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    • 1. 发明申请
    • REFERENCE ELECTRODE HAVING A FLOWING LIQUID JUNCTION AND FILTER MEMBERS
    • 具有流动液体接头和过滤器构件的参考电极
    • US20120097552A1
    • 2012-04-26
    • US13284051
    • 2011-10-28
    • Scott T. BroadleyHerbert R. SilvermanTa-Yung ChenSteven R. Ragsdale
    • Scott T. BroadleyHerbert R. SilvermanTa-Yung ChenSteven R. Ragsdale
    • G01N27/30B82Y99/00
    • C25B15/00C25F7/00G01N27/30G01N27/301G01N27/401
    • A flowing junction reference electrode comprising a liquid junction member matched with a filter. The junction member and the filter are situated between a reference electrolyte solution and a sample solution. An array of nanochannels spans the junction member and provides fluid communication between the electrolyte solution and the sample solution. The filter is configured to allow a greater flux of electrolyte than that associated with the junction member. Preferably, the number of pores is greater than the number of nanochannels. The filter is preferably configured to have pores with an inner diameter that is the same or less than the inner diameter of the nanochannels. In some embodiment, the resistance of the filter is made lower relative to the resistance of the junction member by selecting suitable length, number, and inner diameter size for the pores of the filter relative to the nanochannels of the junction member.
    • 一种流动接合参考电极,包括与过滤器配合的液体接合部件。 接合构件和过滤器位于参考电解质溶液和样品溶液之间。 纳米通道阵列跨越接合部件并提供电解质溶液和样品溶液之间的流体连通。 过滤器被配置为允许比与接合部件相关联的更大的电解质通量。 优选地,孔的数量大于纳米通道的数量。 过滤器优选地构造成具有内径等于或小于纳米通道的内径的孔。 在一些实施例中,通过相对于接合部件的纳米通道选择合适的过滤器的孔的长度,数量和内径尺寸,使得过滤器的电阻相对于连接部件的电阻较低。