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    • 3. 发明授权
    • Process for separating alkylaromatics from aromatic solvents and the
separation of the alkylaromatic isomers using membranes
    • 从芳香族溶剂中分离烷基芳族化合物的方法和使用膜分离烷基芳族异构体的方法
    • US4571444A
    • 1986-02-18
    • US603028
    • 1984-04-27
    • Laura E. BlackHeather A. Boucher
    • Laura E. BlackHeather A. Boucher
    • C07C2/66B01D61/02B01D71/64C07C1/00C07C7/144C07C15/00C07C15/113C07C67/00
    • B01D61/025C07C7/144
    • In the production of alkylaromatics by the alkylation of aromatic hydrocarbons with alkylating agents such as olefins typically in the presence of a catalyst, the unconverted aromatic hydrocarbon remaining after completion of the alkylation process is separated from the alkylaromatic product and the terminal alkylaromatic isomers are separated from the mixture of alkylaromatic isomers produced in the alkylation process by the selective permeation of the aromatic hydrocarbon and the terminal isomers through a permselective membrane, preferably an asymmetric membrane producing a permeate rich in the terminal isomers and a retentate which is lean (i.e., depleated) in the terminal isomers. Permeation is under reverse osmosis conditions, that is, under a pressure sufficient to at least overcome the osmotic pressure of the aromatic hydrocarbon present in the mixture made up of the aromatic hydrocarbon, the olefin and the mixed isomer alkylaromatic product. Permeation is carried out at a pressure of about 100 to 800 psig, preferably a pressure of about 200 to 600 psig, more preferably a pressure of about 300 to 500 psig, at a temperature of about 0.degree. to 100.degree. C., preferably about 20.degree.-80.degree. C., most preferably about 20.degree. to 50.degree. C. The membrane of choice is an asymmetric polyimide membrane.
    • 在通过芳族烃与烷基化剂如烯烃的烷基化(通常在催化剂存在下)进行烷基芳族化合物的生产中,将烷基化方法完成后残留的未转化的芳族烃与烷基芳族化合物分离,并将末端烷基芳族异构体与 在烷基化方法中通过选择性渗透芳族烃和末端异构体通过选择性选择性膜,优选不对称膜,产生富含末端异构体的渗透物和贫(即,耗尽)的滞留物在烷基化方法中产生的烷基芳族异构体的混合物, 在末端异构体中。 渗透处于反渗透条件下,即在足以至少克服由芳族烃,烯烃和混合异构体烷基芳族化合物产物组成的混合物中存在的芳族烃的渗透压的压力下。 渗透在约0℃至100℃的温度下进行,压力为约100至800psig,优选压力为约200至600psig,更优选压力为约300至500psig,优选约为 20℃-80℃,最优选约20℃至50℃。所选择的膜是不对称聚酰亚胺膜。