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    • 3. 发明授权
    • Low hydrogen overvoltage cathode and process for the production thereof
    • 低氢过电压阴极及其生产方法
    • US5948223A
    • 1999-09-07
    • US733420
    • 1996-10-18
    • Hideharu HorikoshiKazumasa SuetsuguTakashi SakakiKanji Yoshimitsu
    • Hideharu HorikoshiKazumasa SuetsuguTakashi SakakiKanji Yoshimitsu
    • C25B11/04C25B11/06C25B11/00
    • C25B11/0478Y10S420/90
    • A cathode of sufficiently low hydrogen overvoltage is provided which is useful in electrolysis of water or of an aqueous alkali metal chloride solution such as a sodium chloride solution. A process for producing the cathode is also provided. The low hydrogen overvoltage cathode has an electroconductive base material coated with an alloy layer containing nickel and molybdenum, the alloy layer containing the nickel at a content ranging from 35 to 90% by weight and the molybdenum at a content ranging from 10 to 65% by weight. The alloy laser has an X-ray diffraction (CuK.alpha. line) pattern with a main peak at an angle ranging from 42 to 45.degree. with a peak half width ranging from 0.4 to 7.degree.. One process for producing the low hydrogen overvoltage cathode of the present invention involves plating an electroconductive base material by an arc discharge type ion plating method. Another process for producing the low hydrogen overvoltage cathode of the present invention involves co-electrodepositing nickel and molybdenum onto an electroconductive base material in a plating bath.
    • 提供足够低的氢过电压的阴极,其可用于电解水或碱金属氯化物水溶液如氯化钠溶液。 还提供了一种生产阴极的方法。 低氢过电压阴极具有涂覆有含有镍和钼的合金层的导电基材,合金层含有含量范围为35-90%重量的镍,含量范围为10-65%的钼由 重量。 合金激光器具有X射线衍射(CuKα线)图案,主峰的角度范围为42至45°,峰半宽度范围为0.4至7°。 制造本发明的低氢过电压阴极的一个方法包括通过电弧放电型离子镀法镀覆导电基材。 制造本发明的低氢过电压阴极的另一种方法包括将镍和钼共同电沉积在镀浴中的导电基材上。