroperoxide, and N-acetylthiourea, and having a polymerization curing time which does not change with time, that is, does not delay or quicken from a time set for a product even though the composition is stored, the polymerizable composition includes a first paste and a second paste, wherein the first paste includes a polymer of α-β unsaturated monocarboxylic acid or α-β unsaturated dicarboxylic acid, water, and a hydroperoxide as a peroxide, and the second paste includes a (meth)acrylate compound not having an acid group, fluoroaluminosilicate glass powder, a thiourea derivative as a reducing material, and a vanadium compound as a polumerization accelerator.
    • 为了提供具有比铜化合物,氢过氧化枯烯和N-乙酰基硫脲组合的常规组合物更优异的糊剂保存稳定性的聚合性组合物,并且具有不随时间变化的聚合固化时间,即不 延迟或加速,即使存在组合物,可聚合组合物包括第一糊剂和第二糊剂,其中第一糊剂包括α-淀粉的聚合物; 不饱和一元羧酸或α- 不饱和二羧酸,水和作为过氧化物的氢过氧化物,第二糊剂包括不具有酸基的(甲基)丙烯酸酯化合物,氟铝硅酸盐玻璃粉末,作为还原剂的硫脲衍生物和作为聚合促进剂的钒化合物 。