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1. 发明授权

US08765024B2 Functionalized carbon nanotubes exhibiting enhanced solubility and methods of making 有权
标题翻译：显示增强溶解度的功能化碳纳米管和制备方法
公开(公告)号：US08765024B2
公开(公告)日：2014-07-01
申请号：US13330616
申请日：2011-12-19
申请人： Henning Richter , Ramesh Sivarajan
发明人： Henning Richter , Ramesh Sivarajan
IPC分类号： H01B1/06 , H01B1/24 , C01B31/02 , B82Y40/00 , B82Y30/00
CPC分类号： C09K5/14 , B82Y30/00 , B82Y40/00 , C01B32/174 , H01B1/12
摘要： Functionalized carbon nanotubes and dispersions containing functionalized carbon nanotubes are provided. Exemplary functionalized carbon nanotubes include optionally substituted indene-based moieties. Methods of making functionalized carbon nanotubes and dispersions containing functionalized carbon nanotubes are provided. Methods of making conductive carbon nanotube dispersions, including films, are provided. Such methods include heating carbon nanotubes in a solvent in the absence of externally applied energy, to obtain an adduct that includes the solvent moiety bound to the carbon nanotube. Where the solvent includes an indene-based compound, the carbon nanotube thus prepared includes optionally indene-based moieties bound to the carbon nanotubes.
摘要翻译：提供功能化的碳纳米管和含有官能化碳纳米管的分散体。示例性官能化碳纳米管包括任选取代的基于茚的部分。提供制备官能化碳纳米管和含有官能化碳纳米管的分散体的方法。提供制造导电性碳纳米管分散体（包括膜）的方法。这样的方法包括在没有外部施加的能量的情况下在溶剂中加热碳纳米管，以获得包括结合到碳纳米管的溶剂部分的加合物。当溶剂包括基于茚的化合物时，如此制备的碳纳米管包括任选的与碳纳米管结合的基于茚的部分。

2. 发明授权

US08715606B2 Organic photovoltaic devices comprising fullerenes and derivatives thereof and improved methods of making fullerene derivatives 有权
标题翻译：包含富勒烯及其衍生物的有机光伏器件和制备富勒烯衍生物的改进方法
公开(公告)号：US08715606B2
公开(公告)日：2014-05-06
申请号：US12340587
申请日：2008-12-19
申请人： Darin W. Laird , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada, II
发明人： Darin W. Laird , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada, II
IPC分类号： C01B31/02
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08G2261/3223 , C08G2261/91 , C08L65/00 , H01L51/0036 , Y02E10/549 , Y02P70/521
摘要： Improved methods of fullerene derivative production including use of less solvent, or elimination of solvent, as well as use of shorter reaction times and higher reaction temperatures. Methods useful for production of bis-, tris-, tetra-, penta-, and hexa-fullerene derivatives. Indene is a preferred derivative. The derivatives used in active layers for solar cell applications.
摘要翻译：富勒烯衍生物生产的改进方法包括使用较少溶剂或消除溶剂，以及使用较短的反应时间和较高的反应温度。用于生产双 - ，三 - ，四 - ，五 - 和六 - 富勒烯衍生物的方法。茚是优选的衍生物。用于太阳能电池应用的有源层的衍生物。

3. 发明授权

US08217260B2 Organic photovoltaic devices comprising fullerenes and derivatives thereof 有权
标题翻译：含有富勒烯及其衍生物的有机光伏器件
公开(公告)号：US08217260B2
公开(公告)日：2012-07-10
申请号：US11743587
申请日：2007-05-02
申请人： Darin W. Laird , Reza Stegamat , Malika Daadi, legal representative , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
发明人： Darin W. Laird , Reza Stegamat , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
IPC分类号： H01L31/00
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y99/00 , H01G9/2004 , H01L31/0256 , H01L51/0036 , H01L51/0046 , H01L51/4253 , H01L2031/0344 , Y02E10/549 , Y02P70/521 , Y10S977/734 , Y10S977/735 , Y10S977/737 , Y10S977/738 , Y10S977/778 , Y10S977/784 , Y10S977/948
摘要： Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.
摘要翻译：包含作为p型材料的共聚聚合物如聚噻吩和区域性聚噻吩的活性层的光伏电池，以及至少一种富勒烯衍生物作为n型材料。富勒烯衍生物可以是C60，C70或C84。富勒烯也可以用茚基官能化。可以提高效率。

4. 发明申请

US20100132782A1 ORGANIC PHOTOVOLTAIC DEVICES COMPRISING FULLERENES AND DERIVATIVES THEREOF 有权
标题翻译：包含富勒烯及其衍生物的有机光伏器件
公开(公告)号：US20100132782A1
公开(公告)日：2010-06-03
申请号：US11743587
申请日：2007-05-02
申请人： Darin W. Laird , Reza Stegamat , Malika Daadi , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
发明人： Darin W. Laird , Reza Stegamat , Malika Daadi , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
IPC分类号： H01L31/00 , H01B1/12
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y99/00 , H01G9/2004 , H01L31/0256 , H01L51/0036 , H01L51/0046 , H01L51/4253 , H01L2031/0344 , Y02E10/549 , Y02P70/521 , Y10S977/734 , Y10S977/735 , Y10S977/737 , Y10S977/738 , Y10S977/778 , Y10S977/784 , Y10S977/948
摘要： Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.
摘要翻译：包含作为p型材料的共聚聚合物如聚噻吩和区域性聚噻吩的活性层的光伏电池，以及作为n型材料的至少一种富勒烯衍生物。富勒烯衍生物可以是C60，C70或C84。富勒烯也可以用茚基官能化。可以提高效率。

5. 发明申请

US20080069759A1 Direct liquid-phase collection and processing of fullerenic materials 有权
标题翻译：直接液相收集和处理富勒烯材料
公开(公告)号：US20080069759A1
公开(公告)日：2008-03-20
申请号：US11896405
申请日：2007-08-31
申请人： Henning Richter , Jack Howard
发明人： Henning Richter , Jack Howard
IPC分类号： C01B31/02 , B01D11/00
CPC分类号： C01B31/0233 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/162 , C01B32/174
摘要： An in-situ method and system of collecting, in a liquid, non-agglomerated fullerenic material from a gaseous suspension is provided. The method and system collects non-agglomerated fullerenic material by contacting a gaseous suspension comprising fullerenic material with a suspension liquid, so as to capture the fullerenic material in the suspension liquid; and collecting the liquid suspension as a suspension liquid containing the fullerenic material. This method and system may be particularly useful for collecting fullerenes or nanotubes and maintaining them in solution in non-agglomerated states.
摘要翻译：提供了一种从气体悬浮液中收集液体非团聚的富勒烯物质的原位方法和系统。所述方法和系统通过将包含富勒烯物质的气态悬浮液与悬浮液接触来收集非团聚的富勒烯物质，以捕获悬浮液中的富勒烯物质; 并收集液体悬浮液作为含有富勒烯物质的悬浮液。该方法和系统可能特别适用于收集富勒烯或纳米管并将其保持在非聚集状态的溶液中。

6. 发明申请

US20120219489A1 CARBON NANOSTRUCTURES FROM PYROLYSIS OF ORGANIC MATERIALS 有权
标题翻译：有机材料热解的碳纳米管结构
公开(公告)号：US20120219489A1
公开(公告)日：2012-08-30
申请号：US13260397
申请日：2010-03-26
申请人： Yiannis Levendis , Henning Richter , Chuanwei Zhuo
发明人： Yiannis Levendis , Henning Richter , Chuanwei Zhuo
IPC分类号： D01F9/12 , B82Y40/00
CPC分类号： C01B32/16 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/40 , C01B33/1071 , C01B2202/06 , C01B2202/34 , C01B2202/36 , Y10S977/842 , Y10S977/843
摘要： Methods and apparatus to generate carbon nanostructures from organic materials are described. Certain embodiments provide solid waste materials into a furnace, that pyrolyzes the solid waste materials into gaseous decomposition products, which are then converted to carbon nanostructures. Methods and apparatuses described herein provide numerous advantages over conventional methods, such as cost savings, reducion of handling risks, optimization of process conditions, and the like.
摘要翻译：描述了从有机材料产生碳纳米结构的方法和装置。某些实施方案将固体废物提供到炉中，将固体废物热解成气态分解产物，然后将其转化为碳纳米结构。本文所述的方法和装置提供了许多优于常规方法的优点，例如成本节约，操作风险的降低，工艺条件的优化等。

7. 发明申请

US20050147552A1 Method for combustion synthesis of fullerenes 有权
标题翻译：富勒烯燃烧合成方法
公开(公告)号：US20050147552A1
公开(公告)日：2005-07-07
申请号：US10489846
申请日：2002-08-31
申请人： Jack Howard , David Kronholm , Anthony Modestino , Henning Richter
发明人： Jack Howard , David Kronholm , Anthony Modestino , Henning Richter
IPC分类号： B01J19/26 , C01B31/02 , F23C6/02 , F23C99/00
CPC分类号： F23C6/02 , B01J2219/00157 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , F23C99/00 , Y10S977/734 , Y10S977/842
摘要： A mod of combustion and a multi-component reactor to accomplish this mode of combustion are disclosed which produces fullerenes and fullerenic material by combustion. This mode consists of de-coupling an oxidation region of a flame from a post-flame region, thus giving greater control over operating parameters, such as equivalence ratio, temperature, and pressure ; allows conditions of the operating parameters of the combustion reaction to be attained which would not be easily attained by conventional methods; and offers the ability to more easily stabilize the combustion reactions to allow for higher throughputs of fuel and oxidant. Several embodiments of a primary zone of a multicomponent reactor are also disclosed. Said primary zone serves as the oxidation region, operates on the principle of providing recycle to the reacting combustion mixture, and which may be operated as approximately a well-mixed reactor. A secondary zone is also disclosed which provides further residence time for reaction and the ability to control operating parameters, operates on the principle of minimizing recycle of the reacting combustion mixture. The secondary zone may be operated as approximately a plug-flow reactor. The primary and secondary zones may be operated in conjunction or either one alone.
摘要翻译：公开了一种用于实现这种燃烧模式的燃烧模块和多组分反应器，其通过燃烧产生富勒烯和富勒烯材料。该模式包括将来自火焰后区域的火焰的氧化区域去耦合，从而对操作参数（例如当量比，温度和压力）进行更大的控制; 允许通过常规方法不容易地获得燃烧反应的操作参数的条件; 并提供更容易稳定燃烧反应的能力，以允许更高的燃料和氧化剂产量。还公开了多组分反应器的主要区域的几个实施方案。所述主区域用作氧化区域，其操作原理是向反应燃烧混合物提供循环，并且可以作为大致良好混合的反应器操作。还公开了次级区域，其提供进一步的反应停留时间和控制操作参数的能力，其操作原理是使反应燃烧混合物的循环最小化。次级区可以作为大约一个活塞流反应器操作。主区域和次区域可以一起操作或者单独操作。

8. 发明授权

US4328858A Device for absorbing heat from the earth 失效
标题翻译：用于从地球吸收热量的装置
公开(公告)号：US4328858A
公开(公告)日：1982-05-11
申请号：US135838
申请日：1980-03-31
申请人： Henning Richter , Klaus Brocks
发明人： Henning Richter , Klaus Brocks
IPC分类号： F24J20060101 , F28D15/00 , F28F27/00
CPC分类号： F24J3/084 , F24J2003/088 , Y02E10/125
摘要： In order to guarantee that the floor space be kept to a minimum and nevertheless render a closed circuit system possible with a device for absorbing the heat of the earth, particularly for operating a heat pump which at the same time affords high, steady final temperatures of the medium to be heated, a probe with a tube body extending into the ground like a column is used. The end of the probe pointing to the ground is sealed, and in the interior thereof an inner tube is arranged, the diameter of which is smaller than the inside diameter of the tube body, so as to form a circulation jacket. The inner tube is provided at its bottom end with an overflow opening into the circulation jacket. It is advantageous to seal the tube body at its end that points to the ground by means of a removable piston. This enables the tube body to be inserted into the ground as a permanently implanted boring rod during a wash boring operation.
摘要翻译：为了保证占地面积最小化，并且使得闭路回路系统可以用于吸收地球热量的装置，特别是用于操作热泵的装置，同时提供高的稳定的最终温度要加热的介质，使用具有如柱状延伸到地面的管体的探针。指向地面的探针的端部被密封，并且在其内部设置有内管，其直径小于管体的内径，从而形成循环护套。内管在其底端处设置有进入循环护套的溢流开口。有利的是，通过可拆卸的活塞密封管本体的其指向地面的端部。这使得管体能够在洗涤钻孔操作期间作为永久植入的钻杆插入地面。

9. 发明授权

US09296912B2 Solvent-based and water-based carbon nanotube inks with removable additives 有权
标题翻译：具有可除去添加剂的溶剂型和水性碳纳米管油墨
公开(公告)号：US09296912B2
公开(公告)日：2016-03-29
申请号：US12855640
申请日：2010-08-12
申请人： Ramesh Sivarajan , Henning Richter , Viktor Vejins
发明人： Ramesh Sivarajan , Henning Richter , Viktor Vejins
IPC分类号： H01B1/04 , C01B31/02 , C09D11/52 , C09D11/03
CPC分类号： C09D11/52 , C09D11/03
摘要： In accordance with some embodiments, compositions and methods for forming solvent-based and water-based carbon nanotubes inks with removable additives are provided. In some embodiments, the ink composition comprises one or more carbon nanotubes, a solvent, and a removable additive, which may function as a stabilizing agent, a viscosity adjustment agent, or any suitable combination thereof. The removable additive may be removed from articles derived from the ink composition by means of thermal annealing.
摘要翻译：根据一些实施方案，提供了用于形成具有可除去添加剂的溶剂基和水基碳纳米管油墨的组合物和方法。在一些实施方案中，油墨组合物包含一种或多种碳纳米管，溶剂和可除去的添加剂，其可用作稳定剂，粘度调节剂或其任何合适的组合。可以通过热退火将可除去的添加剂从衍生自油墨组合物的制品中除去。

10. 发明授权

US09051185B2 Carbon nanostructures from pyrolysis of organic materials 有权
标题翻译：有机材料热解碳纳米结构
公开(公告)号：US09051185B2
公开(公告)日：2015-06-09
申请号：US13260397
申请日：2010-03-26
申请人： Yiannis Levendis , Henning Richter , Chuanwei Zhuo
发明人： Yiannis Levendis , Henning Richter , Chuanwei Zhuo
IPC分类号： C01B31/02 , B82Y30/00 , B82Y40/00 , C01B33/107
CPC分类号： C01B32/16 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/40 , C01B33/1071 , C01B2202/06 , C01B2202/34 , C01B2202/36 , Y10S977/842 , Y10S977/843
摘要： Methods and apparatus to generate carbon nanostructures from organic materials are described. Certain embodiments provide solid waste materials into a furnace, that pyrolyzes the solid waste materials into gaseous decomposition products, which are then converted to carbon nanostructures. Methods and apparatuses described herein provide numerous advantages over conventional methods, such as cost savings, reduction of handling risks, optimization of process conditions, and the like.
摘要翻译：描述了从有机材料产生碳纳米结构的方法和装置。某些实施方案将固体废物提供到炉中，将固体废物热解成气态分解产物，然后将其转化为碳纳米结构。本文所述的方法和装置提供了诸如成本节约，降低处理风险，工艺条件优化等常规方法的许多优点。

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